File name: Pandora204s1_BoulderCO-NCAR_20231217_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20240212T182855.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20231217_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20231217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231217T145934.1Z 8751.624700 64 1 49.15 2 84.08 127.43 127.96 79.98 0.00 1 0.00 1 0 17 7.052e-01 1.690e-02 3.376e-01 6.932e-03 1.017826e+00 4.014139e-03 1.044725e-02 -6.000000e+00 4.031545e-01 222.30 -2.00 3.45 -2.00 322.41 0.00e+00 8.417270e-03 1.921561e-03 1.698262e-03 -6.000000e+00 1.727283e-02 268.14 -2.00 20.00 -2.00 322.07 0.00e+00 8.683 0.011 302.00 328.00 3 3.8843e+00 1.3715e-02 8.9045e-02 -6.0000e+00 9.9870e-01 7.4526e-01 2.3157e-02 5.4921e-02 -6.0000e+00 1.0936e+00 -1.0867e+00 2.7877e-02 3.3716e-02 -6.0000e+00 6.4180e-01 4.5157e-01 1.2924e-02 1.2538e-02 -6.0000e+00 2.6983e-01 3.2943e-06 -1.3956e-03 1.9240e-04 1.6211e-04 -6.0000e+00 1.9788e-02 -2.4215e-02 5.0437e-05 12 8 8 10 0 0 40.18 18.39 0.30 -0.02421 -0.03470 163 36 1 5 0 301.450 21.27 15.00 18.39 9.61 13.4 765.38 -238049 -66769 -245150 900000 -258412 900000 72452 900000 -175152 -123378 -201198 -182559 900000 -142510 122078 -122064 900000 -91178 139714 -88222 900000 -91471 -78241 -81945 -117124 -68325 -118341 -13938 -149309 99244 -77086 309532 -24125 89990 -22558 99868 -19340 46643 42331 -29716 53752 16584 48226 8372 83915 12812 51916 3177 16218 45173 41606 44063 16521 49390 18647 50407 12992 47429 14418 30915 19158 27949 14044 37783 13104 12599 18699 6305 19520 7838 19429 11863 17765 6091 6615 -2429 -160 165 2594 5442 -670 6743 -420 5643 -1240 955 38 2521 1236 2107 597 -777 264 -7174 -3185 -3502 -327 -2604 1330 -1392 -386 -2466 -145 -179 -3930 -2888 -3575 -1049 -1448 514 -403 -111 -778 -38 -1739 -751 -537 -743 108 -144 1273 1900 2792 455 1634 346 603 1396 267 141 117 266 -473 475 -604 389 87 1155 252 -285 -466 -782 -1363 -3081 -451 -4414 900000 -4508 900000 489 900000 -1398 -833 -2223 -1905 900000 -1837 824 -2173 900000 -1567 943 -1625 900000 -1628 -1201 -1358 -2876 -1049 -2979 -120 -4950 670 -1751 2090 -504 729 -499 674 -404 630 650 -1113 990 478 1066 283 1339 425 1211 129 627 1442 1558 1839 930 2395 1207 2692 943 2620 965 1822 1270 1853 1146 2870 1431 1432 2041 827 2493 1301 3203 2210 3069 1097 1057 -375 -23 24 431 1087 -161 1772 -135 1829 -456 363 15 1016 504 824 222 -278 92 -2884 -1433 -1916 -209 -2022 1130 -1267 -332 -1931 -97 -114 -2709 -2096 -2763 -859 -1343 548 -471 -145 -1080 -53 -2395 -995 -711 -1029 156 -216 1831 2750 3783 612 2111 441 749 1804 407 238 228 575 -1112 1193 -1652 1114 257 3377 738 -803 -1211 -1860 -3053 SS 20231217T151110.0Z 8751.632755 67 1 49.23 2 82.34 129.46 125.84 81.98 0.00 1 0.00 1 0 17 7.468e-01 9.239e-03 1.687e-01 2.542e-03 8.642822e-01 1.397725e-03 9.041166e-03 -6.000000e+00 4.199895e-01 222.30 -2.00 3.45 -2.00 321.98 0.00e+00 7.213617e-03 6.270725e-04 1.209042e-03 -6.000000e+00 1.723109e-02 268.14 -2.00 20.00 -2.00 321.65 0.00e+00 7.004 0.006 302.00 328.00 3 3.8952e+00 4.5375e-03 7.2730e-02 -6.0000e+00 1.0388e+00 2.0298e-01 7.7044e-03 4.6649e-02 -6.0000e+00 1.1351e+00 -3.2619e-01 9.7349e-03 2.8670e-02 -6.0000e+00 6.7006e-01 1.3866e-01 4.5664e-03 1.0448e-02 -6.0000e+00 2.8323e-01 1.4643e-05 -9.1023e-04 7.0648e-05 1.2515e-04 -6.0000e+00 2.0327e-02 -2.4672e-02 5.2066e-05 11 8 0 10 0 0 34.30 18.38 0.23 -0.02467 -0.03151 359 78 1 5 0 137.100 21.27 15.00 18.38 10.48 13.2 770.75 -240170 -257946 -229498 -247405 -196391 -278018 -197315 -264170 -101694 -232002 -196103 -201008 -144159 -166950 -116159 -88343 -135102 -89918 -79092 -30043 -116202 -33678 -84704 -60410 -79393 -45069 -42111 -62856 -34176 -48600 -14863 -41304 10732 -17642 -7984 -27959 -11264 -14556 -10898 3072 11680 5829 3586 13599 -5317 22124 2224 14894 1631 8832 5395 13037 13259 12040 10429 6272 8099 1067 7331 531 4919 6768 8901 7649 8402 7360 4584 3624 3167 5878 2485 4317 940 3424 -2217 -566 -2580 -4816 -2955 -1982 51 -1059 -1851 -1469 -82 -716 1432 803 1549 622 1409 -279 -1798 -1850 -2318 -936 -467 1015 227 322 -348 -806 -997 -281 -2010 -1690 -1457 -1011 195 386 608 369 360 -226 -682 -684 -475 -313 60 54 467 1265 1223 739 214 -307 -190 798 -5 12 55 -58 -97 -112 -180 -269 360 571 216 -63 -62 -543 -563 -1191 -1919 -1448 -1896 -925 -2569 -930 -2441 -252 -1883 -1313 -1645 -894 -1656 -1037 -767 -2040 -993 -874 -238 -2043 -284 -1107 -734 -1145 -536 -501 -836 -381 -699 -192 -810 168 -374 -153 -636 -231 -361 -319 95 382 222 150 536 -238 853 101 692 86 476 341 875 997 1012 961 632 828 117 732 55 497 738 1107 1127 1260 1143 738 618 600 1257 616 1109 248 830 -516 -115 -500 -980 -672 -544 17 -407 -806 -684 -40 -374 770 448 860 338 714 -135 -862 -926 -1327 -628 -370 929 219 320 -358 -744 -816 -219 -1681 -1498 -1359 -1012 215 452 812 543 548 -343 -1003 -967 -668 -456 92 86 727 1858 1708 1081 304 -426 -255 1098 -7 21 107 -124 -219 -272 -469 -743 1011 1618 613 -174 -159 -1282 -1257 SS 20231217T154930.0Z 8751.659375 78 1 49.84 2 76.98 136.54 118.76 88.17 0.00 1 0.00 1 0 17 1.749e-01 6.024e-03 1.731e-02 5.207e-04 5.808212e-01 2.670978e-04 6.481973e-03 -6.000000e+00 9.835771e-02 222.30 -2.00 3.45 -2.00 320.54 0.00e+00 2.946723e-03 8.895907e-05 4.286626e-04 -6.000000e+00 4.035313e-03 268.13 -2.00 20.00 -2.00 320.24 0.00e+00 4.330 0.001 302.00 328.00 3 3.7864e+00 7.6201e-04 4.5804e-02 -6.0000e+00 2.4327e-01 1.2783e-02 9.7293e-04 2.9282e-02 -6.0000e+00 2.6581e-01 -2.6840e-02 1.0657e-03 1.6074e-02 -6.0000e+00 1.5691e-01 8.1350e-03 5.5555e-04 5.2866e-03 -6.0000e+00 6.6338e-02 1.7347e-04 -4.5054e-04 1.4808e-05 6.0238e-05 -6.0000e+00 4.7594e-03 -2.5499e-02 6.5057e-05 10 0 0 10 0 0 6.05 18.37 0.23 -0.02550 -0.02888 1268 276 1 5 0 38.840 21.27 14.99 18.37 13.92 13.4 798.72 -54497 -67476 -36493 -71688 -49473 -73844 -48676 -61090 -47171 -53078 -51486 -43271 -40581 -21338 -23971 -7011 -14046 -1131 -10932 -784 -7937 -4946 -8293 -6296 -6682 -7325 -7581 -12153 -7428 -11722 -3825 -5329 1206 -4215 -4161 -6970 -5598 -3781 -2183 -766 -1923 589 -949 906 25 1418 386 1177 -165 854 1763 1253 2154 1786 1805 1278 1289 -396 82 -339 1265 1461 2847 3215 1339 1128 446 -30 596 994 642 1158 103 586 -439 -839 -1766 -2656 -1954 -1962 -1290 -1230 -1976 -1714 -835 -655 606 626 1213 1115 956 409 -594 -544 -637 -399 204 1209 360 88 -131 -730 -617 -13 -1208 -1337 -788 -597 341 668 791 418 483 17 -325 -293 -242 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