File name: Pandora204s1_BoulderCO-NCAR_20231223_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20240212T183843.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20231223_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20231223 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231223T155214.5Z 8757.661279 216 1 49.97 2 77.07 136.54 120.44 356.74 0.00 1 0.00 1 0 25 3.565e-01 1.339e-02 3.141e-01 9.845e-03 6.434742e-01 5.161708e-03 7.101828e-03 -6.000000e+00 2.006892e-01 222.48 -2.00 3.45 -2.00 320.97 0.00e+00 5.327389e-03 1.871742e-03 5.485086e-04 -6.000000e+00 8.254723e-03 267.76 -2.00 20.00 -2.00 320.65 0.00e+00 4.357 0.001 302.00 328.00 3 8.5397e+00 1.5051e-02 4.8184e-02 -6.0000e+00 4.9657e-01 1.1978e-01 2.0060e-02 3.2718e-02 -6.0000e+00 5.4277e-01 -9.5336e-02 2.2620e-02 1.8275e-02 -6.0000e+00 3.2022e-01 3.4356e-02 1.1562e-02 6.1197e-03 -6.0000e+00 1.3635e-01 1.2800e-06 -9.2334e-04 2.7928e-04 7.2537e-05 -6.0000e+00 9.7772e-03 -2.5824e-02 4.2374e-05 12 9 8 11 8 0 99.75 18.41 0.26 -0.02582 -0.03276 20 4 1 5 0 2498.100 21.27 15.00 18.41 11.12 13.1 777.04 900000 -112087 -20629 -105403 -25689 -116503 -67534 -208465 -69349 4129 -93655 -20402 -151608 -93484 -73721 -48721 53746 -33365 42466 -35924 -37548 12882 30610 -27983 -62810 -29281 -39022 1279 22809 88827 14105 -9531 -13864 51953 33189 23359 -14010 -2369 -3621 -275 -4524 17014 837 12118 3062 -697 8965 9741 12962 -8088 5921 2866 3344 6535 1628 5899 8471 -2592 2714 -2016 6355 5889 1496 9220 1931 6764 2068 1393 -1355 3458 2857 2664 2143 2487 -1425 -4326 -2118 -4309 2830 -2580 -315 -3318 -2955 -2450 -1835 -1074 -342 73 2249 411 -97 1659 -1341 -821 -537 -284 1094 562 314 -250 -387 -1533 -1326 -558 -1032 -2309 -888 -1682 -217 409 859 725 642 -5 -242 -105 -998 -133 -33 -391 149 1190 1407 1360 761 -919 -148 1764 -549 -258 1294 -436 48 -176 -400 -580 -91 1104 628 134 -469 -457 -1060 900000 -1224 -198 -1200 -247 -1315 -648 -6060 -666 40 -1239 -196 -4503 -2120 -1763 -1125 572 -847 599 -1073 -1172 258 534 -871 -2854 -1037 -1545 35 513 1179 418 -416 -729 1655 1238 925 -822 -144 -267 -23 -450 1502 91 1226 343 -83 1002 1118 1505 -1214 852 473 602 1238 343 1240 1787 -608 592 -450 1335 1344 403 2603 628 2092 653 449 -483 1341 1239 1221 986 1089 -597 -1679 -741 -1526 1017 -1144 -160 -1979 -1935 -1694 -1335 -823 -274 60 1824 330 -74 1154 -912 -558 -398 -241 1050 618 380 -312 -460 -1670 -1304 -532 -1045 -2513 -997 -2018 -278 576 1328 1194 1073 -7 -376 -155 -1472 -200 -53 -651 247 1893 2150 2012 1090 -1290 -198 2357 -824 -433 2349 -854 99 -377 -908 -1388 -222 2697 1544 322 -1074 -986 -2206 SS 20231223T162221.1Z 8757.682189 230 1 26.39 2 73.33 142.54 120.28 4.57 0.00 1 0.00 1 0 25 1.008e-01 6.425e-03 1.703e-02 8.852e-04 5.216558e-01 4.440700e-04 5.964533e-03 -6.000000e+00 5.674518e-02 222.48 -2.00 3.45 -2.00 319.71 0.00e+00 2.056250e-03 1.197391e-04 2.702616e-04 -6.000000e+00 2.326425e-03 267.76 -2.00 20.00 -2.00 319.42 0.00e+00 3.434 0.001 302.00 328.00 3 5.4014e+00 1.2189e-03 3.8232e-02 -6.0000e+00 1.4040e-01 2.3513e-02 1.4427e-03 2.5801e-02 -6.0000e+00 1.5339e-01 -1.5394e-02 1.3463e-03 1.3587e-02 -6.0000e+00 9.0537e-02 2.4686e-03 7.2837e-04 4.2441e-03 -6.0000e+00 3.8266e-02 7.2851e-05 -5.2789e-04 2.4604e-05 4.5395e-05 -6.0000e+00 2.7439e-03 -2.6583e-02 4.2498e-05 12 9 1 12 1 1 94.95 18.41 0.22 -0.02658 -0.03055 166 68 1 5 0 157.940 21.27 15.00 18.41 13.02 13.3 793.47 -46977 -27757 -40225 -22743 -35094 -20681 -47966 -31177 -20560 -25840 -21944 -31270 -18747 -18059 -3943 -8745 -1783 -5316 -1192 -3502 -1315 -2353 -4480 -3743 -6898 -2822 -7659 -5469 -7465 -2939 -3910 -381 -67 -2047 -2596 -3759 -4768 -2894 -966 -997 -685 -765 149 -726 1329 1124 558 930 -515 1044 897 1568 1662 2142 729 1609 671 427 -199 61 1028 1667 2611 2578 1198 607 415 -842 918 586 621 781 460 478 -180 -391 -1608 -2149 -1975 -1884 -1806 -1118 -2338 -1495 -923 -551 439 507 1102 867 935 261 -330 -429 -308 -422 426 1108 518 8 -218 -774 -668 -101 -1331 -1077 -906 -484 204 765 756 492 477 127 -297 -208 -94 -190 133 -226 -65 429 651 189 395 -323 -402 778 76 22 -52 -320 -360 -7 -138 -80 178 625 238 -27 -70 -452 -379 -700 -405 -723 -341 -548 -266 -851 -529 -357 -515 -439 -741 -469 -563 -132 -366 -78 -264 -61 -195 -74 -134 -268 -238 -450 -205 -547 -407 -548 -211 -319 -32 -7 -219 -274 -389 -530 -369 -147 -182 -142 -171 35 -175 318 274 138 233 -134 279 260 500 578 799 270 612 265 170 -78 23 395 686 1192 1311 653 325 213 -437 500 365 431 531 314 337 -118 -231 -876 -1143 -1119 -1232 -1273 -889 -2065 -1387 -904 -536 447 533 1157 886 956 249 -296 -380 -293 -426 487 1337 688 11 -281 -970 -760 -113 -1606 -1380 -1139 -640 288 1177 1199 826 802 206 -451 -316 -141 -293 203 -367 -107 681 995 297 593 -468 -556 1067 115 34 -89 -585 -644 -13 -275 -158 363 1288 495 -55 -143 -870 -699 SS 20231223T162748.7Z 8757.685980 233 1 49.42 2 72.70 143.67 120.17 5.98 0.00 1 0.00 1 0 17 9.052e-02 6.103e-03 3.012e-02 1.495e-03 5.042248e-01 7.533387e-04 5.753329e-03 -6.000000e+00 5.095797e-02 222.48 -2.00 3.45 -2.00 319.91 0.00e+00 1.982167e-03 2.120853e-04 2.783298e-04 -6.000000e+00 2.089154e-03 267.76 -2.00 20.00 -2.00 319.61 0.00e+00 3.316 0.001 302.00 328.00 3 6.8160e+00 2.0841e-03 3.6982e-02 -6.0000e+00 1.2609e-01 2.4586e-02 2.4939e-03 2.5031e-02 -6.0000e+00 1.3774e-01 -1.0103e-03 2.3940e-03 1.3260e-02 -6.0000e+00 8.1302e-02 -5.2004e-03 1.2864e-03 4.1771e-03 -6.0000e+00 3.4364e-02 1.9722e-05 -5.6886e-04 4.2623e-05 4.6114e-05 -6.0000e+00 2.4640e-03 -2.6699e-02 4.4119e-05 10 0 0 10 0 0 99.79 18.41 0.13 -0.02670 -0.03097 94 20 1 5 0 525.660 21.27 15.01 18.41 13.77 13.2 796.97 -32546 -30025 -32543 -18422 -42397 -35619 -30854 -28215 -11980 -26635 -30542 -20530 -16163 -11846 346 -6836 -3374 1020 -714 1647 -2151 -290 752 36 -4055 -5145 -6972 -2855 -6910 -4078 -2113 116 715 -2201 -2881 -3008 -3348 -3584 -475 -1482 -265 -1063 -265 -432 495 502 169 821 -675 882 1214 590 1618 1949 347 1145 324 -406 -107 -108 1364 1204 2761 2747 875 246 384 -909 1043 698 315 888 269 980 -219 -479 -1130 -2110 -1814 -1754 -1252 -1093 -2083 -1542 -810 -372 484 450 998 922 966 233 -118 -350 -339 -424 322 1161 357 156 -102 -867 -964 -308 -1275 -1182 -960 -663 222 857 778 439 542 179 -254 -347 -318 -374 115 -114 -105 366 670 281 443 -278 -449 687 40 -32 -52 -316 -359 -111 -32 -94 277 588 165 2 101 -594 -340 -422 -444 -532 -264 -701 -532 -461 -461 -191 -524 -648 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