File name: Pandora204s1_BoulderCO-NCAR_20240527_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20240528T070646.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20240527_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20240527 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240527T122008.7Z 8913.513989 197 1 49.17 2 83.28 67.58 71.65 205.76 0.00 1 0.00 1 0 25 6.565e-01 2.274e-02 3.965e-01 9.696e-03 1.040490e+00 5.798738e-03 1.062998e-02 -6.000000e+00 3.836383e-01 230.77 -2.00 3.45 -2.00 322.42 0.00e+00 3.097959e-03 2.669523e-03 1.607691e-03 -6.000000e+00 1.581141e-02 277.10 -2.00 20.00 -2.00 322.07 0.00e+00 7.810 0.008 302.00 328.00 3 5.0483e+00 1.9880e-02 8.6059e-02 -6.0000e+00 9.6811e-01 9.9412e-01 3.0326e-02 5.7489e-02 -6.0000e+00 1.0526e+00 -1.4510e+00 3.4027e-02 3.4156e-02 -6.0000e+00 6.1823e-01 5.9523e-01 1.6296e-02 1.2263e-02 -6.0000e+00 2.5820e-01 1.7617e-06 -1.4785e-03 2.7453e-04 1.5649e-04 -6.0000e+00 1.8808e-02 -2.9330e-02 6.2212e-05 12 8 8 10 0 0 0.91 18.40 0.30 -0.02933 -0.04044 73 16 1 5 0 673.420 21.27 14.99 18.40 16.69 14.6 832.58 -144572 -98883 -150700 900000 -53938 -56095 91521 -91553 31234 -210454 173830 -218067 900000 -123728 900000 -74245 900000 19120 -62405 140615 90366 900000 81387 224200 -31375 138733 -108569 152726 -108523 36139 -24415 5401 34023 4787 85631 -11753 900000 5166 900000 -497 249493 10979 94323 46671 105115 31113 97964 102249 7469 139890 46605 108017 25132 63836 16778 80804 46835 51022 30931 23507 29060 20591 40344 6926 47597 9150 46969 18050 37660 18023 25193 18839 16253 13350 8639 20015 3951 14982 -11118 6594 1497 3805 -2265 2821 5643 1564 3589 85 7537 -4 3003 -5433 1132 -8197 -1596 -5966 -1501 -2484 -704 -690 -4442 -1448 -4681 -779 -4229 -1317 -5632 -97 -2688 -887 -1720 77 303 -1081 -60 -1995 712 -1471 890 78 2262 908 3568 1560 2158 1225 122 1747 -444 1421 -459 1224 -519 682 -446 11 53 734 174 -129 238 -1658 -1492 -2535 -1365 -3354 900000 -509 -530 864 -865 295 -6530 1641 -8090 900000 -3146 900000 -1780 900000 222 -1723 1328 853 900000 769 2117 -615 1310 -4247 1442 -4099 370 -514 106 593 122 1011 -316 900000 135 900000 -20 2356 463 1930 1424 1903 1085 1927 2012 374 2202 1930 2975 1509 3060 1279 3639 3028 3113 2179 1673 1921 1472 2931 761 3885 1129 4023 2179 4140 2784 4044 3380 2949 2314 1398 2538 544 1900 -2100 1281 348 1020 -733 936 1929 589 1385 35 2871 -2 1087 -2021 388 -3272 -690 -3253 -942 -1867 -593 -608 -3899 -1105 -3236 -489 -2876 -927 -4375 -78 -2471 -937 -2009 100 413 -1512 -82 -2676 931 -2051 1278 116 3248 1328 4793 2069 2763 1541 151 2216 -669 2347 -890 2594 -1211 1698 -1213 31 156 2159 511 -365 617 -3986 -3336 SS 20240527T123129.9Z 8913.521874 200 1 49.20 2 81.25 69.30 72.59 208.16 0.00 1 0.00 1 0 17 7.772e-01 9.488e-03 2.027e-01 3.085e-03 8.760974e-01 1.734695e-03 9.080436e-03 -6.000000e+00 4.514231e-01 230.77 -2.00 3.45 -2.00 321.93 0.00e+00 7.008124e-03 7.580606e-04 1.191816e-03 -6.000000e+00 1.815261e-02 277.10 -2.00 20.00 -2.00 321.60 0.00e+00 6.226 0.004 302.00 328.00 3 4.8083e+00 5.6783e-03 7.0137e-02 -6.0000e+00 1.1383e+00 1.6252e-01 9.5234e-03 4.8683e-02 -6.0000e+00 1.2359e+00 -2.8812e-01 1.1997e-02 2.8939e-02 -6.0000e+00 7.2558e-01 1.2164e-01 5.6163e-03 1.0203e-02 -6.0000e+00 3.0304e-01 9.9849e-06 -6.3507e-04 8.6770e-05 1.2650e-04 -6.0000e+00 2.1207e-02 -2.9412e-02 7.1950e-05 12 8 8 10 0 0 25.55 18.40 0.21 -0.02941 -0.03418 205 45 1 5 0 239.960 21.27 15.00 18.40 17.52 14.6 838.62 -226023 -295459 900000 -267068 -283231 -235167 -279667 -262240 -231777 -204625 -215343 -195982 -162580 -102984 -135288 -11808 -81373 -88525 -99255 -51446 -110004 -50625 -78212 -91824 -44153 -54035 7125 -90210 -35812 -80876 -46221 -52730 -18694 -15117 -32530 -31450 -16126 -25156 -10236 8440 378 12362 -5086 6494 -9430 10582 1983 6867 -5036 7298 7957 14121 10740 4947 8243 8791 9432 7677 5081 715 3889 5059 7392 7826 9109 8817 4720 3512 3946 2270 4291 4515 2665 1528 163 -510 -2152 -3555 -680 -767 -56 -60 -1333 -1628 -675 -1084 619 637 2086 1911 1780 -135 -1413 -2739 -2162 -938 -474 858 384 167 -301 -989 -1140 -393 -2017 -1679 -1237 -1508 164 108 705 -92 269 -385 -683 -818 -307 120 72 126 279 1338 1348 987 475 -157 -473 573 -89 -23 247 -394 -73 88 -68 -363 258 577 390 -58 -119 -712 -549 -804 -2666 900000 -2118 -2478 -1222 -2371 -2080 -1521 -1119 -1413 -1233 -978 -527 -1184 -43 -645 -871 -1221 -422 -1685 -429 -898 -1306 -423 -606 49 -1505 -353 -1393 -708 -1110 -343 -302 -774 -722 -340 -681 -294 245 13 403 -212 252 -442 422 90 318 -285 402 495 949 840 419 731 816 901 750 495 71 380 536 889 1096 1399 1393 783 618 766 520 1085 1207 724 396 39 -110 -437 -748 -158 -216 -19 -24 -560 -737 -322 -553 327 349 1129 1007 883 -69 -711 -1449 -1198 -609 -364 762 386 174 -301 -894 -916 -301 -1651 -1457 -1126 -1480 176 132 981 -142 429 -614 -1051 -1212 -451 182 116 210 460 2071 1982 1407 657 -212 -620 766 -137 -42 498 -815 -162 206 -172 -976 708 1594 1079 -157 -296 -1649 -1198 SS 20240527T130038.4Z 8913.542111 210 1 49.24 2 75.97 73.63 75.32 214.10 0.00 1 0.00 1 0 25 2.086e-01 6.119e-03 2.383e-02 6.716e-04 6.006773e-01 3.555080e-04 6.606725e-03 -6.000000e+00 1.211687e-01 230.77 -2.00 3.45 -2.00 320.65 0.00e+00 3.372131e-03 1.183137e-04 4.459837e-04 -6.000000e+00 4.816074e-03 277.10 -2.00 20.00 -2.00 320.35 0.00e+00 4.035 0.001 302.00 328.00 3 4.4059e+00 1.0339e-03 4.6025e-02 -6.0000e+00 3.0554e-01 9.8656e-03 1.3187e-03 3.1464e-02 -6.0000e+00 3.3173e-01 -3.5964e-02 1.4396e-03 1.6865e-02 -6.0000e+00 1.9461e-01 1.2333e-02 7.4391e-04 5.3689e-03 -6.0000e+00 8.0893e-02 1.0993e-04 -4.0418e-04 1.9229e-05 6.0628e-05 -6.0000e+00 5.6882e-03 -2.9879e-02 7.7910e-05 10 0 0 10 0 0 -0.47 18.41 0.20 -0.02988 -0.03292 762 166 1 5 0 64.600 21.27 15.01 18.41 20.28 14.6 858.59 -77757 -36472 -71022 -50696 -71707 -82316 -81272 -72823 -65284 -65760 -56600 -61769 -31552 -31409 -22456 -22801 -7880 -15417 -4535 -10966 -9595 -8953 -6834 -8397 -7470 -10221 -10644 -13493 -13394 -7318 -8600 -3029 -2045 -3249 -5349 -6155 -6000 -3796 -1424 -2232 -228 -791 644 -78 1680 765 1312 1009 -146 1422 1767 1830 1790 2786 1368 1818 1060 -58 -375 139 1027 1418 2883 2902 1733 709 730 -379 1238 875 797 813 434 564 -211 -910 -1833 -2674 -2174 -1761 -1614 -1079 -2195 -1349 -861 -441 417 687 1309 1034 1083 318 -618 -669 -585 -610 372 1111 461 131 -71 -772 -652 -19 -1277 -1217 -871 -544 178 743 674 411 387 84 -462 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