File name: Pandora204s1_BoulderCO-NCAR_20240618_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20240619T070713.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20240618_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20240618 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240618T121527.4Z 8935.510734 124 1 49.35 2 83.51 64.74 128.59 276.68 0.00 1 0.00 1 0 17 6.586e-01 1.854e-02 3.457e-01 8.419e-03 8.996121e-01 5.039177e-03 9.238077e-03 -6.000000e+00 3.898994e-01 231.72 -2.00 3.45 -2.00 322.22 0.00e+00 5.108087e-03 2.281789e-03 1.330133e-03 -6.000000e+00 1.757105e-02 279.49 -2.00 20.00 -2.00 321.86 0.00e+00 8.033 0.009 302.00 328.00 3 4.9072e+00 1.7063e-02 8.2839e-02 -6.0000e+00 9.8938e-01 5.2601e-01 2.7375e-02 5.0272e-02 -6.0000e+00 1.0770e+00 -7.9325e-01 3.2855e-02 2.9603e-02 -6.0000e+00 6.2428e-01 3.3188e-01 1.5419e-02 1.0498e-02 -6.0000e+00 2.6118e-01 2.1153e-06 -1.1347e-03 2.5661e-04 1.3418e-04 -6.0000e+00 1.9419e-02 -3.3102e-02 8.6154e-05 12 9 8 11 8 0 32.93 18.40 0.29 -0.03310 -0.04163 75 16 1 5 0 657.870 21.27 15.00 18.40 18.36 14.9 825.96 900000 -245651 -157962 -161118 900000 -188833 -234159 900000 -119746 900000 -247902 900000 -219581 900000 -110510 1388 -25329 -101308 31916 -50475 900000 -116579 900000 -89292 900000 -139929 196114 -60356 900000 -22736 -5622 28060 31554 90543 -34922 900000 -27465 900000 29791 163065 16957 107535 28980 25413 74939 2032 21519 1935 33396 -18697 147860 -1360 89977 16642 56651 16843 30796 21443 12209 20536 13513 32073 2682 38915 4202 30665 948 13437 1405 17789 11353 11029 11682 3970 7254 -6493 16029 -7434 8717 -11673 8182 3328 990 -509 -250 643 814 2544 -1886 4665 635 6785 -6671 576 -5301 -206 -2249 -548 -1232 -835 129 -2332 -1098 -3305 -344 -3236 -1402 -1160 -51 -1377 -1103 181 -1132 87 -1741 -594 -1335 761 -1021 1839 37 2511 2401 1988 1374 -448 541 -74 1294 -316 791 -516 311 -207 391 -154 545 468 208 85 -563 -279 -1758 900000 -4248 -1298 -1345 900000 -1728 -3325 900000 -981 900000 -5163 900000 -4890 900000 -1513 11 -222 -2022 261 -709 900000 -2995 900000 -1889 900000 -5208 1606 -1067 900000 -299 -76 344 445 809 -997 900000 -733 900000 640 1336 552 1641 960 894 1689 91 831 94 1291 -1258 2403 -98 3125 1228 3112 1388 2302 1745 1048 1576 1110 2391 298 3566 584 3421 140 1837 235 2933 2220 2288 2402 833 1348 -1231 2292 -1342 1515 -2948 2052 1018 348 -195 -102 275 366 1162 -906 2054 275 2616 -2848 238 -2612 -114 -1504 -421 -1075 -759 112 -1877 -780 -2295 -244 -2520 -1130 -1004 -48 -1508 -1377 247 -1629 124 -2448 -800 -1810 1050 -1515 2762 56 3568 3261 2628 1775 -574 667 -95 1847 -533 1488 -1072 685 -489 986 -413 1489 1295 580 230 -1434 -658 -3979 SS 20240618T122646.9Z 8935.518599 127 1 49.23 2 81.53 66.44 130.67 278.63 0.00 1 0.00 1 0 17 5.541e-01 7.794e-03 1.904e-01 2.846e-03 7.502780e-01 1.577475e-03 7.932739e-03 -6.000000e+00 3.231052e-01 231.72 -2.00 3.45 -2.00 321.64 0.00e+00 5.412397e-03 6.521130e-04 8.870288e-04 -6.000000e+00 1.279609e-02 279.49 -2.00 20.00 -2.00 321.29 0.00e+00 6.404 0.004 302.00 328.00 3 4.6709e+00 4.9755e-03 6.6757e-02 -6.0000e+00 8.1662e-01 8.6272e-02 7.5844e-03 4.1384e-02 -6.0000e+00 8.8586e-01 -1.5136e-01 9.3363e-03 2.3739e-02 -6.0000e+00 5.1929e-01 6.3064e-02 4.4908e-03 8.1147e-03 -6.0000e+00 2.1554e-01 1.1510e-05 -5.9852e-04 8.3084e-05 9.7101e-05 -6.0000e+00 1.5110e-02 -3.3134e-02 8.4286e-05 11 8 0 10 0 0 11.90 18.40 0.21 -0.03313 -0.03763 204 44 1 5 0 241.170 21.27 15.00 18.40 18.84 15.0 829.41 -114851 -219130 -185966 -162074 -172844 -172157 -188597 -150602 -212171 -172372 -191052 -49494 -127868 -43167 -102030 -76386 -51991 -67619 -32859 -45309 -32431 -52939 -21818 -55329 -5525 -59904 -8539 -38462 -27076 -39007 -18609 -33355 -15811 -12508 -7854 -569 -31684 -1340 -20016 -6189 4816 6660 14776 9614 1117 2607 -1616 -3612 1767 92 9597 3616 8216 8034 6452 3625 5216 1286 2256 730 1058 4978 4498 6121 3785 4677 1756 2202 2437 1708 2752 2289 69 1299 -744 -2812 -2167 -4569 -2253 -3700 -28 -796 -1704 -1057 -847 -398 499 1088 1308 1352 433 607 -1583 -1563 -1350 -1199 -126 1511 584 187 -145 -1192 -762 -295 -1168 -1663 -668 -585 173 766 379 384 119 -11 -420 -605 -546 -396 196 80 43 896 1146 416 469 -334 -318 507 234 -176 -49 -312 -121 -229 -48 -201 217 681 352 66 -65 -284 -703 -319 -1769 -1220 -859 -959 -1003 -1237 -836 -2248 -1348 -1928 -151 -1000 -216 -1107 -809 -512 -887 -340 -572 -376 -761 -237 -907 -60 -1194 -106 -640 -403 -709 -333 -867 -415 -357 -214 -14 -1048 -42 -852 -279 225 336 735 527 68 163 -109 -262 130 7 788 359 870 866 762 463 680 176 299 96 142 699 729 1124 781 967 370 477 576 470 845 751 23 412 -221 -767 -542 -1171 -625 -1246 -11 -361 -874 -578 -493 -247 324 729 882 888 270 353 -902 -906 -869 -900 -110 1397 610 203 -151 -1133 -697 -260 -1098 -1677 -652 -610 196 974 545 602 191 -17 -639 -881 -789 -593 310 133 71 1415 1726 610 663 -460 -422 679 352 -306 -95 -658 -269 -543 -115 -506 559 1776 927 169 -169 -683 -1615 SS 20240618T125738.6Z 8935.540030 137 1 49.30 2 76.03 70.98 136.27 284.40 0.00 1 0.00 1 0 17 1.022e-01 6.119e-03 1.412e-02 5.886e-04 5.063413e-01 3.082715e-04 5.655891e-03 -6.000000e+00 5.959111e-02 231.72 -2.00 3.45 -2.00 320.18 0.00e+00 2.493846e-03 8.982078e-05 3.019555e-04 -6.000000e+00 2.359892e-03 279.49 -2.00 20.00 -2.00 319.87 0.00e+00 4.052 0.001 302.00 328.00 3 4.2803e+00 8.7602e-04 4.2800e-02 -6.0000e+00 1.5061e-01 1.4917e-02 1.0509e-03 2.6384e-02 -6.0000e+00 1.6337e-01 -1.7046e-02 1.0275e-03 1.3686e-02 -6.0000e+00 9.5770e-02 2.3708e-03 5.4370e-04 4.2083e-03 -6.0000e+00 3.9757e-02 1.3807e-04 -3.5432e-04 1.7189e-05 4.6322e-05 -6.0000e+00 2.7863e-03 -3.3831e-02 9.1243e-05 10 0 0 10 0 0 17.74 18.40 0.21 -0.03383 -0.03649 815 178 1 5 0 60.400 21.27 15.00 18.40 20.87 14.9 843.79 -46285 -20705 -30265 -27741 -27881 -39564 -31870 -39412 -27902 -35582 -26272 -33758 -16547 -17637 -6155 -6501 -2023 -1067 -3149 17 -4046 -286 -5506 -1825 -6692 -3946 -8230 -4604 -7461 -4733 -4544 -2031 852 -3202 -3615 -5553 -3400 -4033 -576 -2024 -816 -983 -219 -254 624 1034 606 1191 -508 884 607 1410 1530 1908 981 1417 625 -259 -225 175 1039 1185 2562 2539 1481 478 621 -842 756 762 668 974 532 805 -284 -667 -1879 -2323 -2168 -1780 -1610 -993 -2200 -1628 -796 -486 503 537 1190 1041 1102 416 -358 -549 -426 -472 246 1142 440 166 -212 -797 -891 28 -1264 -1158 -801 -559 96 665 754 524 467 60 -392 -463 -219 -353 99 -99 15 503 706 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