File name: Pandora204s1_BoulderCO-NCAR_20240823_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20240824T071231.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20240823_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20240823 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240823T130021.8Z 9001.541919 218 1 49.33 2 83.45 80.92 47.64 242.37 0.00 1 0.00 1 0 17 7.131e-01 1.259e-02 3.102e-01 5.282e-03 8.549135e-01 2.968179e-03 8.878635e-03 -6.000000e+00 4.131233e-01 229.94 -2.00 3.45 -2.00 322.09 0.00e+00 7.810216e-03 1.343653e-03 1.227531e-03 -6.000000e+00 1.646765e-02 281.71 -2.00 20.00 -2.00 321.75 0.00e+00 7.969 0.009 302.00 328.00 3 4.1567e+00 9.9784e-03 8.0749e-02 -6.0000e+00 1.0397e+00 3.2951e-01 1.6329e-02 4.7688e-02 -6.0000e+00 1.1293e+00 -5.2578e-01 1.9975e-02 2.8158e-02 -6.0000e+00 6.6294e-01 2.2373e-01 9.3555e-03 9.9520e-03 -6.0000e+00 2.7618e-01 5.0664e-06 -1.2973e-03 1.5373e-04 1.2516e-04 -6.0000e+00 1.9437e-02 -3.3381e-02 7.5765e-05 12 8 8 10 0 0 0.42 18.41 0.25 -0.03338 -0.04313 171 37 1 5 0 288.400 21.27 15.00 18.41 20.86 15.6 805.91 -277300 -251065 -83027 -254349 -251298 -213544 -174625 -263626 -78718 -141392 -183372 -237472 -124140 -175699 -123879 -76513 -101522 68959 -41307 -19135 -51017 25755 -89307 41647 -77345 42827 -91358 -59493 -123637 -73140 -35563 -35447 24382 -13600 22294 -24072 36859 -43041 35248 -15379 37846 -1961 6728 13386 16918 15384 9760 33628 5473 28285 10411 10320 9276 24859 20621 19340 13589 9621 14210 12197 12070 5816 19875 8189 14470 7660 10659 2339 9857 5602 8001 8004 1836 5753 1088 3394 -2445 -3111 -4661 -300 -521 257 -1367 -352 -41 45 1732 1058 2230 92 1346 -1326 -1591 -3317 -2749 -3380 -548 -36 -181 -40 -316 -1133 -1749 -463 -2255 -1297 -1838 -833 -824 218 210 78 126 -349 -346 -1107 -320 -665 261 -117 962 861 1492 859 986 566 -305 928 210 53 -79 171 143 167 -160 -294 290 520 276 49 -72 -1073 -730 -3247 -2822 -428 -3335 -2942 -1600 -990 -3580 -406 -728 -1374 -3448 -831 -2468 -1392 -749 -1379 355 -426 -168 -573 146 -1464 215 -1268 243 -1840 -864 -3416 -1336 -605 -697 352 -293 368 -552 532 -1451 726 -576 957 -81 271 527 658 627 439 1260 292 1311 594 673 685 1729 1611 1602 1231 909 1244 1058 1062 594 2039 1100 2031 1181 1597 397 1705 1081 1699 1805 441 1258 227 670 -473 -614 -1053 -73 -153 88 -535 -147 -18 21 851 543 1140 47 639 -607 -707 -1547 -1440 -2114 -396 -30 -174 -40 -304 -993 -1371 -342 -1788 -1089 -1637 -791 -864 259 286 109 184 -509 -525 -1626 -465 -1009 415 -195 1581 1354 2220 1246 1382 773 -407 1255 325 96 -151 357 319 400 -412 -807 814 1475 789 137 -187 -2597 -1661 SS 20240823T131136.4Z 9001.549727 221 1 49.30 2 81.32 82.69 49.49 245.00 0.00 1 0.00 1 0 17 4.992e-01 7.408e-03 1.007e-01 1.843e-03 7.120837e-01 1.005112e-03 7.598401e-03 -6.000000e+00 2.892825e-01 229.94 -2.00 3.45 -2.00 321.50 0.00e+00 5.645005e-03 4.083367e-04 8.020411e-04 -6.000000e+00 1.153045e-02 281.71 -2.00 20.00 -2.00 321.16 0.00e+00 6.262 0.004 302.00 328.00 3 4.0583e+00 3.1262e-03 6.4306e-02 -6.0000e+00 7.2801e-01 5.3586e-02 4.6335e-03 3.8819e-02 -6.0000e+00 7.9075e-01 -1.0520e-01 5.6566e-03 2.2162e-02 -6.0000e+00 4.6418e-01 4.2380e-02 2.7540e-03 7.5497e-03 -6.0000e+00 1.9341e-01 2.4730e-05 -6.0633e-04 5.3922e-05 9.0579e-05 -6.0000e+00 1.3608e-02 -3.4024e-02 9.5250e-05 11 8 0 10 0 0 5.79 18.40 0.19 -0.03402 -0.03858 405 88 1 5 0 121.710 21.27 15.00 18.40 22.11 15.6 814.38 -208415 -125342 -180190 -139126 -162385 -135982 -209207 -126672 -152403 -149665 -127041 -129216 -77361 -110986 -51328 -83148 -21629 -54843 -13653 -52044 -1623 -35647 -30597 -20757 -28937 -24559 -38981 -21988 -40687 -14526 -34969 -4120 -10477 -4561 -15684 -18695 -14566 -8102 2317 -289 3280 -2987 3024 -688 4022 745 5386 798 3857 3289 3793 5590 5226 5810 3694 3954 1741 1328 -2383 997 506 3646 3711 5141 4050 2678 2715 1085 2311 2113 2316 1420 1866 22 -83 -1747 -1703 -3590 -3290 -1657 -1589 -322 -2097 -1199 -1254 -213 461 693 1263 1481 1037 43 -792 -1143 -1215 -1086 170 1198 770 -111 9 -1295 -681 -118 -1727 -1393 -1033 -803 57 700 624 643 265 100 -606 -545 -341 -363 6 -49 103 747 1204 475 670 -410 -441 201 237 -112 92 -279 -329 -34 -145 -168 100 723 277 82 6 -397 -549 -1498 -541 -1383 -800 -1109 -684 -2085 -683 -1205 -1264 -913 -1068 -487 -1197 -443 -1127 -206 -753 -152 -833 -18 -512 -430 -285 -468 -405 -770 -366 -817 -242 -857 -92 -300 -138 -530 -635 -507 -310 90 -14 177 -188 192 -48 272 54 386 63 312 288 368 604 584 708 495 554 259 200 -365 145 75 573 667 1046 911 616 615 256 587 621 766 504 663 8 -27 -509 -457 -977 -983 -579 -661 -154 -1136 -690 -769 -138 314 490 897 1024 678 26 -469 -688 -809 -841 152 1141 823 -123 10 -1263 -639 -106 -1680 -1443 -1123 -863 66 910 911 1018 432 159 -929 -796 -493 -545 10 -82 171 1192 1832 704 955 -570 -591 272 358 -193 177 -582 -725 -80 -339 -418 254 1863 721 209 15 -953 -1256 SS 20240823T134039.0Z 9001.569895 231 1 49.53 2 75.78 87.28 54.44 251.25 0.00 1 0.00 1 0 17 7.704e-02 6.114e-03 9.759e-03 4.565e-04 4.805773e-01 2.365955e-04 5.415143e-03 -6.000000e+00 4.464936e-02 229.94 -2.00 3.45 -2.00 320.04 0.00e+00 2.425169e-03 6.687815e-05 2.780928e-04 -6.000000e+00 1.779558e-03 281.71 -2.00 20.00 -2.00 319.73 0.00e+00 3.986 0.001 302.00 328.00 3 3.9023e+00 6.6651e-04 4.1402e-02 -6.0000e+00 1.1236e-01 -3.1822e-03 7.9224e-04 2.4874e-02 -6.0000e+00 1.2204e-01 -7.9870e-03 7.5414e-04 1.2942e-02 -6.0000e+00 7.1642e-02 2.4046e-04 4.0127e-04 3.9996e-03 -6.0000e+00 2.9855e-02 2.2088e-04 -3.5638e-04 1.3432e-05 4.4374e-05 -6.0000e+00 2.0999e-03 -3.4542e-02 1.1240e-04 10 0 0 10 0 0 4.02 18.39 0.23 -0.03454 -0.03722 1238 270 1 5 0 39.770 21.27 14.99 18.39 25.72 15.5 839.43 -27076 -22986 -19941 -19447 -24548 -25562 -29913 -22885 -25165 -19315 -29649 -20326 -18475 -16074 -8274 -6002 -3120 -1949 -97 26 169 -2070 -851 -2497 -3359 -3586 -5711 -5660 -7012 -4438 -2884 -1547 -401 -2113 -4306 -4192 -5241 -3121 -1367 -1059 -1218 -889 -378 -371 948 557 758 534 6 190 1377 1204 1406 1764 1123 1299 819 -362 -326 124 795 1482 2368 2771 1247 613 414 -788 651 754 517 977 502 558 -10 -721 -1488 -2465 -1977 -1818 -1576 -1289 -2143 -1541 -889 -456 424 574 1272 1052 932 476 -383 -496 -508 -463 208 1081 484 98 -140 -937 -735 -172 -1173 -1298 -817 -614 155 691 804 558 483 140 -365 -323 -292 -318 32 -91 -152 473 689 276 366 -223 -474 579 192 -106 -55 -367 -316 -114 -45 -69 212 654 273 -18 -51 -479 -422 -318 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