File name: Pandora204s1_BoulderCO-NCAR_20240909_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20240910T070436.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20240909_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20240909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240909T131613.3Z 9018.552932 57 1 48.61 2 83.33 89.07 151.57 64.05 0.00 1 0.00 1 0 25 5.478e-01 2.162e-02 3.964e-01 1.416e-02 8.883716e-01 8.581964e-03 9.258309e-03 -6.000000e+00 3.244840e-01 228.64 -2.00 3.45 -2.00 322.25 0.00e+00 8.875475e-03 3.891689e-03 1.315769e-03 -6.000000e+00 1.533069e-02 280.23 -2.00 20.00 -2.00 321.90 0.00e+00 7.860 0.008 302.00 328.00 3 5.8827e+00 2.8973e-02 8.0837e-02 -6.0000e+00 8.1739e-01 7.1057e-01 4.2554e-02 4.8377e-02 -6.0000e+00 8.9553e-01 -1.0662e+00 4.8179e-02 2.7906e-02 -6.0000e+00 5.2057e-01 4.4457e-01 2.3149e-02 9.8727e-03 -6.0000e+00 2.1682e-01 8.8878e-07 -1.4455e-03 4.4185e-04 1.3606e-04 -6.0000e+00 1.5498e-02 -3.2176e-02 6.8664e-05 12 8 8 10 0 0 31.16 18.39 0.60 -0.03218 -0.04304 36 8 1 5 0 1350.060 21.27 14.99 18.39 20.21 15.7 797.78 27942 900000 -46256 -50220 -202109 900000 -127761 -173145 -194370 900000 -202480 900000 8633 900000 30828 -103374 20503 -24578 900000 -10352 900000 -36683 900000 -92358 900000 -38690 900000 -117055 28100 165231 -52215 900000 -68617 900000 -6343 900000 58943 900000 31950 161738 49745 47458 51912 17813 900000 15843 192046 49781 78807 36507 99927 18890 57610 24711 55679 18762 9112 50650 -1762 73961 8693 25710 789 47021 11415 23421 13842 21366 12748 8471 11224 4733 14779 5526 21386 208 30660 -8525 10945 -7939 -4600 1207 4073 249 -3365 1686 -914 6651 -4159 3249 -2980 99 -4490 -2364 -2292 -3400 -3136 -2476 1343 -2960 1634 -1460 272 -2911 -1160 -3764 -2229 -1641 -3972 568 -35 933 -1569 1106 -1367 -376 -2641 1386 -1765 1500 325 1970 998 2183 2473 -420 1242 1537 1955 -284 1178 -674 1114 -1179 -264 534 226 1005 -253 552 -911 -791 -1442 385 900000 -637 -691 -5565 900000 -1759 -3129 -4515 900000 -5227 900000 119 900000 424 -2935 282 -429 900000 -171 900000 -741 900000 -3020 900000 -817 900000 -4834 387 2275 -1534 900000 -3306 900000 -186 900000 866 900000 821 2227 1415 1481 1620 801 900000 742 2644 1782 2242 1709 2751 1318 3014 1829 3424 1614 878 3393 -179 3598 763 2194 93 4315 1552 2882 1870 2776 1974 1574 2269 1075 3014 1160 3459 37 3693 -1540 1836 -1954 -1322 383 1332 91 -1352 684 -400 2795 -1957 1381 -1269 39 -1877 -1003 -1038 -1853 -2034 -1879 1113 -2675 1353 -1125 182 -1919 -790 -2811 -1731 -1366 -3757 591 -42 1234 -2226 1526 -1872 -491 -3525 1853 -2579 2214 481 2738 1331 2788 3052 -519 1463 1859 2688 -468 2178 -1395 2427 -2818 -673 1432 624 2787 -711 1485 -2313 -1849 -3187 SS 20240909T132747.8Z 9018.560970 60 1 49.27 2 81.12 90.94 149.66 67.43 0.00 1 0.00 1 0 25 5.676e-01 1.052e-02 2.033e-01 3.885e-03 7.386062e-01 2.128670e-03 7.847550e-03 -6.000000e+00 3.288005e-01 228.64 -2.00 3.45 -2.00 321.62 0.00e+00 6.067737e-03 8.864411e-04 8.614148e-04 -6.000000e+00 1.342664e-02 280.23 -2.00 20.00 -2.00 321.30 0.00e+00 6.139 0.004 302.00 328.00 3 5.4931e+00 6.7377e-03 6.4140e-02 -6.0000e+00 8.2624e-01 9.2887e-02 1.0189e-02 3.9982e-02 -6.0000e+00 8.9885e-01 -2.1030e-01 1.2460e-02 2.3027e-02 -6.0000e+00 5.2622e-01 9.1378e-02 6.0406e-03 7.9345e-03 -6.0000e+00 2.1957e-01 6.3771e-06 -7.4451e-04 1.1388e-04 9.8411e-05 -6.0000e+00 1.5818e-02 -3.3536e-02 1.0796e-04 12 8 8 10 0 0 11.51 18.38 0.35 -0.03354 -0.03913 122 27 1 5 0 403.770 21.27 15.00 18.38 20.99 15.6 802.33 -251365 -185739 -3450 -218366 900000 -227357 19035 -221697 900000 -201534 -138947 -196713 -131560 -137228 -95954 -17053 -88038 -1867 -73032 -672 -81439 55913 -51860 8944 -67608 -25020 29238 -26616 -17865 -45289 10459 -28082 29367 -4801 29700 -27751 -15617 -20411 9822 4414 4607 4455 -3914 9101 2035 17637 -210 15729 2934 16235 421 13035 9640 13641 5727 7943 5766 4385 7755 -515 3987 -481 10031 4871 5420 4993 3354 1700 2261 1835 1749 3251 765 3264 120 420 -3663 -2811 -2242 -1053 -1156 -1544 -976 -2582 -144 -2018 1643 -143 1330 404 1403 674 -1710 -1886 -942 -1487 -368 1146 1 621 -432 -693 -1445 -74 -2272 -1904 -878 -1256 -270 110 678 461 695 -310 -215 -1224 -160 -364 114 -137 278 1056 1200 1241 198 191 -785 959 -214 283 -37 110 -124 -141 -31 -347 72 708 362 -154 32 -776 -530 -2943 -1407 -13 -2631 900000 -2662 72 -2824 900000 -2567 -1005 -2845 -1268 -1890 -1156 -117 -1455 -15 -1308 -6 -1767 339 -857 86 -1513 -388 272 -431 -265 -951 151 -744 526 -136 593 -955 -505 -808 352 185 222 236 -241 514 127 969 -14 958 216 1127 38 1181 1007 1503 734 1043 801 621 1038 -73 551 -76 1630 959 1165 1091 736 389 518 488 524 1019 247 979 34 116 -969 -736 -645 -330 -433 -674 -475 -1368 -79 -1210 1004 -93 854 255 826 374 -929 -1042 -572 -1061 -305 1085 1 686 -461 -671 -1263 -62 -2045 -1824 -876 -1346 -314 144 992 735 1136 -503 -334 -1827 -234 -555 183 -232 468 1698 1842 1843 287 267 -1069 1304 -329 497 -68 218 -261 -315 -74 -885 188 1865 959 -398 79 -1771 -1144 SS 20240909T135540.0Z 9018.580324 70 1 49.31 2 75.80 95.49 144.89 74.44 0.00 1 0.00 1 0 17 9.790e-02 6.069e-03 1.999e-02 7.791e-04 5.052495e-01 4.037803e-04 5.670059e-03 -6.000000e+00 5.645883e-02 228.64 -2.00 3.45 -2.00 320.24 0.00e+00 2.509611e-03 1.211718e-04 3.195988e-04 -6.000000e+00 2.261235e-03 280.23 -2.00 20.00 -2.00 319.94 0.00e+00 3.990 0.001 302.00 328.00 3 4.8656e+00 1.1460e-03 4.2114e-02 -6.0000e+00 1.4165e-01 -2.0286e-02 1.3868e-03 2.6073e-02 -6.0000e+00 1.5401e-01 -1.0344e-02 1.3845e-03 1.3749e-02 -6.0000e+00 9.0494e-02 1.1498e-03 7.3303e-04 4.3179e-03 -6.0000e+00 3.7806e-02 8.2644e-05 -3.6290e-04 2.2878e-05 4.8542e-05 -6.0000e+00 2.6678e-03 -3.3606e-02 1.0270e-04 10 0 0 10 0 0 10.20 18.39 0.22 -0.03361 -0.03633 544 119 1 5 0 90.620 21.27 15.00 18.39 24.58 15.7 827.59 -31405 -22644 -24945 -28305 -18686 -39067 -32437 -45270 -19355 -29398 -29907 -35679 -20922 -21645 -11329 -10713 -4029 -3632 -5992 -449 -4535 -1253 -2969 -1203 -5362 -4044 -7684 -6008 -7389 -8712 -2269 -3300 26 -3801 -3867 -5200 -5376 -3927 -693 -1225 -1125 -924 -353 -119 359 999 167 1210 -474 1182 1327 1414 1711 2086 1046 1214 838 -363 190 -272 1172 1324 2722 2791 1319 735 553 -572 717 766 576 1014 393 750 -361 -731 -1547 -2617 -2130 -1979 -1902 -1015 -2125 -1712 -855 -415 522 538 1294 1001 995 493 -299 -424 -504 -418 112 1124 360 240 -230 -763 -805 -135 -1294 -1257 -658 -518 171 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