File name: Pandora204s1_BoulderCO-NCAR_20240911_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20240912T070252.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20240911_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20240911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240911T131829.3Z 9020.554506 57 1 49.65 2 83.25 90.14 168.16 15.19 0.00 1 0.00 1 0 25 6.416e-01 1.235e-02 4.184e-01 9.725e-03 8.495693e-01 5.757781e-03 8.752912e-03 -6.000000e+00 3.743402e-01 228.49 -2.00 3.45 -2.00 322.17 0.00e+00 6.776480e-03 2.630285e-03 1.282705e-03 -6.000000e+00 1.759814e-02 280.06 -2.00 20.00 -2.00 321.82 0.00e+00 7.781 0.008 302.00 328.00 3 5.4528e+00 1.9394e-02 7.9140e-02 -6.0000e+00 9.3866e-01 1.9181e-01 3.3216e-02 4.7817e-02 -6.0000e+00 1.0238e+00 -3.4886e-01 4.1839e-02 2.9177e-02 -6.0000e+00 6.0106e-01 1.4753e-01 1.9443e-02 1.0560e-02 -6.0000e+00 2.5877e-01 1.6810e-06 -6.8568e-04 3.0077e-04 1.3013e-04 -6.0000e+00 1.8356e-02 -3.2986e-02 1.0689e-04 12 8 8 10 0 0 86.70 18.40 0.38 -0.03299 -0.03814 65 14 1 5 0 763.640 21.27 15.00 18.40 21.42 15.7 804.57 900000 900000 -253402 900000 900000 900000 -296080 -98689 -282100 -249467 900000 -259996 -71473 -107973 900000 -144556 -119500 -130733 900000 -72132 900000 41314 -157958 -18424 900000 -45284 -50099 -111499 -49255 900000 -60913 -7415 26734 976 -3945 62568 -663 50636 -1668 50156 29140 -33784 24759 -10191 32170 11842 14376 -145 -17729 1178 19383 31595 11222 12873 -13917 17170 12 11713 -2078 17916 37064 8266 458 17180 6688 6793 2023 -290 18252 2431 4243 1562 1167 1117 -3432 5674 2149 665 -1373 1535 716 3626 -1350 1534 -74 202 2133 3771 469 869 1251 -476 -1025 -6031 807 -3657 148 -251 348 215 497 -1612 -2082 -360 -758 -4480 -2165 296 -1375 570 450 66 -621 -626 -634 -585 337 -613 653 197 686 1661 1220 1053 874 -529 -341 1442 -35 143 743 -565 -506 -488 32 142 -315 934 257 454 -302 -640 -831 900000 900000 -2398 900000 900000 900000 -2802 -934 -2875 -2361 900000 -2839 -676 -1022 900000 -1710 -1319 -1713 900000 -683 900000 391 -3450 -174 900000 -429 -514 -2110 -505 900000 -961 -88 274 15 -62 592 -10 559 -38 831 689 -1525 722 -408 939 405 502 -6 -981 59 917 1518 743 928 -1317 1350 1 1015 -201 1383 2401 782 50 1870 900 937 294 -45 2603 472 912 366 275 250 -733 989 360 115 -274 361 205 1184 -523 581 -30 88 965 1741 226 406 588 -214 -449 -2874 380 -2132 99 -197 307 198 437 -1304 -1505 -245 -547 -3584 -1787 256 -1341 625 565 92 -903 -904 -883 -783 445 -853 950 301 1033 2368 1663 1393 1120 -668 -416 1778 -50 237 1388 -1171 -1120 -1156 82 383 -876 2598 722 1230 -772 -1519 -1869 SS 20240911T133022.9Z 9020.562765 60 1 49.21 2 80.98 92.06 167.40 26.36 0.00 1 0.00 1 0 17 5.106e-01 1.040e-02 3.370e-01 6.415e-03 6.969648e-01 3.498364e-03 7.437189e-03 -6.000000e+00 2.942151e-01 228.49 -2.00 3.45 -2.00 321.55 0.00e+00 5.902267e-03 1.432899e-03 7.833104e-04 -6.000000e+00 1.187784e-02 280.06 -2.00 20.00 -2.00 321.22 0.00e+00 6.053 0.004 302.00 328.00 3 6.3723e+00 1.0898e-02 6.2140e-02 -6.0000e+00 7.3788e-01 2.7202e-02 1.6205e-02 3.7678e-02 -6.0000e+00 8.0248e-01 -9.1432e-02 1.9786e-02 2.1658e-02 -6.0000e+00 4.7191e-01 3.8316e-02 9.6386e-03 7.4387e-03 -6.0000e+00 1.9843e-01 2.9717e-06 -7.1201e-04 1.9073e-04 8.8553e-05 -6.0000e+00 1.3930e-02 -3.2307e-02 6.0404e-05 12 8 8 10 0 0 99.43 18.40 0.18 -0.03231 -0.03766 65 14 1 5 0 756.970 21.27 15.00 18.40 21.98 15.6 808.02 -262536 900000 -224888 128398 -176990 -12938 -230873 -27517 -146048 -134094 -75077 -111274 -73887 -122624 -75103 -58537 18519 -68747 49475 58130 -9428 -27074 11750 13308 17131 -20474 -29782 -21575 -72714 87678 -47880 82756 8872 13976 26337 29627 -40963 25502 11039 -6892 7247 -7875 14004 -15716 26086 15422 23324 -11838 11602 -6156 5363 3610 4364 9362 -4389 4545 -1045 5901 -483 8317 3685 6805 1584 10240 5369 1194 5380 -1712 6025 -1593 3634 -817 3118 -1036 4739 -179 639 -3996 -2685 -1293 -2178 -12 -3899 -280 -1740 384 -370 2022 395 737 627 -340 -569 -2206 -399 -1936 1341 814 1011 -818 542 -903 -634 -1598 -1915 -1352 -1462 -49 -657 1081 598 825 -167 -35 -408 229 -583 -444 -656 -261 556 633 1688 -290 982 -577 -483 483 302 333 56 14 85 -39 -393 -23 -236 876 8 125 -85 -194 -744 -3522 900000 -2948 803 -1462 -81 -3126 -172 -1145 -1026 -470 -819 -485 -1640 -842 -696 127 -1166 318 370 -116 -393 124 148 198 -351 -572 -386 -2052 630 -1362 894 217 362 612 655 -1796 715 423 -367 388 -526 816 -1251 1463 982 1433 -1043 871 -582 503 386 512 1144 -652 650 -163 869 -74 1159 548 1066 296 2008 1198 279 1193 -415 1474 -480 1166 -290 1072 -356 1426 -51 167 -1093 -794 -445 -892 -5 -2076 -154 -1031 237 -244 1351 271 492 396 -204 -326 -1298 -254 -1445 1124 788 1084 -920 577 -889 -563 -1395 -1774 -1328 -1508 -53 -778 1405 869 1286 -268 -55 -617 330 -839 -661 -1034 -429 912 1005 2555 -435 1403 -810 -655 660 457 571 107 28 182 -88 -945 -58 -616 2293 20 322 -208 -451 -1665 SS 20240911T135515.3Z 9020.580039 70 1 49.26 2 76.23 96.14 164.76 45.06 0.00 1 0.00 1 0 17 9.326e-02 6.026e-03 1.725e-02 7.136e-04 4.977160e-01 3.676495e-04 5.577620e-03 -6.000000e+00 5.375282e-02 228.48 -2.00 3.45 -2.00 320.20 0.00e+00 2.597515e-03 1.092247e-04 3.041535e-04 -6.000000e+00 2.154020e-03 280.06 -2.00 20.00 -2.00 319.88 0.00e+00 4.108 0.001 302.00 328.00 3 4.6208e+00 1.0371e-03 4.2549e-02 -6.0000e+00 1.3481e-01 -7.6036e-03 1.2527e-03 2.5593e-02 -6.0000e+00 1.4659e-01 -1.0545e-02 1.2415e-03 1.3464e-02 -6.0000e+00 8.6144e-02 4.1542e-04 6.5783e-04 4.2144e-03 -6.0000e+00 3.6002e-02 9.6757e-05 -3.8626e-04 2.0957e-05 4.6629e-05 -6.0000e+00 2.5411e-03 -3.3741e-02 1.1132e-04 10 0 0 10 0 0 38.06 18.40 0.22 -0.03374 -0.03664 615 134 1 5 0 80.070 21.27 15.00 18.40 22.19 15.7 810.48 -34087 -25659 -22143 -22049 -34025 -34259 -40699 -29823 -31430 -24737 -30542 -20222 -21604 -13630 -9712 -4280 -4599 -3268 -2386 -2993 -1686 -4305 429 -5251 -2136 -4493 -5020 -6827 -6008 -5401 -4261 -2256 -1434 -3445 -5479 -3692 -4056 -2281 -511 -434 -1586 -620 -343 -446 948 417 931 677 74 322 1561 1207 1960 1720 1159 1372 514 -355 -210 29 472 1544 2293 2568 1331 903 425 -535 682 871 587 746 236 545 -236 -912 -1459 -2646 -1876 -1998 -1576 -1190 -2113 -1687 -876 -398 464 716 1230 1191 1101 573 -347 -435 -508 -473 276 1102 466 -9 -138 -853 -817 -182 -1223 -1231 -692 -496 196 633 754 561 465 70 -406 -275 -295 -280 -24 -101 -137 525 694 324 319 -314 -543 645 68 -160 -44 -342 -242 -107 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