File name: Pandora204s1_BoulderCO-NCAR_20240916_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20240917T070129.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20240916_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20240916 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240916T132218.8Z 9025.557162 186 1 49.14 2 83.41 92.52 119.27 276.26 0.00 1 0.00 1 0 17 6.290e-01 1.249e-02 3.051e-01 5.384e-03 8.219992e-01 3.009870e-03 8.524399e-03 -6.000000e+00 3.643157e-01 228.05 -2.00 3.45 -2.00 322.02 0.00e+00 9.892965e-03 1.348453e-03 1.151096e-03 -6.000000e+00 1.479856e-02 279.53 -2.00 20.00 -2.00 321.69 0.00e+00 7.939 0.009 302.00 328.00 3 4.3096e+00 9.9135e-03 7.8980e-02 -6.0000e+00 9.1370e-01 2.8476e-01 1.6173e-02 4.5184e-02 -6.0000e+00 9.9526e-01 -4.6307e-01 1.9956e-02 2.6853e-02 -6.0000e+00 5.8478e-01 2.0113e-01 9.4033e-03 9.5839e-03 -6.0000e+00 2.4366e-01 4.6691e-06 -1.1195e-03 1.5737e-04 1.1156e-04 -6.0000e+00 1.7415e-02 -3.2866e-02 8.8754e-05 12 8 8 10 0 0 10.84 18.40 0.29 -0.03287 -0.04128 151 33 1 5 0 325.350 21.27 15.00 18.40 18.44 15.6 784.29 -157334 -166507 -24970 -285188 900000 -250853 -38150 -129336 -246419 -262853 -207267 -130546 -181474 -107960 -137260 -24646 1540 900000 -99015 22344 -73017 -71130 -67602 -52372 -50790 -60310 -41188 -105134 52 -41285 -9604 -24677 -7907 -40857 21928 -20383 -4909 9371 -6826 32107 -2307 35383 6346 46789 5490 16582 15789 7931 3091 17340 19703 12897 18342 6440 17464 5621 20416 11110 18143 4888 3753 7800 11186 7451 10029 8176 7774 8036 2398 6946 5587 5958 3737 3762 1218 1161 882 -10979 -1758 -4459 86 -801 -1186 -1000 -682 -496 1810 220 1373 2114 385 281 -3159 -2478 -3106 -1802 -1187 1050 321 188 -694 -717 -995 -1713 -2029 -2047 -1650 -1440 348 233 578 25 337 -533 -809 -724 -666 -266 64 530 88 1371 1483 1241 379 473 -526 1153 -113 -90 428 -200 -30 32 -164 -458 421 564 497 -147 34 -719 -986 -826 -874 -131 -5115 900000 -2993 -200 -679 -3292 -4390 -2077 -685 -2078 -824 -1899 -141 9 900000 -1795 141 -1115 -1052 -968 -675 -679 -921 -531 -2559 0 -591 -124 -471 -155 -1248 356 -486 -105 201 -208 797 -92 1064 273 1407 257 720 723 382 168 887 1103 880 1324 575 1497 566 1822 1089 1611 483 382 836 1341 1079 1571 1334 1272 1360 435 1391 1277 1439 924 881 267 228 174 -2279 -374 -1181 26 -288 -483 -437 -316 -245 923 118 737 1100 192 132 -1478 -1185 -1683 -1141 -887 900 313 192 -684 -638 -791 -1313 -1646 -1775 -1504 -1408 369 283 797 36 493 -781 -1145 -1060 -969 -402 95 817 136 2156 2222 1804 538 651 -708 1564 -176 -164 810 -417 -67 76 -418 -1242 1163 1579 1396 -403 86 -1720 -2234 SS 20240916T133335.3Z 9025.564991 189 1 49.31 2 81.26 94.36 121.29 278.20 0.00 1 0.00 1 0 17 4.401e-01 7.441e-03 9.022e-02 1.795e-03 6.811856e-01 9.680594e-04 7.304821e-03 -6.000000e+00 2.532390e-01 228.05 -2.00 3.45 -2.00 321.40 0.00e+00 5.371312e-03 3.845447e-04 7.413514e-04 -6.000000e+00 1.016455e-02 279.53 -2.00 20.00 -2.00 321.07 0.00e+00 6.227 0.004 302.00 328.00 3 4.1219e+00 2.9819e-03 6.2707e-02 -6.0000e+00 6.3446e-01 6.0119e-02 4.3033e-03 3.6660e-02 -6.0000e+00 6.9013e-01 -1.1010e-01 5.1854e-03 2.0895e-02 -6.0000e+00 4.0570e-01 4.5382e-02 2.5544e-03 7.1377e-03 -6.0000e+00 1.6970e-01 2.4897e-05 -5.3662e-04 5.2670e-05 8.5487e-05 -6.0000e+00 1.1990e-02 -3.3325e-02 1.1237e-04 11 8 0 10 0 0 2.88 18.39 0.20 -0.03332 -0.03736 389 85 1 5 0 126.720 21.27 15.00 18.39 19.63 15.6 791.68 -146669 -112908 -126714 -69322 -196698 -135743 -151727 -153747 -146621 -128754 -126411 -117182 -103700 -74941 -68134 -46026 -23412 -45103 -17580 -38171 -21482 -38279 -16191 -31924 -15358 -32918 -28816 -31355 -22374 -23776 -26973 -188 -8873 7435 -16870 -3621 -15229 -348 -2947 3290 -457 787 3249 1943 6904 405 5605 -2659 2998 125 5029 3970 5340 5591 3448 4264 3277 2021 -1927 2028 -226 4033 2789 5718 1899 2715 2031 220 2108 1127 2705 722 2045 -69 815 -1709 -1632 -4149 -2315 -1738 -1339 -718 -2127 -1301 -1252 -317 -127 1242 1235 1488 962 189 -1445 -1027 -1205 -961 75 768 871 388 103 -1351 -914 -461 -1348 -1491 -1098 -782 108 723 644 536 382 71 -626 -435 -454 -274 -105 -60 82 839 1121 266 471 -340 -358 552 167 -195 54 -286 -286 -113 -224 14 126 669 244 21 -33 -398 -573 -817 -557 -807 -279 -2411 -864 -1183 -1370 -1377 -1107 -1127 -1063 -1040 -751 -835 -564 -268 -725 -238 -680 -338 -719 -250 -620 -274 -744 -647 -719 -467 -537 -747 -5 -276 219 -633 -116 -582 -13 -143 181 -30 56 241 153 530 34 465 -231 259 12 506 456 672 769 520 667 536 337 -328 325 -38 704 563 1281 481 685 506 57 582 362 963 279 783 -26 279 -538 -473 -1223 -734 -649 -591 -364 -1220 -792 -812 -202 -85 858 861 1010 665 123 -908 -648 -839 -719 65 760 961 443 112 -1361 -825 -402 -1259 -1490 -1150 -871 129 968 967 870 634 115 -976 -644 -665 -417 -169 -101 138 1365 1743 404 687 -481 -489 757 255 -341 105 -600 -591 -246 -524 34 320 1723 635 52 -79 -895 -1230 SS 20240916T140219.9Z 9025.584953 199 1 49.80 2 75.80 99.12 126.36 283.42 0.00 1 0.00 1 0 17 6.508e-02 6.165e-03 8.534e-03 4.534e-04 4.619440e-01 2.328376e-04 5.239721e-03 -6.000000e+00 3.744573e-02 228.05 -2.00 3.45 -2.00 319.91 0.00e+00 2.296305e-03 6.382352e-05 2.542017e-04 -6.000000e+00 1.503003e-03 279.53 -2.00 20.00 -2.00 319.60 0.00e+00 3.991 0.001 302.00 328.00 3 3.9339e+00 6.5119e-04 4.0607e-02 -6.0000e+00 9.3816e-02 3.3868e-04 7.6804e-04 2.3674e-02 -6.0000e+00 1.0205e-01 -8.0425e-03 7.1088e-04 1.2311e-02 -6.0000e+00 5.9989e-02 2.3672e-04 3.8016e-04 3.8081e-03 -6.0000e+00 2.5093e-02 2.2023e-04 -3.4929e-04 1.3344e-05 4.2401e-05 -6.0000e+00 1.7730e-03 -3.3609e-02 1.0445e-04 10 0 0 10 0 0 19.52 18.39 0.23 -0.03361 -0.03623 1211 264 1 5 0 40.650 21.27 15.00 18.39 22.99 15.6 815.34 -20524 -17256 -12427 -22126 -16781 -27929 -22041 -27147 -18094 -21354 -17814 -16098 -16209 -9811 -7114 -3802 -4377 1055 -2715 991 -1908 -19 -1236 -1346 -2507 -2979 -4058 -5739 -5627 -5484 -1914 -2404 914 -2928 -3622 -4290 -4469 -3116 -1545 -1369 -1405 -562 -737 -11 272 1001 186 884 -337 770 1292 1134 1490 1736 1171 1197 895 -485 -69 10 1007 1311 2445 2533 1318 572 371 -699 558 812 427 1056 341 764 -243 -700 -1388 -2316 -1836 -1791 -1465 -1215 -2169 -1659 -784 -671 474 543 1175 975 912 519 -449 -437 -503 -338 171 1140 385 101 -283 -893 -731 -57 -1219 -1265 -800 -650 153 708 813 510 519 118 -344 -363 -246 -299 90 -79 -119 549 665 340 316 -207 -535 638 89 -124 -71 -381 -321 -36 -15 -120 179 645 316 -56 -5 -508 -425 -274 -264 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