File name: Pandora204s1_BoulderCO-NCAR_20241027_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20241028T064946.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20241027_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20241027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241027T140459.6Z 9066.586801 200 1 49.37 2 83.68 112.97 36.38 142.82 0.00 1 0.00 1 0 25 5.699e-01 1.309e-02 2.932e-01 6.068e-03 7.491813e-01 3.395565e-03 7.933314e-03 -6.000000e+00 3.257172e-01 224.11 -2.00 3.45 -2.00 321.91 0.00e+00 8.717790e-03 1.498867e-03 1.009393e-03 -6.000000e+00 1.383259e-02 274.08 -2.00 20.00 -2.00 321.56 0.00e+00 8.224 0.010 302.00 328.00 3 4.4239e+00 1.1083e-02 7.8205e-02 -6.0000e+00 8.1129e-01 2.1708e-01 1.6919e-02 4.0428e-02 -6.0000e+00 8.8601e-01 -3.4491e-01 2.0490e-02 2.3678e-02 -6.0000e+00 5.1942e-01 1.4948e-01 9.8103e-03 8.4257e-03 -6.0000e+00 2.2049e-01 3.7818e-06 -1.1589e-03 1.8624e-04 1.0808e-04 -6.0000e+00 1.5918e-02 -3.2128e-02 8.4908e-05 12 8 8 10 0 0 65.80 18.38 0.29 -0.03213 -0.04084 128 28 1 5 0 385.610 21.27 15.00 18.38 11.84 15.4 746.04 -127983 900000 -229610 900000 -262091 -51757 -285452 900000 -212309 900000 -177744 -161069 -110404 -132987 -6075 -118534 59081 -128972 36395 -84007 -14156 -37279 1999 -92354 66109 11761 -46383 8426 -57758 -10121 -42673 20582 -22932 2768 -17787 42672 18258 -1637 10533 20706 5926 13669 26234 -3236 19929 -375 21329 -3123 28767 13918 23861 11923 17366 9646 6859 13674 3115 11137 -6023 17133 -2434 10013 7080 17639 8674 9400 10872 4986 8376 2516 6731 2370 6281 -157 1715 -1188 1248 -4680 419 -1247 -860 2998 -3144 -728 -2486 383 -983 883 -1439 2093 1862 -408 -1063 -2959 -59 -3424 207 -843 179 -157 881 -1656 -1270 -911 -2113 -1553 -1145 -601 -916 272 34 794 -267 -489 -1131 -459 96 -535 -57 119 1135 723 1686 814 1417 77 -58 325 401 215 39 68 30 83 -150 -124 45 752 -57 193 -142 -517 -1049 -757 900000 -3055 900000 -4521 -306 -5908 900000 -2739 900000 -1816 -1559 -831 -1716 -36 -2230 349 -3305 215 -1761 -152 -501 18 -2284 391 114 -823 86 -1149 -136 -964 310 -641 67 -526 665 383 -48 334 712 248 579 1047 -182 913 -22 1041 -205 1460 885 1529 975 1498 984 771 1496 360 1290 -745 1782 -290 1248 966 2503 1484 1621 1830 916 1623 596 1721 672 1717 -43 428 -274 259 -1037 98 -357 -294 1147 -1435 -348 -1288 206 -567 520 -876 1201 1010 -212 -534 -1545 -33 -2355 151 -722 171 -156 830 -1448 -1066 -734 -1826 -1427 -1027 -576 -966 322 45 1156 -405 -734 -1635 -631 131 -761 -86 187 1770 1090 2410 1138 1905 102 -75 455 587 363 74 140 65 195 -377 -331 123 2080 -160 524 -363 -1239 -2399 SS 20241027T141636.5Z 9066.594867 203 1 49.24 2 81.65 114.96 35.16 147.18 0.00 1 0.00 1 0 17 3.097e-01 7.007e-03 1.348e-01 2.773e-03 6.196829e-01 1.467371e-03 6.721676e-03 -6.000000e+00 1.756304e-01 224.11 -2.00 3.45 -2.00 321.23 0.00e+00 4.011166e-03 5.701802e-04 6.338285e-04 -6.000000e+00 7.174463e-03 274.08 -2.00 20.00 -2.00 320.90 0.00e+00 6.488 0.005 302.00 328.00 3 4.8950e+00 4.4389e-03 6.2005e-02 -6.0000e+00 4.3612e-01 3.6226e-02 6.1740e-03 3.2587e-02 -6.0000e+00 4.7598e-01 -5.5736e-02 7.3048e-03 1.8397e-02 -6.0000e+00 2.8046e-01 1.8979e-02 3.6508e-03 6.2725e-03 -6.0000e+00 1.1913e-01 1.0443e-05 -4.2802e-04 8.2882e-05 7.5575e-05 -6.0000e+00 8.4956e-03 -3.2928e-02 1.0079e-04 11 8 0 10 0 0 95.81 18.37 0.24 -0.03293 -0.03614 152 33 1 5 0 323.900 21.27 15.00 18.37 12.59 15.2 748.77 900000 -160577 -48029 -92810 -53351 -140802 -113034 -97673 -91129 -53026 -93208 -59562 -98466 -20595 -69168 -27560 -32244 -16523 -37173 -19693 -14112 -16997 -16696 -34562 -8809 -20559 -17177 -27732 -12674 -34968 -4240 -4831 -10889 -4458 -8801 298 -11770 4463 -251 4127 -5671 2692 -1607 2245 2107 5049 -285 3706 2766 880 7003 666 5638 3105 4526 197 2912 -2247 1308 1307 1127 3174 2803 5511 846 1900 -243 768 524 1216 945 1727 346 1381 45 -750 -1086 -3101 -846 -2954 -369 -1499 -2162 -1497 -738 -936 888 437 1412 661 607 671 -1048 -454 -1282 -681 32 1522 376 283 13 -889 -555 -574 -790 -1741 -758 -851 67 551 758 566 408 -88 -511 -516 -846 -167 304 -23 19 721 852 710 300 -409 -574 236 354 -291 243 -536 -148 -312 -158 -128 246 713 313 55 89 -451 -565 900000 -1855 -201 -616 -223 -1350 -861 -720 -717 -313 -871 -439 -1331 -167 -1173 -379 -539 -264 -737 -382 -271 -338 -341 -833 -195 -500 -418 -743 -315 -1048 -109 -151 -427 -182 -373 11 -533 201 -15 277 -446 213 -141 197 190 454 -28 359 283 98 804 92 816 503 774 37 548 -449 247 242 214 641 645 1402 244 540 -69 218 161 426 373 720 147 558 17 -258 -343 -987 -286 -1199 -172 -814 -1313 -965 -504 -636 627 323 1041 479 446 459 -691 -298 -928 -565 29 1527 423 328 15 -903 -508 -514 -754 -1794 -814 -975 83 753 1149 923 676 -143 -788 -755 -1227 -249 480 -38 32 1172 1331 1075 439 -581 -786 323 537 -504 462 -1101 -318 -661 -358 -308 606 1780 790 136 208 -997 -1280 SS 20241027T144821.6Z 9066.616917 213 1 49.70 2 76.28 120.63 32.62 160.29 0.00 1 0.00 1 0 25 4.408e-02 6.154e-03 6.389e-03 4.357e-04 4.237962e-01 2.204229e-04 4.881243e-03 -6.000000e+00 2.499210e-02 224.11 -2.00 3.45 -2.00 319.67 0.00e+00 1.984366e-03 5.684018e-05 2.130517e-04 -6.000000e+00 1.018007e-03 274.08 -2.00 20.00 -2.00 319.37 0.00e+00 4.122 0.001 302.00 328.00 3 3.8559e+00 6.0778e-04 3.9931e-02 -6.0000e+00 6.2058e-02 8.0991e-03 7.0917e-04 2.1361e-02 -6.0000e+00 6.7696e-02 -5.3032e-03 6.2640e-04 1.1104e-02 -6.0000e+00 3.9911e-02 -2.3047e-03 3.3819e-04 3.4489e-03 -6.0000e+00 1.6830e-02 2.3089e-04 -3.9192e-04 1.2831e-05 3.8558e-05 -6.0000e+00 1.1999e-03 -3.3162e-02 9.1753e-05 10 0 0 10 0 0 68.29 18.38 0.23 -0.03316 -0.03611 1239 270 1 5 0 39.750 21.27 15.00 18.38 16.41 15.5 778.70 -11612 -9540 -9303 -13188 -12882 -23415 -11498 -15547 -9744 -13689 -13567 -14244 -9624 -7253 -3126 -1967 -2681 331 -821 1647 -911 894 -1030 -420 -2967 -2233 -4196 -4103 -4355 -4574 -1012 -1581 1535 -2582 -3070 -4222 -3410 -3114 -936 -921 -1236 -686 -383 -407 110 552 -28 618 -351 531 1184 1014 1285 1532 1119 1123 687 -328 -19 -85 1045 1387 2521 2529 1129 441 233 -797 608 668 403 985 285 852 -82 -552 -1391 -2271 -1663 -1756 -1526 -1301 -2145 -1644 -843 -562 436 544 1166 858 860 369 -507 -382 -478 -368 311 1189 350 85 -261 -844 -757 -122 -1239 -1161 -771 -659 186 709 800 473 491 124 -269 -320 -244 -309 115 -78 -154 507 558 346 339 -216 -544 685 89 -102 -127 -407 -317 -76 -33 -66 259 602 312 -65 22 -521 -452 -204 -192 -201 -293 -262 -497 -225 -355 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