File name: Pandora252s1_BoulderCO-NCAR_20250508_L2Fit_fout2c3d20230118p1-8.txt File generation date: 20250731T080638.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 252 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora252_OF_v2d20221123.txt Instrument calibration file used: Pandora252s1_CF_v3d20230118.txt Level 1 file used: Pandora252s1_BoulderCO-NCAR_20250508_L1_smca1c3d20230118p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20250508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Updated OoB with correct parameters based on session 2 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0965 305.2374 305.3783 305.5193 305.6602 305.8010 305.9419 306.0828 306.2237 306.3645 306.5053 306.6462 306.7870 306.9278 307.0686 307.2094 307.3501 307.4909 307.6316 307.7724 307.9131 308.0538 308.1945 308.3352 308.4759 308.6166 308.7572 308.8979 309.0385 309.1792 309.3198 309.4604 309.6010 309.7416 309.8821 310.0227 310.1633 310.3038 310.4443 310.5848 310.7253 310.8658 311.0063 311.1468 311.2873 311.4277 311.5682 311.7086 311.8490 311.9894 312.1298 312.2702 312.4106 312.5509 312.6913 312.8316 312.9719 313.1123 313.2526 313.3929 313.5332 313.6734 313.8137 313.9539 314.0942 314.2344 314.3746 314.5148 314.6550 314.7952 314.9354 315.0755 315.2157 315.3558 315.4960 315.6361 315.7762 315.9163 316.0564 316.1964 316.3365 316.4765 316.6166 316.7566 316.8966 317.0366 317.1766 317.3166 317.4566 317.5965 317.7365 317.8764 318.0164 318.1563 318.2962 318.4361 318.5759 318.7158 318.8557 318.9955 319.1353 319.2752 319.4150 319.5548 319.6946 319.8344 319.9741 320.1139 320.2536 320.3934 320.5331 320.6728 320.8125 320.9522 321.0918 321.2315 321.3712 321.5108 321.6504 321.7901 321.9297 322.0693 322.2088 322.3484 322.4880 322.6275 322.7671 322.9066 323.0461 323.1856 323.3251 323.4646 323.6041 323.7435 323.8830 324.0224 324.1618 324.3012 324.4406 324.5800 324.7194 324.8588 324.9981 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250508T132335.5Z 9259.558050 182 1 53.98 2 74.11 80.59 127.84 305.75 0.00 1 0.00 1 0 17 1.988e-01 8.945e-03 7.180e-02 3.002e-03 5.339017e-01 1.592237e-03 6.042854e-03 -6.000000e+00 1.187908e-01 229.51 -2.00 3.45 -2.00 319.56 0.00e+00 2.595143e-03 4.407683e-04 3.130271e-04 -6.000000e+00 5.019708e-03 274.77 -2.00 20.00 -2.00 319.04 0.00e+00 3.591 0.001 302.00 328.00 3 4.7845e+00 4.4664e-03 4.0613e-02 -6.0000e+00 2.9704e-01 7.4394e-02 5.2580e-03 2.7477e-02 -6.0000e+00 3.2131e-01 -1.0244e-01 4.3961e-03 1.4158e-02 -6.0000e+00 1.9020e-01 3.8632e-02 2.3059e-03 5.2324e-03 -6.0000e+00 8.0515e-02 1.1434e-04 -3.5445e-04 8.7807e-05 5.3751e-05 -6.0000e+00 5.8388e-03 1.3128e-02 -4.5364e-05 11 9 0 11 8 0 94.42 26.86 0.36 0.01313 0.01046 18 2 1 5 0 2998.570 35.50 20.00 26.86 17.39 10.2 943.85 -60886 -60857 -39330 -50562 -84071 -4769 -65277 -4023 135479 -58352 -61541 -27495 -39387 -20839 -8534 -10514 -7771 3496 -7373 -4286 24735 9460 -10007 3026 -16350 -12035 -13258 -10275 908 -2182 4807 1849 539 -5635 1586 -2404 7736 2625 -2064 2619 -2516 -1623 4735 1239 -3126 3509 1803 -1383 -1606 3585 4769 949 941 4415 1882 3311 1498 -908 1927 -405 2212 2767 1726 1499 965 273 -934 -150 3053 678 -586 -97 -325 1377 513 -2803 -2758 162 -2053 -2045 -958 -1963 -1490 -1153 83 -189 -443 357 536 190 -309 -939 595 -158 -49 318 825 229 71 -1019 -479 -334 1174 90 -1162 -602 -978 196 316 -28 -346 -249 1 -519 1098 714 783 55 -720 -291 503 703 146 740 343 571 1092 523 -36 -328 -366 -351 317 -19 314 -161 215 -12 -301 -28 -264 -604 900000 -1390 -1550 -829 -1125 -2436 -63 -1720 -65 595 -1879 -2161 -789 -1568 -854 -372 -535 -423 184 -460 -270 1180 532 -718 205 -1426 -1039 -1149 -836 66 -178 423 193 63 -714 181 -293 962 412 -408 571 -576 -390 1105 304 -812 865 457 -369 -445 1007 1454 330 354 1707 779 1393 649 -398 803 -174 975 1341 940 807 525 144 -491 -82 1797 459 -432 -73 -238 927 317 -1623 -1518 90 -1305 -1509 -738 -1696 -1376 -1126 79 -192 -470 381 562 190 -310 -886 537 -150 -49 356 975 301 97 -1374 -593 -404 1342 108 -1406 -763 -1315 278 458 -45 -557 -408 2 -834 1635 1037 1159 87 -1130 -467 790 1132 228 1102 491 835 1571 754 -58 -544 -649 -651 576 -36 605 -324 439 -24 -613 -54 -513 -1127 900000 SS 20250508T133442.1Z 9259.565765 185 1 55.18 2 72.00 82.28 129.51 308.43 0.00 1 0.00 1 0 17 8.997e-02 7.720e-03 2.553e-02 2.346e-03 4.797759e-01 1.241608e-03 5.496648e-03 -6.000000e+00 5.374337e-02 229.51 -2.00 3.45 -2.00 319.01 0.00e+00 1.782835e-03 2.868180e-04 3.566996e-04 -6.000000e+00 2.271279e-03 274.77 -2.00 20.00 -2.00 318.47 0.00e+00 3.195 0.001 302.00 328.00 3 4.7832e+00 3.4053e-03 3.6258e-02 -6.0000e+00 1.3439e-01 5.2734e-02 3.9008e-03 2.4487e-02 -6.0000e+00 1.4537e-01 -6.1887e-02 2.9472e-03 1.2367e-02 -6.0000e+00 8.6056e-02 2.0089e-02 1.5613e-03 4.0464e-03 -6.0000e+00 3.6424e-02 1.6770e-04 -2.8558e-04 6.9476e-05 4.3960e-05 -6.0000e+00 2.6421e-03 1.3606e-02 -6.4740e-05 11 9 0 11 8 0 96.98 26.86 0.15 0.01361 0.01146 21 2 1 5 0 2627.000 35.50 20.00 26.86 17.74 10.3 946.63 -28493 -24757 -12219 -22614 -51128 -9361 -35357 3352 17663 -33211 -33383 -16750 -29982 -22376 -1272 -2182 -10960 6776 -3791 -367 10500 5989 -4626 -2543 -2272 -3034 -6157 -1753 -6655 -2014 5180 222 -814 -4798 -2416 -5467 -1681 441 -1947 953 -1519 -1067 727 336 -208 2040 1425 -1490 -292 2044 3523 2154 1677 2119 1220 3022 1365 -234 876 1011 2680 1938 2613 957 683 50 -480 -641 1652 473 -618 298 -440 -139 462 -1624 -976 -406 -1282 -691 -926 -1679 -2615 -930 -827 -868 -63 -81 575 542 -211 -995 1066 355 433 4 470 142 -305 -784 -234 -535 849 179 -1432 -933 -652 -144 435 53 270 201 -400 -3 890 794 572 293 -244 86 71 531 286 343 290 322 800 673 10 -288 -169 -352 151 130 -224 -130 432 -112 -489 197 -441 -368 900000 -795 -736 -327 -631 -1766 -214 -1148 84 420 -1382 -1458 -701 -1735 -1464 -80 -157 -935 521 -342 -33 867 523 -472 -273 -258 -359 -742 -195 -769 -238 648 33 -135 -838 -398 -955 -319 98 -485 265 -474 -349 242 114 -71 691 488 -531 -106 765 1419 960 741 989 598 1499 696 -120 435 504 1384 1109 1641 602 430 30 -310 -396 1109 360 -474 232 -336 -107 323 -1048 -641 -271 -891 -551 -781 -1578 -2479 -920 -872 -972 -68 -89 660 591 -215 -1016 1028 358 452 4 587 185 -414 -1036 -302 -634 959 213 -1842 -1184 -870 -203 626 83 424 321 -621 -4 1274 1169 860 438 -389 141 115 830 432 497 426 452 1103 982 15 -479 -283 -613 259 236 -431 -248 835 -218 -947 382 -817 -653 900000 SS 20250508T135033.6Z 9259.576778 195 1 55.49 2 68.98 84.71 131.79 312.48 0.00 1 0.00 1 0 17 5.893e-02 7.988e-03 1.864e-02 2.583e-03 4.174166e-01 1.358259e-03 4.820717e-03 -6.000000e+00 3.520159e-02 229.51 -2.00 3.45 -2.00 318.53 0.00e+00 1.982819e-03 2.697222e-04 1.881487e-04 -6.000000e+00 1.487638e-03 274.77 -2.00 20.00 -2.00 317.97 0.00e+00 2.763 0.000 302.00 328.00 3 5.3636e+00 3.6761e-03 3.1436e-02 -6.0000e+00 8.8024e-02 5.5699e-02 4.1635e-03 2.1308e-02 -6.0000e+00 9.5217e-02 -5.6668e-02 2.8851e-03 1.0647e-02 -6.0000e+00 5.6366e-02 1.8544e-02 1.5113e-03 3.5848e-03 -6.0000e+00 2.3858e-02 1.4304e-04 -2.5649e-04 7.7687e-05 3.8739e-05 -6.0000e+00 1.7305e-03 1.3505e-02 -5.9586e-05 11 8 0 10 0 0 94.66 26.87 0.52 0.01351 0.01158 15 1 1 5 0 3698.870 35.50 20.00 26.87 18.45 10.3 951.55 -12452 -19008 -17840 301 -24081 -18582 -11504 1247 24163 -22682 -27362 -3386 -13241 -6533 -9323 227 -8994 4329 -1709 3835 10890 8168 -8380 1446 -5113 -717 -5305 -6082 -1117 -78 2950 514 -981 -2482 -2235 -3779 -1544 150 -942 2896 -2204 -921 321 -3 98 1758 -288 -156 -1422 1574 3511 1718 1790 3278 1844 2695 2214 -701 1712 -243 2858 1300 1743 1146 -1165 227 -427 587 1848 468 -120 33 -435 212 335 -1411 -2042 -1001 -1532 -1347 -1282 -1033 -2069 -1590 -458 -728 -274 -167 582 239 197 -501 126 487 -331 1182 511 -25 -253 -794 -462 -762 798 -49 -1021 -528 -507 134 380 67 -140 198 63 -63 1010 574 476 -334 -517 124 485 575 -66 593 610 390 707 770 -237 89 -119 -352 310 -88 -95 -121 282 -92 -193 12 -583 -492 900000 -521 -929 -872 11 -1080 -786 -493 53 888 -1388 -1812 -196 -1007 -558 -958 24 -1105 496 -219 481 1286 998 -1258 209 -834 -115 -876 -968 -166 -12 496 99 -209 -541 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