File name: Pandora57s1_BoulderCO_20220912_L2Fit_fout2c7d20220707p1-8.txt File generation date: 20250331T080245.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v7d20220707.txt Level 1 file used: Pandora57s1_BoulderCO_20220912_L1_smca1c7d20220707p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20220912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1062 305.2469 305.3876 305.5283 305.6689 305.8096 305.9503 306.0909 306.2315 306.3722 306.5128 306.6534 306.7939 306.9345 307.0751 307.2156 307.3562 307.4967 307.6372 307.7777 307.9182 308.0587 308.1992 308.3396 308.4801 308.6205 308.7609 308.9013 309.0417 309.1821 309.3225 309.4629 309.6032 309.7436 309.8839 310.0242 310.1645 310.3048 310.4451 310.5854 310.7257 310.8659 311.0062 311.1464 311.2866 311.4268 311.5670 311.7072 311.8474 311.9875 312.1277 312.2678 312.4079 312.5480 312.6881 312.8282 312.9683 313.1084 313.2484 313.3885 313.5285 313.6685 313.8085 313.9485 314.0885 314.2285 314.3685 314.5084 314.6484 314.7883 314.9282 315.0681 315.2080 315.3479 315.4878 315.6276 315.7675 315.9073 316.0471 316.1869 316.3267 316.4665 316.6063 316.7461 316.8858 317.0256 317.1653 317.3050 317.4447 317.5844 317.7241 317.8638 318.0035 318.1431 318.2828 318.4224 318.5620 318.7016 318.8412 318.9808 319.1203 319.2599 319.3995 319.5390 319.6785 319.8180 319.9575 320.0970 320.2365 320.3760 320.5154 320.6548 320.7943 320.9337 321.0731 321.2125 321.3519 321.4913 321.6306 321.7700 321.9093 322.0486 322.1879 322.3272 322.4665 322.6058 322.7451 322.8843 323.0236 323.1628 323.3020 323.4412 323.5804 323.7196 323.8588 323.9980 324.1371 324.2762 324.4154 324.5545 324.6936 324.8327 324.9718 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220912T130948.3Z 8290.548475 223 1 49.56 2 85.01 88.89 70.14 258.21 0.00 1 0.00 1 0 41 5.676e-01 5.063e-02 4.701e-01 2.592e-02 1.085793e+00 1.709412e-02 1.076739e-02 -6.000000e+00 3.478552e-01 228.46 -2.00 3.45 -2.00 322.58 0.00e+00 9.692383e-03 8.104758e-03 1.682271e-03 -6.000000e+00 1.812829e-02 279.85 -2.00 20.00 -2.00 322.21 0.00e+00 9.877 0.017 302.00 328.00 3 1.1632e+00 5.8284e-02 9.9797e-02 -6.0000e+00 8.7093e-01 1.6215e+00 7.7683e-02 5.5228e-02 -6.0000e+00 9.5251e-01 -1.9400e+00 7.3597e-02 2.9340e-02 -6.0000e+00 5.6337e-01 7.4466e-01 3.6203e-02 1.0066e-02 -6.0000e+00 2.4084e-01 1.3804e-05 1.7052e-04 7.8216e-04 1.5780e-04 -6.0000e+00 1.7794e-02 7.0563e-03 -3.1062e-05 12 8 8 10 0 0 8.73 20.14 0.93 0.00706 0.00834 37 7 1 5 0 1339.300 25.90 20.00 20.14 18.66 23.4 789.57 -133116 900000 -97990 900000 -12474 -41972 900000 128686 900000 -108414 900000 900000 -105122 900000 900000 900000 -16934 900000 900000 900000 900000 900000 900000 900000 900000 27879 90445 900000 900000 900000 -1458 900000 17270 124725 -3202 30253 900000 74231 900000 900000 51232 192320 -23094 900000 900000 900000 900000 900000 900000 54902 53738 116371 123942 180980 7084 900000 23962 285212 139085 72175 52204 25255 30407 39976 65590 42710 38162 28013 21228 34874 -1967 20480 10507 53821 335 14066 33866 -20248 22794 16975 17119 5435 10288 6115 6572 8453 -4415 -3214 -2177 10878 2423 -17945 -13314 -442 -7314 -2570 2104 243 -2728 -99 -3659 472 -10401 -5551 -3315 -9938 1556 -4249 -2308 -2694 -2705 -679 -2487 2306 1260 -722 -469 -482 4434 -1532 2420 819 -821 951 3454 40 -201 4027 3636 4200 4644 2899 4452 -13464 3367 2422 2026 384 593 607 -2195 448 -2714 -7591 900000 -3800 900000 -313 -1053 900000 3229 900000 -2720 900000 900000 -3837 900000 900000 900000 -502 900000 900000 900000 900000 900000 900000 900000 900000 700 2270 900000 900000 900000 -37 900000 473 3130 -95 759 900000 1863 900000 900000 1543 4826 -1507 900000 900000 900000 900000 900000 900000 2066 2292 2920 3110 4541 622 900000 1744 7157 3490 2717 2489 1774 2365 3210 4279 3537 3447 3023 2770 4463 -385 3186 1687 4997 46 1518 2974 -3404 3031 2939 3522 1446 2840 1857 2094 2757 -1531 -1218 -797 3303 748 -6574 -4811 -159 -3070 -1249 1171 160 -2010 -70 -2463 267 -5908 -3014 -1868 -6302 948 -3053 -1885 -2606 -3011 -806 -3098 2719 1463 -846 -566 -612 5593 -2048 2953 953 -931 1026 3538 41 -211 4574 4969 6697 8370 5845 9566 -37409 8471 6383 5417 1046 1568 1492 -5062 927 -5622 SS 20220912T131950.2Z 8290.555442 226 1 50.03 2 83.09 90.51 71.95 259.94 0.00 1 0.00 1 0 25 7.463e-01 1.214e-02 3.006e-01 5.492e-03 8.639547e-01 3.161041e-03 8.805124e-03 -6.000000e+00 4.353742e-01 228.46 -2.00 3.45 -2.00 322.06 0.00e+00 3.634837e-03 1.431892e-03 1.180365e-03 -6.000000e+00 1.958011e-02 279.85 -2.00 20.00 -2.00 321.70 0.00e+00 7.632 0.008 302.00 328.00 3 1.2346e+00 1.0404e-02 7.7769e-02 -6.0000e+00 1.0952e+00 2.4944e-01 1.7856e-02 4.6820e-02 -6.0000e+00 1.1976e+00 -3.4983e-01 2.2368e-02 2.7056e-02 -6.0000e+00 6.9916e-01 1.3596e-01 1.0317e-02 9.3451e-03 -6.0000e+00 2.9049e-01 1.2744e-04 -7.4597e-04 1.6197e-04 1.2618e-04 -6.0000e+00 2.1826e-02 7.6437e-03 -6.5454e-05 12 8 8 10 0 0 21.90 20.15 0.39 0.00764 0.00204 145 29 1 5 0 342.650 25.90 20.00 20.15 19.56 23.0 794.97 -331186 900000 -334277 900000 -228169 -282846 900000 -271953 900000 -276995 900000 -160001 900000 900000 -165675 900000 -131555 -27918 -73048 -68402 900000 -108203 900000 -94752 132292 -96250 -65571 85487 -91991 89875 -89856 73869 11124 -16476 -3306 -51627 42035 -46906 97773 -10213 -16317 53962 -3814 33317 -16152 22131 -564 15304 27878 -2750 36526 9262 25539 4520 15217 14822 2861 25452 4155 21091 2423 1712 8288 5205 14000 -4084 7800 4281 4818 8540 2739 9443 1118 5238 1448 2264 6641 -4912 5291 -2468 1094 -718 -1880 371 -1648 294 -1901 2342 1130 280 1718 -2208 1270 -3870 263 -952 -793 428 -492 832 -1733 169 -848 -1541 -94 -2358 -50 -2545 120 -333 -407 216 -658 332 -790 360 381 4 519 -767 693 -328 1223 606 469 523 476 1434 237 659 126 -89 203 -73 -83 -323 522 -54 -450 417 -534 406 -905 -3701 900000 -4711 900000 -1220 -2199 900000 -2379 900000 -3096 900000 -855 900000 900000 -2013 900000 -1758 -149 -664 -622 900000 -1504 900000 -1367 707 -1595 -806 457 -1524 480 -2209 434 143 -291 -49 -1297 472 -1554 941 -344 -654 1154 -153 944 -768 745 -25 622 1088 -163 1679 634 1652 396 1277 1307 291 2027 395 1680 246 199 954 703 1823 -641 1126 691 883 1730 639 2111 262 1089 281 395 1084 -974 1124 -687 348 -268 -777 160 -774 144 -988 1187 573 136 771 -987 552 -1933 147 -640 -627 385 -481 790 -1564 134 -620 -1154 -74 -2005 -45 -2535 131 -420 -577 324 -1010 493 -1138 501 543 7 814 -1237 1066 -484 1713 823 617 667 604 1969 382 1212 238 -181 442 -171 -208 -848 1382 -147 -1196 1036 -1246 878 -1937 SS 20220912T133006.5Z 8290.562575 229 1 49.14 2 81.13 92.17 73.81 261.67 0.00 1 0.00 1 0 25 4.865e-01 5.273e-03 1.600e-01 2.052e-03 7.253302e-01 1.120722e-03 7.564451e-03 -6.000000e+00 2.800288e-01 228.46 -2.00 3.45 -2.00 321.55 0.00e+00 2.327479e-03 4.551303e-04 7.523850e-04 -6.000000e+00 1.129528e-02 279.85 -2.00 20.00 -2.00 321.19 0.00e+00 6.144 0.004 302.00 328.00 3 1.0179e+00 3.3877e-03 6.2973e-02 -6.0000e+00 7.0182e-01 4.2746e-02 5.1468e-03 3.8232e-02 -6.0000e+00 7.6573e-01 -5.9207e-02 6.3823e-03 2.1566e-02 -6.0000e+00 4.4995e-01 1.7137e-02 3.0925e-03 7.2282e-03 -6.0000e+00 1.8554e-01 5.8307e-04 -5.2635e-04 6.0019e-05 8.5088e-05 -6.0000e+00 1.3642e-02 6.7065e-03 -5.1324e-05 10 0 0 10 0 0 -22.67 20.16 0.29 0.00671 0.00275 343 68 1 5 0 143.270 25.90 19.99 20.16 21.09 23.0 802.96 -197994 -159847 -162158 -148583 -88688 -200219 -196561 -147903 -198791 -67543 -64252 -124805 -105033 -37151 -45565 -65797 -38052 -47753 -24147 -33484 -37861 -36764 -46136 -33159 -19176 -23127 -31942 -38474 -20301 -33483 -9437 -14585 -2476 -15101 -1057 -16509 -15810 -3922 -5499 2940 462 1329 -1691 -3656 3609 -1498 -633 1512 1341 255 438 3110 4231 4111 1770 4051 1435 727 354 269 1419 2978 4121 3136 1219 1616 1353 709 1571 1939 1111 859 408 239 -632 -856 -1050 -473 -733 -679 -1014 -763 -1457 -1381 -874 -377 356 668 1011 1022 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