File name: Pandora57s1_BoulderCO_20221023_L2Fit_fout2c7d20220707p1-8.txt File generation date: 20250331T080248.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v7d20220707.txt Level 1 file used: Pandora57s1_BoulderCO_20221023_L1_smca1c7d20220707p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20221023 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1062 305.2469 305.3876 305.5283 305.6689 305.8096 305.9503 306.0909 306.2315 306.3722 306.5128 306.6534 306.7939 306.9345 307.0751 307.2156 307.3562 307.4967 307.6372 307.7777 307.9182 308.0587 308.1992 308.3396 308.4801 308.6205 308.7609 308.9013 309.0417 309.1821 309.3225 309.4629 309.6032 309.7436 309.8839 310.0242 310.1645 310.3048 310.4451 310.5854 310.7257 310.8659 311.0062 311.1464 311.2866 311.4268 311.5670 311.7072 311.8474 311.9875 312.1277 312.2678 312.4079 312.5480 312.6881 312.8282 312.9683 313.1084 313.2484 313.3885 313.5285 313.6685 313.8085 313.9485 314.0885 314.2285 314.3685 314.5084 314.6484 314.7883 314.9282 315.0681 315.2080 315.3479 315.4878 315.6276 315.7675 315.9073 316.0471 316.1869 316.3267 316.4665 316.6063 316.7461 316.8858 317.0256 317.1653 317.3050 317.4447 317.5844 317.7241 317.8638 318.0035 318.1431 318.2828 318.4224 318.5620 318.7016 318.8412 318.9808 319.1203 319.2599 319.3995 319.5390 319.6785 319.8180 319.9575 320.0970 320.2365 320.3760 320.5154 320.6548 320.7943 320.9337 321.0731 321.2125 321.3519 321.4913 321.6306 321.7700 321.9093 322.0486 322.1879 322.3272 322.4665 322.6058 322.7451 322.8843 323.0236 323.1628 323.3020 323.4412 323.5804 323.7196 323.8588 323.9980 324.1371 324.2762 324.4154 324.5545 324.6936 324.8327 324.9718 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221023T140146.0Z 8331.584560 109 1 8.17 2 83.27 111.20 61.48 117.86 0.00 1 0.00 1 0 25 7.337e-01 1.396e-02 4.252e-01 1.009e-02 9.137233e-01 5.617209e-03 9.421234e-03 -6.000000e+00 4.197455e-01 224.51 -2.00 3.45 -2.00 321.87 0.00e+00 1.440452e-03 2.458171e-03 1.160849e-03 -6.000000e+00 1.827319e-02 274.54 -2.00 20.00 -2.00 321.52 0.00e+00 7.810 0.008 302.00 328.00 3 1.3281e+00 1.7757e-02 7.9436e-02 -6.0000e+00 1.0415e+00 3.0911e-01 2.9865e-02 4.8374e-02 -6.0000e+00 1.1413e+00 -3.6842e-01 3.7235e-02 2.8303e-02 -6.0000e+00 6.7096e-01 1.3859e-01 1.7365e-02 9.8453e-03 -6.0000e+00 2.8444e-01 9.6236e-05 -1.1332e-03 2.7324e-04 1.2661e-04 -6.0000e+00 2.1124e-02 3.9530e-03 -1.0159e-04 12 9 9 12 1 1 32.24 20.18 0.30 0.00395 -0.00456 14 18 1 5 0 533.890 25.90 20.00 20.18 16.46 23.4 788.08 900000 -280328 900000 900000 -333809 900000 -257104 -209537 -275781 -205604 -84283 -211429 -30400 -187745 900000 -63899 -133730 -194377 -79971 -39784 -133206 -21428 -104236 177720 -122810 -125907 -15150 -28993 596 -100795 -45972 -24578 26202 2340 -89874 39809 -11895 -5574 4378 11976 59630 13344 23920 2365 58413 17408 8049 37857 26933 9382 5140 35022 14905 11192 29380 15997 20421 3607 17492 8667 10682 7425 11837 12052 5656 11454 6641 5056 2308 4969 5939 2120 9337 -70 -2007 -5245 1201 12131 3053 4876 -2451 -3083 -337 -3106 -1293 -1410 1181 -126 -931 2038 -173 1628 -225 -1601 -1728 -2657 1115 -760 66 -526 -405 -803 -498 -266 -2150 306 -403 -1415 -900 33 717 63 -608 -200 -18 -319 -355 803 -873 147 -579 934 1666 311 520 -75 947 475 997 600 103 426 -616 -95 -129 284 140 59 478 244 -222 -402 -1335 900000 -2756 900000 900000 -3878 900000 -2527 -2060 -2711 -2021 -829 -2078 -299 -2399 900000 -628 -1840 -5038 -786 -391 -2357 -211 -1537 1747 -2656 -2971 -149 -285 6 -2279 -768 -411 309 37 -3446 430 -246 -132 116 353 1231 472 799 100 1436 667 356 1340 1165 544 359 2066 1202 1034 2426 1588 1987 408 1651 878 1113 905 1470 1712 910 1761 1116 935 501 1208 1555 591 2336 -18 -463 -1130 237 2331 764 1460 -940 -1375 -161 -1624 -708 -817 692 -76 -558 1129 -92 813 -116 -917 -1064 -1967 940 -755 70 -555 -395 -698 -392 -210 -1849 270 -384 -1490 -1069 42 1012 96 -949 -305 -26 -457 -519 1216 -1407 238 -905 1361 2314 423 681 -105 1292 657 1602 1116 199 896 -1400 -231 -336 717 359 153 1211 626 -527 -892 -2906 SS 20221023T142515.3Z 8331.600871 117 1 1.98 2 79.14 115.25 57.76 122.94 0.00 1 0.00 1 0 17 3.621e-01 1.690e-02 3.031e-01 1.505e-02 6.270655e-01 7.846379e-03 6.920228e-03 -6.000000e+00 2.087209e-01 224.51 -2.00 3.45 -2.00 320.37 0.00e+00 7.271264e-03 2.532782e-03 4.229917e-04 -6.000000e+00 9.203892e-03 274.54 -2.00 20.00 -2.00 320.06 0.00e+00 5.121 0.002 302.00 328.00 3 3.0171e+00 2.2046e-02 5.2348e-02 -6.0000e+00 5.1831e-01 6.6662e-02 2.7592e-02 3.1472e-02 -6.0000e+00 5.6813e-01 -7.1015e-02 2.9199e-02 1.6603e-02 -6.0000e+00 3.3177e-01 3.0765e-02 1.5217e-02 5.1861e-03 -6.0000e+00 1.3876e-01 1.8914e-04 -4.7359e-04 4.2469e-04 5.9746e-05 -6.0000e+00 1.0503e-02 3.9750e-03 -1.0877e-04 12 9 9 12 1 1 999.00 20.18 0.33 0.00398 0.00042 1 11 1 5 0 905.770 25.90 20.00 20.18 17.77 23.7 797.39 -184446 900000 -80560 900000 -190553 900000 900000 76462 -109049 -116756 900000 -112794 6380 -47601 -61004 102914 -61184 5314 -5422 122643 -21653 30035 -1971 -13421 30661 -36859 -6413 -52464 -7442 -15537 -15972 7521 -31177 -3800 26531 24949 28595 -13785 -1118 27577 34001 32071 23780 -2817 2034 21040 6570 5609 -6181 12076 4055 -1620 13579 -2205 -4362 5567 -5471 2055 -6935 -1731 2991 6702 408 4894 1511 -585 5667 -5603 614 -104 4076 1461 -2049 -1699 -481 -231 -2511 3619 2241 -980 1177 -2718 -317 -3052 -2825 413 -674 372 -166 480 -364 2294 1106 -1100 -408 277 -1427 -893 841 -740 111 971 -1023 1043 -2318 1009 -1524 -2714 1515 516 2018 1481 -1045 1023 -224 173 -1129 -256 291 -43 365 927 253 -1810 517 734 -474 2331 -1088 -67 518 -1257 253 1200 1063 -1156 -314 -570 -34 1342 -1278 -182 138 -4369 900000 -1181 900000 -5158 900000 900000 1121 -1722 -2107 900000 -2544 94 -966 -1789 1509 -2415 120 -147 1798 -733 610 -58 -469 726 -1788 -231 -2959 -277 -718 -901 399 -2778 -266 1317 1294 1613 -1415 -122 2644 3375 3473 2950 -437 309 2732 1018 916 -1198 2112 858 -402 3157 -604 -1275 1627 -1690 622 -2095 -499 874 2116 156 1986 650 -251 2277 -2634 285 -55 2249 849 -1200 -927 -235 -109 -1154 1631 1101 -588 754 -2042 -251 -2484 -2453 368 -634 354 -157 430 -305 1862 883 -944 -371 275 -1663 -1113 1094 -957 131 1085 -1085 1112 -2739 1152 -1890 -3487 2050 749 3156 2314 -1655 1586 -332 258 -1654 -391 467 -67 591 1435 381 -2671 749 1023 -654 3327 -1725 -112 938 -2349 488 2329 2200 -2452 -674 -1243 -73 2808 -2585 -358 266 SS 20221023T143011.2Z 8331.604296 120 1 46.63 2 78.29 116.13 57.00 124.06 0.00 1 0.00 1 0 25 1.682e-01 4.353e-03 3.078e-02 6.119e-04 6.083772e-01 3.154312e-04 6.625907e-03 -6.000000e+00 9.543270e-02 224.51 -2.00 3.45 -2.00 320.75 0.00e+00 1.317869e-03 1.109380e-04 4.679723e-04 -6.000000e+00 3.905468e-03 274.54 -2.00 20.00 -2.00 320.41 0.00e+00 4.777 0.002 302.00 328.00 3 1.5861e-01 9.0447e-04 4.9611e-02 -6.0000e+00 2.3703e-01 2.6739e-02 1.1876e-03 3.0762e-02 -6.0000e+00 2.5934e-01 -1.5941e-05 1.3457e-03 1.6646e-02 -6.0000e+00 1.5284e-01 -9.1757e-03 6.9008e-04 5.3490e-03 -6.0000e+00 6.3568e-02 4.4785e-03 -6.7111e-04 1.7767e-05 6.1040e-05 -6.0000e+00 4.7122e-03 4.1287e-03 -8.5583e-05 10 0 0 10 0 0 99.17 20.17 0.24 0.00413 -0.00091 1325 262 1 5 0 35.190 25.90 19.99 20.17 18.70 23.5 803.69 -18262 -69143 -59824 -42797 -77713 -48873 -66604 -46308 -54888 -49956 -50106 -43826 -23887 -29480 -3821 -16200 -9964 -6067 -13454 -3826 -13986 -4048 -5861 -8543 -3570 -11453 -2639 -13855 -3700 -7671 -4051 -668 -4309 -905 -8595 -4015 -5299 -2066 -880 -2471 -426 -2011 -257 -758 -291 -171 -955 179 -1403 981 658 970 1843 407 1282 321 585 -373 -93 373 773 2321 1928 2061 989 715 103 105 1284 760 768 537 391 220 -359 60 -754 -292 -441 -679 -557 -1436 -1458 -1596 -814 -422 29 526 457 1016 764 819 444 484 350 256 852 460 229 8 -580 -786 -452 -352 -1204 -948 -821 -662 65 157 293 134 200 -42 -129 155 105 249 -198 -277 -177 55 87 163 478 69 641 519 206 334 -5 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