File name: Pandora57s1_BoulderCO_20230320_L2Fit_fout2c7d20220707p1-8.txt File generation date: 20250331T080232.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v7d20220707.txt Level 1 file used: Pandora57s1_BoulderCO_20230320_L1_smca1c7d20220707p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20230320 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1062 305.2469 305.3876 305.5283 305.6689 305.8096 305.9503 306.0909 306.2315 306.3722 306.5128 306.6534 306.7939 306.9345 307.0751 307.2156 307.3562 307.4967 307.6372 307.7777 307.9182 308.0587 308.1992 308.3396 308.4801 308.6205 308.7609 308.9013 309.0417 309.1821 309.3225 309.4629 309.6032 309.7436 309.8839 310.0242 310.1645 310.3048 310.4451 310.5854 310.7257 310.8659 311.0062 311.1464 311.2866 311.4268 311.5670 311.7072 311.8474 311.9875 312.1277 312.2678 312.4079 312.5480 312.6881 312.8282 312.9683 313.1084 313.2484 313.3885 313.5285 313.6685 313.8085 313.9485 314.0885 314.2285 314.3685 314.5084 314.6484 314.7883 314.9282 315.0681 315.2080 315.3479 315.4878 315.6276 315.7675 315.9073 316.0471 316.1869 316.3267 316.4665 316.6063 316.7461 316.8858 317.0256 317.1653 317.3050 317.4447 317.5844 317.7241 317.8638 318.0035 318.1431 318.2828 318.4224 318.5620 318.7016 318.8412 318.9808 319.1203 319.2599 319.3995 319.5390 319.6785 319.8180 319.9575 320.0970 320.2365 320.3760 320.5154 320.6548 320.7943 320.9337 321.0731 321.2125 321.3519 321.4913 321.6306 321.7700 321.9093 322.0486 322.1879 322.3272 322.4665 322.6058 322.7451 322.8843 323.0236 323.1628 323.3020 323.4412 323.5804 323.7196 323.8588 323.9980 324.1371 324.2762 324.4154 324.5545 324.6936 324.8327 324.9718 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230320T154136.8Z 8479.653899 130 1 50.50 2 61.74 116.95 62.54 134.19 0.00 1 0.00 1 0 17 1.473e-02 5.735e-03 8.082e-03 1.624e-03 3.240455e-01 8.107414e-04 3.769922e-03 -6.000000e+00 8.408819e-03 225.77 -2.00 3.45 -2.00 318.17 0.00e+00 1.952336e-04 1.356848e-04 9.036409e-05 -6.000000e+00 3.420456e-04 268.62 -2.00 20.00 -2.00 317.84 0.00e+00 2.102 0.000 302.00 328.00 3 4.8674e+00 2.1551e-03 2.3642e-02 -6.0000e+00 2.0946e-02 2.9211e-02 2.4318e-03 1.6011e-02 -6.0000e+00 2.2887e-02 4.0300e-03 1.6088e-03 8.0520e-03 -6.0000e+00 1.3476e-02 -9.3396e-03 8.3705e-04 2.3379e-03 -6.0000e+00 5.5970e-03 4.7009e-04 -2.2158e-04 4.7918e-05 2.6495e-05 -6.0000e+00 4.1269e-04 -3.4686e-03 -4.2544e-05 11 1 0 11 8 0 91.69 20.30 0.30 -0.00347 -0.00513 41 8 1 5 0 1231.640 26.00 19.99 20.30 12.69 23.4 949.80 3403 -2195 -3467 -6606 -9907 1114 -3770 843 -4847 -1794 -159 -1471 1923 -2468 1249 -193 -1157 629 -692 752 -771 28 -142 579 699 -790 68 -1588 -413 776 235 1303 391 -363 -2453 -1376 -1551 -458 1066 -1147 -847 -957 -374 -926 -674 -457 -635 -213 -665 -43 289 572 1187 859 1057 559 721 -130 554 730 936 1524 1762 1317 -18 34 -725 -122 882 622 327 270 663 254 132 18 -1179 -301 -460 -859 -754 -1480 -1796 -1676 -817 -694 -312 428 175 1766 330 251 214 269 415 109 827 748 310 -220 -681 -770 -514 -408 -936 -779 -674 -749 17 258 265 -41 50 -101 -115 110 45 225 -23 -33 -154 201 188 280 914 127 700 705 302 399 89 57 -290 718 -40 -140 250 -173 -55 -13 -414 -434 -400 204 -151 -243 -441 -621 62 -241 58 -389 -146 -13 -129 187 -293 164 -28 -180 101 -118 131 -137 5 -26 113 144 -170 14 -319 -78 148 49 294 97 -91 -593 -333 -419 -132 362 -459 -367 -433 -173 -433 -314 -212 -290 -96 -299 -20 142 300 657 503 637 347 452 -81 338 444 591 1035 1301 1035 -14 25 -504 -85 656 523 274 233 563 225 107 13 -801 -198 -326 -693 -684 -1366 -1771 -1736 -899 -813 -381 532 216 2048 357 250 198 247 410 120 1010 1010 406 -305 -887 -922 -584 -482 -1198 -1047 -949 -1023 25 396 429 -67 80 -149 -157 153 63 329 -33 -50 -238 303 275 391 1304 174 914 941 435 570 134 89 -464 1189 -72 -260 472 -312 -98 -24 -745 -752 -680 SS 20230320T154653.2Z 8479.657561 133 1 49.68 2 60.84 118.05 61.83 135.37 0.00 1 0.00 1 0 17 1.281e-02 5.248e-03 6.516e-03 1.424e-03 3.142087e-01 7.123180e-04 3.676057e-03 -6.000000e+00 7.312645e-03 225.77 -2.00 3.45 -2.00 318.04 0.00e+00 3.761530e-04 1.148855e-04 8.382200e-05 -6.000000e+00 2.974095e-04 268.62 -2.00 20.00 -2.00 317.71 0.00e+00 2.044 0.000 302.00 328.00 3 4.6737e+00 1.8919e-03 2.2980e-02 -6.0000e+00 1.8215e-02 2.6349e-02 2.1320e-03 1.5560e-02 -6.0000e+00 1.9903e-02 4.5176e-03 1.3866e-03 7.8210e-03 -6.0000e+00 1.1719e-02 -9.3952e-03 7.1513e-04 2.2670e-03 -6.0000e+00 4.8677e-03 6.0760e-04 -1.7663e-04 4.2148e-05 2.5574e-05 -6.0000e+00 3.5883e-04 -3.7819e-03 -2.5003e-05 11 1 0 11 8 0 99.20 20.30 0.26 -0.00378 -0.00511 53 10 1 5 0 937.370 26.00 20.00 20.30 12.96 23.3 951.72 -2576 -1985 -5077 -4973 -5227 -6144 -2983 -2030 -316 -683 -3395 -2194 -1609 817 -420 -425 -531 1093 1044 -173 -607 479 1772 -647 -390 -446 -802 -1057 -614 1145 1321 1455 424 -1052 -1554 -1988 -1713 555 253 -821 -989 -565 -899 -504 -40 -430 -296 -754 -492 233 719 789 855 705 752 640 586 391 350 792 880 1414 1602 842 282 -102 -666 -129 712 594 521 638 263 354 -20 -188 -483 -235 -349 -719 -850 -1629 -1797 -1600 -898 -629 -173 95 434 581 509 247 445 493 294 504 701 631 179 -86 -477 -998 -497 -422 -769 -767 -732 -719 -30 304 341 72 133 -154 -201 184 -64 263 240 -199 53 181 57 381 582 414 730 574 336 547 -1 1 -297 394 26 -138 63 -51 -39 -17 -118 -416 -554 -180 -149 -396 -357 -342 -403 -206 -156 -26 -59 -304 -208 -175 101 -60 -67 -88 187 186 -32 -115 90 341 -136 -86 -101 -180 -223 -123 229 286 344 110 -278 -390 -506 -485 164 90 -341 -445 -265 -434 -244 -19 -207 -140 -353 -228 110 361 425 488 425 467 407 378 250 219 494 570 986 1215 681 226 -76 -472 -91 539 508 442 559 229 293 -17 -141 -332 -157 -251 -587 -782 -1524 -1792 -1676 -1000 -744 -213 120 543 691 558 248 415 455 293 556 862 857 236 -111 -623 -1204 -568 -501 -990 -1038 -958 -988 -43 468 553 118 209 -226 -273 256 -89 355 346 -304 81 273 83 533 835 567 956 767 484 779 -2 2 -475 653 46 -255 110 -92 -70 -32 -211 -720 -942 SS 20230320T155158.6Z 8479.661094 136 1 49.71 2 59.99 119.13 61.15 136.53 0.00 1 0.00 1 0 17 1.103e-02 5.159e-03 3.294e-03 7.890e-04 3.057946e-01 3.950972e-04 3.590268e-03 -6.000000e+00 6.296218e-03 225.77 -2.00 3.45 -2.00 317.84 0.00e+00 4.196533e-04 6.064683e-05 7.825852e-05 -6.000000e+00 2.560930e-04 268.62 -2.00 20.00 -2.00 317.51 0.00e+00 1.991 0.000 302.00 328.00 3 3.7210e+00 1.0466e-03 2.2386e-02 -6.0000e+00 1.5683e-02 1.9833e-02 1.1788e-03 1.5160e-02 -6.0000e+00 1.7136e-02 4.2216e-03 7.5748e-04 7.6171e-03 -6.0000e+00 1.0090e-02 -7.7537e-03 3.8760e-04 2.2015e-03 -6.0000e+00 4.1910e-03 1.6695e-03 -2.5671e-04 2.3321e-05 2.5300e-05 -6.0000e+00 3.0898e-04 -3.6687e-03 -3.6540e-05 11 1 0 11 8 0 96.79 20.30 0.27 -0.00367 -0.00560 140 28 1 5 0 355.030 26.00 20.00 20.30 13.26 23.4 953.97 -1327 -4216 -1881 -5567 -5126 -747 -1832 850 -1075 -2586 -2102 -2622 293 -1613 771 -769 -29 -251 -78 592 -861 970 822 841 367 -23 -203 -595 350 378 1251 1852 497 -1023 -2176 -1360 -1495 -503 -218 -700 -579 -1004 -825 -613 -261 -325 -619 -218 -254 367 538 940 993 441 790 802 624 318 512 689 797 1588 1743 1178 -24 10 -540 -382 763 691 621 328 378 116 69 -273 -662 -324 -386 -459 -741 -1394 -1823 -1651 -1065 -737 -194 193 254 486 512 380 205 467 347 394 787 496 185 -67 -590 -920 -468 -176 -892 -732 -699 -575 48 265 279 201 206 -7 -69 82 103 350 105 -81 -46 89 156 245 596 193 689 644 366 407 137 69 -157 37 -82 -125 179 -140 -81 0 -173 -394 -371 -97 -342 -150 -467 -389 -54 -144 73 -104 -264 -214 -287 36 -233 113 -126 -5 -45 -14 113 -168 186 164 178 82 -5 -47 -128 71 78 277 444 131 -275 -557 -349 -428 -168 -87 -323 -289 -525 -443 -330 -140 -174 -326 -112 -130 191 299 558 572 269 495 513 406 205 323 434 522 1115 1329 956 -19 7 -383 -270 578 591 575 315 358 105 57 -204 -457 -217 -278 -373 -679 -1415 -1825 -1736 -1192 -877 -241 245 319 581 564 384 209 469 345 435 966 626 245 -86 -771 -1109 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