File name: Pandora57s1_BoulderCO_20230616_L2Fit_fwvt1c7d20220707p1-8.txt File generation date: 20250331T080555.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v7d20220707.txt Level 1 file used: Pandora57s1_BoulderCO_20230616_L1_smca1c7d20220707p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20230616 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1685 1835 Nominal wavelengths inside fitting window [nm]: 492.0102 492.1309 492.2515 492.3722 492.4928 492.6135 492.7341 492.8547 492.9753 493.0958 493.2164 493.3369 493.4574 493.5779 493.6984 493.8188 493.9393 494.0597 494.1801 494.3005 494.4209 494.5413 494.6616 494.7819 494.9022 495.0225 495.1428 495.2631 495.3833 495.5035 495.6237 495.7439 495.8641 495.9843 496.1044 496.2245 496.3446 496.4647 496.5848 496.7049 496.8249 496.9449 497.0649 497.1849 497.3049 497.4249 497.5448 497.6647 497.7846 497.9045 498.0244 498.1442 498.2641 498.3839 498.5037 498.6235 498.7432 498.8630 498.9827 499.1024 499.2221 499.3418 499.4615 499.5811 499.7008 499.8204 499.9400 500.0595 500.1791 500.2986 500.4182 500.5377 500.6572 500.7767 500.8961 501.0156 501.1350 501.2544 501.3738 501.4931 501.6125 501.7318 501.8512 501.9705 502.0897 502.2090 502.3283 502.4475 502.5667 502.6859 502.8051 502.9243 503.0434 503.1625 503.2816 503.4007 503.5198 503.6389 503.7579 503.8769 503.9960 504.1149 504.2339 504.3529 504.4718 504.5907 504.7096 504.8285 504.9474 505.0662 505.1851 505.3039 505.4227 505.5415 505.6602 505.7790 505.8977 506.0164 506.1351 506.2538 506.3724 506.4911 506.6097 506.7283 506.8469 506.9655 507.0840 507.2026 507.3211 507.4396 507.5581 507.6765 507.7950 507.9134 508.0318 508.1502 508.2686 508.3869 508.5053 508.6236 508.7419 508.8602 508.9785 509.0967 509.2149 509.3332 509.4514 509.5695 509.6877 509.8059 509.9240 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230616T113824.7Z 8567.485008 60 1 16.97 2 89.74 59.11 75.10 71.86 0.00 1 0.00 1 0 22 6.908e-03 6.748e-03 4.321e-04 4.304e-04 2.964050e+04 3.359205e+01 1.984327e+03 -6.000000e+00 3.756938e+02 279.00 -2.00 20.00 -2.00 505.45 0.00e+00 3.797778e-03 1.185242e-05 2.312675e-04 -6.000000e+00 1.912153e-04 279.00 -2.00 20.00 -2.00 500.89 0.00e+00 1.683363e+00 8.463318e-03 1.657916e-01 -6.000000e+00 1.378089e-01 231.69 -2.00 3.45 -2.00 502.41 0.00e+00 20.309 0.146 489.00 513.00 1 3.0681e+00 6.4504e-04 3.3239e-02 -6.0000e+00 1.0531e-02 -5.7900e-02 1.6189e-04 4.7443e-03 -6.0000e+00 2.7611e-03 6.7277e-03 1.9373e-03 3.3869e-05 2.2339e-04 -6.0000e+00 6.8640e-04 1.3272e-03 -8.9444e-05 12 9 9 12 1 1 -4.82 20.15 2.38 0.00133 0.01477 67 40 1 4 0 247.150 25.90 20.01 20.15 14.88 24.3 826.57 900000 -848 -277 569 694 1119 1561 1511 1284 939 691 442 49 -355 -443 -533 -347 -5 379 344 111 315 258 249 692 619 709 471 -52 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654 230 -92 -751 -1600 -1656 -1512 -1109 -234 -130 -100 -444 -679 -551 -220 -352 -395 -78 169 288 881 1395 1178 498 60 -458 -586 -74 719 881 796 855 427 171 331 -403 -635 -364 -666 -693 279 81 20 493 654 507 525 640 707 917 715 140 -510 -816 -632 SQ 20230616T114121.6Z 8567.487055 64 1 50.12 2 89.26 59.58 74.57 72.26 0.00 1 0.00 1 0 22 5.999e-03 5.847e-03 1.520e-04 1.514e-04 2.581717e+04 1.158627e+01 1.731445e+03 -6.000000e+00 3.262168e+02 279.00 -2.00 20.00 -2.00 505.43 0.00e+00 3.111570e-03 4.162820e-06 1.934186e-04 -6.000000e+00 1.660051e-04 279.00 -2.00 20.00 -2.00 500.80 0.00e+00 1.644138e+00 2.975492e-03 1.472475e-01 -6.000000e+00 1.193212e-01 231.69 -2.00 3.45 -2.00 502.34 0.00e+00 19.441 0.128 489.00 513.00 1 2.1010e+00 2.2710e-04 3.0580e-02 -6.0000e+00 9.1260e-03 -4.5681e-02 5.6831e-05 4.1837e-03 -6.0000e+00 2.3784e-03 1.9924e-02 1.2730e-03 1.2307e-05 2.0167e-04 -6.0000e+00 5.9411e-04 -3.3780e-05 -5.4187e-05 12 8 8 10 0 0 39.29 20.16 1.90 -0.00003 0.00880 568 112 1 4 0 88.240 25.90 20.00 20.16 15.01 24.2 827.02 -997 -802 -192 433 556 844 1256 1265 1064 875 615 426 -19 -383 -352 -456 -390 -38 354 309 114 291 210 283 615 584 568 449 8 -821 -903 -915 -944 -225 437 85 -141 -91 -373 -558 -436 -285 -128 138 395 550 437 387 168 -170 -742 -1049 -1255 -1289 -768 -201 101 187 252 139 261 481 556 484 463 236 -9 -155 -344 -665 -810 -690 -560 -404 36 -10 -391 -539 -629 -645 -489 -252 -210 -270 27 85 -196 -285 -186 -34 253 565 1018 1310 1080 953 727 132 -74 -785 -1568 -1675 -1425 -910 -286 -112 -132 -340 -630 -493 -197 -301 -326 -26 175 275 741 1195 1020 456 73 -289 -429 -22 593 606 627 690 307 191 308 -300 -570 -287 -549 -567 187 52 -30 401 528 336 467 503 580 669 467 61 -506 -727 -671 -909 -735 -172 401 531 825 1197 1224 1036 848 590 404 -18 -373 -340 -442 -367 -36 347 309 115 295 214 289 630 578 563 443 8 -817 -878 -887 -928 -227 434 87 -144 -92 -375 -558 -436 -287 -131 142 412 578 461 406 174 -174 -742 -1024 -1207 -1240 -749 -201 104 196 255 141 265 489 569 497 475 240 -9 -160 -351 -674 -813 -691 -565 -411 37 -10 -399 -541 -620 -628 -473 -244 -205 -266 27 85 -191 -289 -187 -34 250 561 1016 1303 1053 894 680 119 -65 -680 -1357 -1469 -1294 -835 -278 -109 -131 -339 -628 -490 -198 -306 -334 -27 179 281 764 1207 1052 475 75 -292 -442 -23 600 619 645 688 308 192 309 -299 -585 -292 -562 -565 189 53 -32 429 553 359 504 545 629 723 501 65 -534 -764 -708 SQ 20230616T114426.6Z 8567.489196 68 1 50.10 2 88.75 60.07 74.02 72.69 0.00 1 0.00 1 0 29 5.420e-03 5.293e-03 2.268e-04 2.260e-04 2.294044e+04 1.712061e+01 1.538644e+03 -6.000000e+00 2.947115e+02 279.00 -2.00 20.00 -2.00 505.42 0.00e+00 2.733397e-03 6.196038e-06 1.725882e-04 -6.000000e+00 1.499665e-04 279.00 -2.00 20.00 -2.00 500.73 0.00e+00 1.600865e+00 4.449705e-03 1.367592e-01 -6.000000e+00 1.077907e-01 231.69 -2.00 3.45 -2.00 502.28 0.00e+00 18.221 0.106 489.00 513.00 1 2.9663e+00 3.3925e-04 2.7747e-02 -6.0000e+00 8.2442e-03 -3.8184e-02 8.5215e-05 3.8094e-03 -6.0000e+00 2.1484e-03 9.8032e-03 8.0059e-04 1.8819e-05 1.7912e-04 -6.0000e+00 5.3680e-04 1.1580e-02 -1.1844e-04 12 8 8 10 0 0 74.33 20.17 1.54 0.01158 0.01713 393 78 1 4 0 127.460 25.90 20.01 20.17 15.11 24.1 827.47 -980 -810 -265 306 420 683 1145 1074 926 752 507 317 -30 -296 -333 -446 -380 1 303 234 36 177 160 259 579 575 512 436 -17 -727 -832 -842 -829 -176 492 65 -75 -41 -282 -504 -459 -54 -137 173 355 489 409 374 199 -90 -631 -978 -1119 -1208 -701 -152 66 188 212 126 245 371 545 447 453 243 -11 -93 -263 -565 -740 -588 -501 -344 58 0 -285 -499 -568 -624 -541 -286 -235 -296 -48 45 -194 -220 -148 -36 263 486 936 1200 950 848 625 181 -132 -689 -1425 -1478 -1274 -828 -174 -96 -120 -323 -605 -423 -164 -217 -240 41 193 307 700 1089 945 378 117 -222 -404 -50 501 556 502 571 210 146 333 -281 -456 -275 -534 -596 136 76 -40 392 467 319 395 448 537 610 423 0 -488 -684 -699 -896 -744 -249 282 400 666 1137 1083 939 759 507 313 -30 -286 -320 -431 -371 1 294 232 36 178 161 261 587 586 523 443 -17 -713 -798 -805 -803 -174 502 68 -78 -43 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