File name: Pandora57s1_BoulderCO_20231001_L2Fit_fout2c7d20220707p1-8.txt File generation date: 20250331T080307.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v7d20220707.txt Level 1 file used: Pandora57s1_BoulderCO_20231001_L1_smca1c7d20220707p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20231001 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1062 305.2469 305.3876 305.5283 305.6689 305.8096 305.9503 306.0909 306.2315 306.3722 306.5128 306.6534 306.7939 306.9345 307.0751 307.2156 307.3562 307.4967 307.6372 307.7777 307.9182 308.0587 308.1992 308.3396 308.4801 308.6205 308.7609 308.9013 309.0417 309.1821 309.3225 309.4629 309.6032 309.7436 309.8839 310.0242 310.1645 310.3048 310.4451 310.5854 310.7257 310.8659 311.0062 311.1464 311.2866 311.4268 311.5670 311.7072 311.8474 311.9875 312.1277 312.2678 312.4079 312.5480 312.6881 312.8282 312.9683 313.1084 313.2484 313.3885 313.5285 313.6685 313.8085 313.9485 314.0885 314.2285 314.3685 314.5084 314.6484 314.7883 314.9282 315.0681 315.2080 315.3479 315.4878 315.6276 315.7675 315.9073 316.0471 316.1869 316.3267 316.4665 316.6063 316.7461 316.8858 317.0256 317.1653 317.3050 317.4447 317.5844 317.7241 317.8638 318.0035 318.1431 318.2828 318.4224 318.5620 318.7016 318.8412 318.9808 319.1203 319.2599 319.3995 319.5390 319.6785 319.8180 319.9575 320.0970 320.2365 320.3760 320.5154 320.6548 320.7943 320.9337 321.0731 321.2125 321.3519 321.4913 321.6306 321.7700 321.9093 322.0486 322.1879 322.3272 322.4665 322.6058 322.7451 322.8843 323.0236 323.1628 323.3020 323.4412 323.5804 323.7196 323.8588 323.9980 324.1371 324.2762 324.4154 324.5545 324.6936 324.8327 324.9718 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231001T133733.4Z 8674.567748 247 1 50.28 2 83.17 100.04 69.64 272.01 0.00 1 0.00 1 0 17 4.950e-01 2.571e-02 3.819e-01 1.635e-02 7.798523e-01 9.309112e-03 8.029937e-03 -6.000000e+00 2.934824e-01 226.60 -2.00 3.45 -2.00 321.84 0.00e+00 6.959407e-04 3.967369e-03 9.465972e-04 -6.000000e+00 1.313551e-02 277.48 -2.00 20.00 -2.00 321.49 0.00e+00 7.712 0.008 302.00 328.00 3 2.9624e+00 2.9167e-02 7.5103e-02 -6.0000e+00 7.3788e-01 4.1567e-01 4.3165e-02 4.1100e-02 -6.0000e+00 8.0896e-01 -5.0121e-01 5.0208e-02 2.3043e-02 -6.0000e+00 4.6607e-01 2.0008e-01 2.4189e-02 7.7878e-03 -6.0000e+00 1.9390e-01 2.2013e-05 -1.1436e-03 4.9503e-04 1.0240e-04 -6.0000e+00 1.4655e-02 2.4802e-03 -4.8938e-05 12 9 8 11 8 0 82.28 20.22 0.32 0.00248 -0.00611 21 4 1 5 0 2393.920 26.00 20.00 20.22 23.14 24.4 808.57 900000 -245157 900000 -175425 -183996 900000 900000 900000 900000 -75915 900000 -190152 -73659 -89518 111420 -112052 900000 38390 -106093 -50667 900000 18653 -66453 900000 -94317 -35909 -121388 -41036 900000 900000 -32880 21157 -57050 -21607 21541 -5466 34932 71352 36605 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-2290 -98 -628 -684 2944 -2200 17888 687 221 36 142 1559 -1733 -718 -693 -1853 -1315 -2208 -351 -2105 -2620 -1978 -811 -1607 -3049 -1836 -358 -399 507 -2830 -1160 -1929 -416 248 2146 707 2766 1899 -196 3387 1552 224 -1745 2874 3307 143 829 1070 1851 -2596 910 510 1415 -326 -763 839 1203 -1459 -956 -3777 SS 20231001T134804.7Z 8674.575054 250 1 43.16 2 81.20 101.79 71.56 273.64 0.00 1 0.00 1 0 17 3.147e-01 1.088e-02 3.246e-01 7.631e-03 6.494598e-01 4.132844e-03 6.912798e-03 -6.000000e+00 1.815974e-01 226.60 -2.00 3.45 -2.00 321.33 0.00e+00 6.138028e-04 1.614027e-03 6.429506e-04 -6.000000e+00 7.811034e-03 277.48 -2.00 20.00 -2.00 320.98 0.00e+00 6.190 0.004 302.00 328.00 3 3.3134e+00 1.2476e-02 6.0745e-02 -6.0000e+00 4.5536e-01 3.4001e-02 1.7582e-02 3.3956e-02 -6.0000e+00 4.9821e-01 -2.6069e-02 2.0986e-02 1.8719e-02 -6.0000e+00 2.9102e-01 4.7103e-03 1.0399e-02 6.1693e-03 -6.0000e+00 1.2084e-01 6.2353e-05 -8.3148e-04 2.3178e-04 7.9258e-05 -6.0000e+00 8.9766e-03 2.4824e-03 -5.0150e-05 12 9 9 12 9 1 98.18 20.22 0.30 0.00248 -0.00377 26 6 1 5 0 1598.490 26.00 20.00 20.22 22.85 24.4 806.53 -57044 900000 -106947 96822 -47260 -144661 37900 900000 900000 34214 13518 900000 -94715 -139253 900000 148370 -38685 -55688 -63631 -45479 -74206 -18142 77547 -40057 -6322 43797 678 -2279 27576 -3110 -4492 -26965 -9688 9916 20125 2260 6247 -4463 5694 -2401 -9279 -8024 2622 -9212 5816 -221 16373 -9207 1802 -2346 6749 6000 4055 2369 36 -2746 3883 -4971 1464 -1969 1114 4811 4096 4453 1308 3481 882 4149 5345 3622 2664 1210 1454 2121 -1739 -319 -28 -35 -2184 -77 -536 -2269 -1821 -3307 -1998 411 -2446 688 1527 -2842 795 2352 1149 -114 226 196 -242 817 339 -723 328 -1112 -177 -95 -36 -200 12 -103 -1313 -107 247 35 566 519 -76 -650 -261 152 355 -108 289 91 310 656 104 -423 247 423 268 5 -704 -347 -1193 3800 -1081 -208 -261 -38 -302 127 -33 94 -24 -424 900000 -795 720 -351 -1076 282 900000 900000 254 101 900000 -1056 -3106 900000 1103 -527 -1001 -1340 -845 -1885 -270 577 -893 -110 488 12 -40 359 -62 -109 -969 -336 295 524 73 221 -213 303 -165 -765 -701 216 -873 483 -20 1288 -975 181 -267 790 792 601 389 6 -527 717 -995 268 -371 214 993 969 1167 365 930 243 1162 1534 1212 981 467 548 745 -577 -102 -8 -11 -805 -30 -248 -1209 -1051 -2059 -1318 281 -1802 502 1096 -2033 511 1400 676 -71 160 160 -229 869 386 -819 343 -1062 -156 -86 -35 -204 13 -120 -1703 -154 388 58 920 809 -113 -937 -381 231 571 -180 471 144 471 955 146 -576 328 593 424 8 -1375 -718 -2428 7817 -2497 -499 -638 -95 -743 298 -73 197 -54 SS 20231001T135956.3Z 8674.583291 255 1 50.09 2 78.98 103.79 73.73 275.46 0.00 1 0.00 1 0 25 1.687e-01 4.691e-03 4.971e-02 1.377e-03 5.582197e-01 7.201695e-04 6.135052e-03 -6.000000e+00 9.651188e-02 226.60 -2.00 3.45 -2.00 320.69 0.00e+00 1.539730e-03 2.465644e-04 4.172842e-04 -6.000000e+00 3.917863e-03 277.48 -2.00 20.00 -2.00 320.36 0.00e+00 5.052 0.002 302.00 328.00 3 1.6181e+00 2.0938e-03 5.0254e-02 -6.0000e+00 2.4084e-01 1.0483e-02 2.6643e-03 2.8635e-02 -6.0000e+00 2.6309e-01 -6.5713e-03 2.8696e-03 1.5189e-02 -6.0000e+00 1.5481e-01 -4.3687e-03 1.4757e-03 4.8015e-03 -6.0000e+00 6.4126e-02 9.0382e-04 -4.8479e-04 4.1289e-05 5.8812e-05 -6.0000e+00 4.7289e-03 2.5291e-03 -5.7905e-05 11 1 0 11 8 0 91.16 20.20 0.25 0.00253 -0.00111 285 56 1 5 0 175.730 26.00 20.00 20.20 22.46 24.5 804.78 -59417 -72408 -35035 -66013 -50456 -74253 -63512 -48316 -52820 -29520 -38368 -24321 -33603 -23603 -22222 -7788 -16917 -17350 -12665 -10833 -11062 -7433 -8196 -11767 -10655 -7693 -13333 -10453 -7599 -5336 -3842 -4800 1783 -5261 -336 -4239 -3795 860 -936 -183 -659 -1199 711 235 1082 -138 1115 -392 -1014 898 1170 2285 1734 1966 1177 1132 568 -153 597 242 1623 2236 2567 1858 844 144 -375 -460 1054 956 764 493 770 -47 87 -318 -809 -867 -526 -618 -669 -1302 -1779 -1556 -812 -841 78 390 623 1388 677 687 492 402 12 269 833 361 226 7 -495 -1033 -296 -515 -1059 -1169 -679 -594 -99 347 219 201 148 -144 -19 34 294 160 88 -254 -151 71 -140 274 383 -26 679 427 310 381 174 -19 -262 -277 -46 -123 168 -58 72 133 -96 -119 -277 -439 -691 -240 -585 -359 -688 -589 -441 -568 -270 -407 -261 -496 -396 -451 -159 -420 -475 -356 -314 -328 -217 -258 -419 -404 -298 -548 -403 -285 -215 -179 -263 103 -338 -20 -268 -271 70 -96 -22 -80 -155 94 32 148 -19 158 -58 -157 147 212 453 376 460 292 292 150 -40 153 62 433 657 847 677 316 52 -136 -173 436 450 392 262 399 -23 39 -129 -312 -343 -234 -322 -402 -885 -1313 -1215 -675 -745 71 365 576 1215 554 526 364 309 10 264 855 420 279 8 -560 -1066 -311 -511 -1137 -1323 -808 -755 -136 527 361 343 248 -232 -29 50 431 246 144 -432 -254 114 -220 413 551 -36 914 606 491 667 330 -36 -507 -568 -100 -281 391 -138 169 299 -205 -241 -553 SS 20231001T140518.8Z 8674.587023 258 1 50.10 2 77.99 104.70 74.71 276.29 0.00 1 0.00 1 0 25 9.518e-02 4.292e-03 2.828e-02 9.161e-04 5.190714e-01 4.713330e-04 5.710759e-03 -6.000000e+00 5.443971e-02 226.60 -2.00 3.45 -2.00 320.46 0.00e+00 8.986478e-04 1.514164e-04 3.448117e-04 -6.000000e+00 2.210049e-03 277.48 -2.00 20.00 -2.00 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