File name: Pandora57s1_BoulderCO_20231220_L2Fit_fout2c7d20220707p1-8.txt File generation date: 20250331T080209.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v7d20220707.txt Level 1 file used: Pandora57s1_BoulderCO_20231220_L1_smca1c7d20220707p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20231220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1062 305.2469 305.3876 305.5283 305.6689 305.8096 305.9503 306.0909 306.2315 306.3722 306.5128 306.6534 306.7939 306.9345 307.0751 307.2156 307.3562 307.4967 307.6372 307.7777 307.9182 308.0587 308.1992 308.3396 308.4801 308.6205 308.7609 308.9013 309.0417 309.1821 309.3225 309.4629 309.6032 309.7436 309.8839 310.0242 310.1645 310.3048 310.4451 310.5854 310.7257 310.8659 311.0062 311.1464 311.2866 311.4268 311.5670 311.7072 311.8474 311.9875 312.1277 312.2678 312.4079 312.5480 312.6881 312.8282 312.9683 313.1084 313.2484 313.3885 313.5285 313.6685 313.8085 313.9485 314.0885 314.2285 314.3685 314.5084 314.6484 314.7883 314.9282 315.0681 315.2080 315.3479 315.4878 315.6276 315.7675 315.9073 316.0471 316.1869 316.3267 316.4665 316.6063 316.7461 316.8858 317.0256 317.1653 317.3050 317.4447 317.5844 317.7241 317.8638 318.0035 318.1431 318.2828 318.4224 318.5620 318.7016 318.8412 318.9808 319.1203 319.2599 319.3995 319.5390 319.6785 319.8180 319.9575 320.0970 320.2365 320.3760 320.5154 320.6548 320.7943 320.9337 321.0731 321.2125 321.3519 321.4913 321.6306 321.7700 321.9093 322.0486 322.1879 322.3272 322.4665 322.6058 322.7451 322.8843 323.0236 323.1628 323.3020 323.4412 323.5804 323.7196 323.8588 323.9980 324.1371 324.2762 324.4154 324.5545 324.6936 324.8327 324.9718 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231220T152145.2Z 8754.640106 91 1 15.57 2 81.05 131.11 132.30 34.09 0.00 1 0.00 1 0 17 5.134e-01 2.042e-02 3.638e-01 1.294e-02 7.802760e-01 6.976101e-03 8.372160e-03 -6.000000e+00 2.911274e-01 222.38 -2.00 3.45 -2.00 321.45 0.00e+00 8.902492e-03 2.813280e-03 8.128194e-04 -6.000000e+00 1.277027e-02 267.73 -2.00 20.00 -2.00 321.11 0.00e+00 6.104 0.004 302.00 328.00 3 3.6662e+00 2.1158e-02 6.3414e-02 -6.0000e+00 7.1921e-01 3.4498e-01 2.9660e-02 3.9880e-02 -6.0000e+00 7.8880e-01 -4.6992e-01 3.4133e-02 2.2182e-02 -6.0000e+00 4.6419e-01 2.0547e-01 1.6859e-02 7.4155e-03 -6.0000e+00 1.9690e-01 3.8443e-05 -1.1838e-03 3.5950e-04 1.0070e-04 -6.0000e+00 1.4562e-02 3.4748e-03 1.1996e-05 12 9 9 12 1 1 80.42 19.99 -0.07 0.00347 -0.00542 5 4 1 5 0 2594.690 25.79 20.00 19.99 14.37 23.5 885.61 900000 -196493 900000 -93979 -69918 900000 -164127 -189610 -171252 -28483 -212913 900000 900000 1156 -68263 -488 -130750 -120568 -68054 133020 160901 108130 -71327 -12339 60440 52556 -53946 86385 -95658 -46045 -48636 -4581 9539 -1454 -820 -29566 7186 48468 56551 43862 35857 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-96 -2725 -169 -692 251 2270 -503 -2462 301 336 -1938 95 -2604 -14 -1155 -306 937 229 155 -1690 398 -1934 1056 -2052 1098 762 55 768 2433 1388 2917 -277 2735 1626 1159 -751 261 -1309 -999 683 3575 -1315 -810 -693 2847 -1574 -426 -601 92 -2579 SS 20231220T153824.1Z 8754.651668 100 1 18.39 2 78.70 134.17 130.42 38.77 0.00 1 0.00 1 0 25 3.946e-01 9.014e-03 2.978e-01 7.264e-03 6.729078e-01 3.997327e-03 7.254491e-03 -6.000000e+00 2.304645e-01 222.38 -2.00 3.45 -2.00 320.96 0.00e+00 2.726937e-03 1.507132e-03 6.026894e-04 -6.000000e+00 1.292729e-02 267.73 -2.00 20.00 -2.00 320.63 0.00e+00 4.940 0.002 302.00 328.00 3 4.0684e+00 1.1674e-02 5.2417e-02 -6.0000e+00 5.7525e-01 -1.9986e-02 1.6619e-02 3.4231e-02 -6.0000e+00 6.3573e-01 1.0912e-01 2.0483e-02 1.9205e-02 -6.0000e+00 3.6309e-01 -6.1384e-02 1.0257e-02 6.3807e-03 -6.0000e+00 1.6330e-01 7.3967e-05 -4.8682e-04 2.1719e-04 7.3689e-05 -6.0000e+00 1.1743e-02 2.3133e-03 -1.7690e-06 12 9 1 12 1 1 98.51 20.02 0.89 0.00231 -0.00134 8 5 1 5 0 2043.670 25.79 20.00 20.02 15.15 23.6 890.47 900000 900000 900000 900000 900000 900000 -89278 900000 900000 900000 900000 900000 900000 900000 167357 -15276 900000 281230 70391 88439 900000 900000 -39367 49739 24653 -1279 158236 58626 29749 88435 95305 47762 34554 10036 -18228 45331 -20591 7195 2850 2529 -3206 -22086 17786 -9955 -6908 -1900 8622 -3460 -4969 1334 2238 7003 5605 3043 1579 -5810 1550 -3555 4506 5389 2288 -534 2868 -2177 -5781 1740 -4633 -959 981 -3564 2874 459 729 2603 1827 3937 -1426 -246 2252 1385 -565 -1792 -2935 -719 -266 -166 -512 575 1480 695 665 126 280 -117 931 1242 193 858 1339 -426 182 -1630 -1260 766 -1705 -519 -584 -286 127 58 759 146 -541 -633 478 -279 296 -277 -144 -741 -765 375 406 -116 337 240 1351 627 -323 19 -74 -298 -594 998 -792 138 173 195 658 -62 605 -327 -1100 900000 900000 900000 900000 900000 900000 -630 900000 900000 900000 900000 900000 900000 900000 1182 -135 900000 1986 497 625 900000 900000 -764 439 305 -22 1117 552 385 729 897 871 834 325 -703 1040 -962 309 158 168 -253 -2267 1295 -984 -679 -184 777 -370 -575 159 298 997 892 542 303 -1253 318 -761 866 1024 473 -127 757 -675 -1925 528 -1510 -317 358 -1443 1187 200 332 1089 698 1330 -486 -86 886 652 -294 -1069 -1923 -488 -192 -127 -410 464 1171 528 469 84 182 -81 720 1109 188 942 1557 -495 195 -1592 -1214 737 -1798 -530 -632 -332 162 83 1108 224 -831 -933 701 -398 425 -418 -215 -1137 -1151 570 595 -163 455 313 1701 846 -497 31 -131 -559 -1175 2062 -1671 301 385 438 1456 -130 1270 -655 -2168 SS 20231220T154324.9Z 8754.655150 103 1 49.70 2 78.02 135.12 129.81 40.12 0.00 1 0.00 1 0 17 3.824e-01 1.619e-02 2.049e-01 6.196e-03 6.270272e-01 3.214945e-03 6.909732e-03 -6.000000e+00 2.152269e-01 222.38 -2.00 3.45 -2.00 321.01 0.00e+00 3.993798e-03 1.174613e-03 5.111491e-04 -6.000000e+00 8.879480e-03 267.73 -2.00 20.00 -2.00 320.68 0.00e+00 4.679 0.002 302.00 328.00 3 4.1452e+00 9.3853e-03 4.9346e-02 -6.0000e+00 5.3209e-01 9.8916e-02 1.2284e-02 3.1577e-02 -6.0000e+00 5.8307e-01 -1.2251e-01 1.3501e-02 1.7068e-02 -6.0000e+00 3.4415e-01 5.3612e-02 6.9016e-03 5.4988e-03 -6.0000e+00 1.4376e-01 8.7680e-05 -1.6360e-03 1.8048e-04 7.3313e-05 -6.0000e+00 1.0709e-02 4.4431e-03 -1.1687e-04 12 8 8 10 0 0 99.95 20.02 -0.10 0.00444 -0.00785 51 10 1 5 0 974.540 25.90 20.00 20.02 15.17 23.5 890.45 -161385 25151 -169652 -80029 -156818 -150043 -131781 -92565 -50512 -128083 31363 -104980 -87810 -30620 -59023 11265 -41186 9931 -30199 -29309 1721 -42040 89450 -37663 -8527 -18567 -10404 -22561 -35024 -782 -26529 -18907 -21714 5426 -6711 -11063 15900 -12471 5111 -6792 -2328 -815 3788 2076 -3899 5003 2124 3065 10602 3836 13244 6793 3610 4611 999 4351 2619 3978 227 647 552 2894 8279 1355 7696 1090 2148 -2522 1754 2847 -549 27943 -1095 1729 -72 -962 1327 -3451 1157 -2136 -916 -1815 -3488 -1519 -1936 1534 -1131 1022 -275 -3579 2758 47 986 -998 -1042 -834 -38 351 -1007 758 -915 -294 -161 -1261 -448 -2201 84 -1148 -9 16 -45 890 -318 -350 -699 -276 -277 -377 125 -28 41 672 352 1519 504 1918 544 1348 -163 -28 275 -590 -538 4355 -647 -698 142 -437 -418 251 -460 75 -1068 -2763 152 -3759 -685 -2685 -2418 -1924 -1025 -444 -2386 190 -1956 -1769 -447 -1427 159 -1099 175 -852 -856 37 -1418 934 -1384 -249 -626 -325 -773 -1376 -24 -1282 -1000 -1345 265 -355 -624 769 -954 399 -701 -254 -94 435 248 -503 605 271 401 1351 564 1974 1197 661 902 213 926 577 852 49 139 124 709 2182 424 2321 342 664 -851 632 1155 -250 9845 -503 722 -28 -337 431 -1216 443 -997 -489 -1106 -2339 -1057 -1445 1173 -927 837 -226 -2895 1943 32 643 -694 -816 -752 -39 408 -1265 919 -1048 -301 -152 -1233 -466 -2447 97 -1435 -12 24 -75 1517 -544 -572 -1082 -409 -415 -591 207 -48 69 1074 546 2233 717 2588 726 1885 -259 -49 530 -1214 -1075 8763 -1458 -1640 337 -1057 -1001 569 -986 163 -2286 SS 20231220T154805.1Z 8754.658392 106 1 50.13 2 77.39 136.00 129.24 41.36 0.00 1 0.00 1 0 25 1.917e-01 4.723e-03 7.193e-02 1.460e-03 6.135350e-01 7.523448e-04 6.710412e-03 -6.000000e+00 1.079204e-01 222.38 -2.00 3.45 -2.00 320.76 0.00e+00 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