File name: Pandora21s1_Bremen_20200519_L2Fit_fout2c2d20191026p1-8.txt File generation date: 20240830T035158.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v3d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200519_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1190 305.2593 305.3995 305.5398 305.6801 305.8203 305.9606 306.1008 306.2410 306.3812 306.5214 306.6616 306.8018 306.9419 307.0821 307.2222 307.3624 307.5025 307.6426 307.7827 307.9228 308.0629 308.2029 308.3430 308.4830 308.6231 308.7631 308.9031 309.0431 309.1831 309.3231 309.4631 309.6031 309.7430 309.8830 310.0229 310.1628 310.3027 310.4426 310.5825 310.7224 310.8623 311.0021 311.1420 311.2818 311.4216 311.5615 311.7013 311.8411 311.9809 312.1206 312.2604 312.4002 312.5399 312.6796 312.8194 312.9591 313.0988 313.2385 313.3781 313.5178 313.6575 313.7971 313.9368 314.0764 314.2160 314.3556 314.4952 314.6348 314.7744 314.9139 315.0535 315.1930 315.3325 315.4721 315.6116 315.7511 315.8906 316.0300 316.1695 316.3090 316.4484 316.5879 316.7273 316.8667 317.0061 317.1455 317.2849 317.4242 317.5636 317.7030 317.8423 317.9816 318.1209 318.2603 318.3995 318.5388 318.6781 318.8174 318.9566 319.0959 319.2351 319.3743 319.5135 319.6527 319.7919 319.9311 320.0703 320.2094 320.3486 320.4877 320.6268 320.7659 320.9050 321.0441 321.1832 321.3223 321.4613 321.6004 321.7394 321.8785 322.0175 322.1565 322.2955 322.4345 322.5734 322.7124 322.8513 322.9903 323.1292 323.2681 323.4070 323.5459 323.6848 323.8237 323.9625 324.1014 324.2402 324.3791 324.5179 324.6567 324.7955 324.9343 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200519T064040.8Z 7444.278250 432 1 37.57 2 62.38 93.30 57.81 138.03 0.00 1 0.00 1 0 17 1.189e-02 4.707e-03 1.037e-02 2.016e-03 3.058970e-01 1.054328e-03 3.996473e-03 -6.000000e+00 7.152802e-03 231.48 -2.00 3.88 -2.00 318.32 0.00e+00 6.125988e-05 1.790170e-04 1.002500e-04 -6.000000e+00 2.844861e-04 276.73 -2.00 20.00 -2.00 317.99 0.00e+00 2.145 0.000 302.00 328.00 3 4.3534e+00 2.8394e-03 2.7890e-02 -6.0000e+00 1.8050e-02 2.2188e-02 3.1788e-03 1.7629e-02 -6.0000e+00 1.9587e-02 4.6905e-03 2.1085e-03 8.7193e-03 -6.0000e+00 1.1480e-02 -6.4932e-03 1.0846e-03 2.4835e-03 -6.0000e+00 4.7119e-03 5.4687e-04 5.0117e-05 6.4162e-05 3.0031e-05 -6.0000e+00 3.5790e-04 -4.0097e-03 1.7359e-04 12 1 1 12 1 1 99.98 22.47 0.10 -0.00401 -0.00363 70 19 1 5 0 519.357 25.39 20.00 22.47 21.36 16.6 1018.37 -3345 -2725 -4401 -3114 19 988 -1683 4379 -1950 -3821 -1552 -3414 -290 -1198 2540 -3702 157 -599 -1392 -718 1690 1288 528 1504 510 -144 -3121 -1014 -302 357 209 1984 414 -1459 -637 -315 435 544 357 123 -925 -1061 -1820 -874 -715 -535 -763 -497 -735 384 744 43 986 708 715 625 891 1045 963 1039 1616 1223 968 331 34 502 63 446 821 394 331 -390 -531 -397 -278 -506 298 394 640 -126 -199 -1133 -1359 -1401 -983 -585 -393 -300 4 330 117 511 825 1114 754 674 804 182 -273 -331 -213 -401 69 -133 -606 -588 -710 -376 17 91 51 -75 -109 8 176 442 344 226 158 -258 -485 35 -115 250 281 357 726 902 469 77 29 301 -54 293 -285 -31 15 -196 -194 54 -168 -134 -265 -209 -181 -298 -196 1 56 -105 289 -149 -308 -125 -299 -28 -133 308 -519 22 -90 -220 -117 273 211 90 270 97 -28 -626 -191 -54 64 40 410 93 -337 -142 -71 106 155 120 47 -389 -467 -829 -399 -327 -244 -345 -221 -326 173 352 22 525 396 413 370 534 624 569 614 982 796 678 245 25 351 42 295 577 306 276 -340 -462 -334 -220 -368 199 256 434 -95 -166 -1039 -1325 -1433 -1059 -664 -465 -363 5 385 130 524 793 1052 748 726 946 234 -367 -442 -272 -482 80 -156 -754 -768 -964 -528 25 140 82 -123 -175 12 252 605 469 316 233 -399 -765 55 -176 370 402 491 963 1198 654 114 44 478 -87 490 -499 -56 27 -371 -368 102 -307 -238 -462 SS 20200519T065901.3Z 7444.290988 444 1 26.68 2 59.63 97.11 56.03 142.96 0.00 1 0.00 1 0 17 1.444e-02 5.688e-03 1.289e-02 3.164e-03 2.818996e-01 1.656346e-03 3.699733e-03 -6.000000e+00 8.688158e-03 231.48 -2.00 3.88 -2.00 317.85 0.00e+00 -2.322674e-04 2.482175e-04 8.020131e-05 -6.000000e+00 3.456047e-04 276.73 -2.00 20.00 -2.00 317.52 0.00e+00 1.970 0.000 302.00 328.00 3 5.2327e+00 4.4273e-03 2.5637e-02 -6.0000e+00 2.1924e-02 2.7239e-02 4.9420e-03 1.6223e-02 -6.0000e+00 2.3792e-02 6.0461e-03 3.1261e-03 7.9940e-03 -6.0000e+00 1.3944e-02 -6.7649e-03 1.5708e-03 2.2592e-03 -6.0000e+00 5.7230e-03 2.7887e-04 5.1712e-05 1.0015e-04 2.7576e-05 -6.0000e+00 4.3479e-04 -4.0266e-03 1.4826e-04 12 1 1 12 1 1 99.99 22.48 0.10 -0.00403 -0.00364 16 6 1 5 0 1558.710 25.39 20.00 22.48 21.70 16.5 1019.27 904 4099 -6900 2543 -2350 -527 1291 -522 2922 -7336 -2722 -1023 -4018 -714 2923 331 -1142 1825 -640 883 -1218 2388 -1097 2439 487 -368 818 -3902 229 612 2542 679 -271 -252 -2224 -1460 -601 874 950 -131 -1004 -1070 -1225 21 -2029 -1257 -460 -1983 -1101 -405 1269 1271 2104 626 146 530 442 416 816 894 1000 2181 1716 277 -252 503 -805 938 443 742 49 -172 43 -205 466 -99 -1135 405 275 345 -1024 -832 -1592 -1002 -808 -153 -185 -258 486 -314 430 101 615 458 134 1006 514 83 -426 -13 -434 -182 -39 -72 -1219 -725 -590 -142 172 -17 76 -226 355 135 -33 183 355 538 -339 -173 -344 -360 -218 334 521 775 1229 848 314 429 -13 -237 53 -16 -358 162 334 102 -281 -23 -48 -573 -319 72 336 -628 198 -179 -39 102 -47 276 -794 -286 -112 -510 -100 445 56 -205 333 -124 174 -249 476 -234 532 114 -89 193 -915 49 132 573 168 -72 -68 -588 -387 -174 290 369 -58 -486 -540 -634 11 -1067 -654 -235 -1007 -551 -205 666 708 1227 386 93 345 292 274 529 580 668 1535 1294 221 -201 377 -580 660 333 610 43 -158 39 -182 387 -76 -816 279 198 272 -899 -789 -1606 -1053 -893 -178 -223 -319 597 -377 486 107 609 445 137 1097 611 106 -573 -17 -556 -220 -46 -85 -1533 -951 -802 -199 251 -26 120 -363 556 201 -47 247 476 741 -493 -262 -532 -555 -329 489 733 1049 1605 1111 431 619 -20 -367 83 -25 -604 283 596 184 -513 -41 -84 -984 -538 SS 20200519T070817.1Z 7444.297420 447 1 4.14 2 58.25 99.07 55.21 145.51 0.00 1 0.00 1 0 17 1.915e-02 8.633e-03 1.703e-02 6.701e-03 2.776350e-01 3.539566e-03 3.734423e-03 -6.000000e+00 1.151291e-02 231.48 -2.00 3.88 -2.00 316.73 0.00e+00 -2.605320e-04 4.003766e-04 5.438920e-05 -6.000000e+00 4.584463e-04 276.73 -2.00 20.00 -2.00 316.40 0.00e+00 1.893 0.000 302.00 328.00 3 4.8745e+00 9.3250e-03 2.4965e-02 -6.0000e+00 2.9050e-02 4.7651e-02 1.0364e-02 1.6070e-02 -6.0000e+00 3.1534e-02 -9.1428e-03 6.1018e-03 7.8832e-03 -6.0000e+00 1.8482e-02 -3.1010e-03 2.8775e-03 2.1941e-03 -6.0000e+00 7.5804e-03 4.3060e-04 -1.0492e-03 2.0711e-04 2.9022e-05 -6.0000e+00 5.7672e-04 -3.5729e-03 -4.1450e-05 12 9 1 12 1 1 999.00 22.48 0.21 -0.00357 -0.01146 1 5 1 5 0 1982.674 25.39 20.00 22.48 22.15 16.6 1022.32 7661 -3054 -4796 -7912 -2038 -2079 -6355 3864 -75 -6142 1910 4251 1966 5340 3551 2220 -3542 1315 -1443 196 -1167 -1143 -1145 -2759 -1322 -2652 -723 -1959 3238 66 662 4079 2715 -2415 -1959 1979 -1732 -597 -1005 -339 1409 -301 183 -1047 670 -396 -995 275 1395 781 1100 1876 -295 -140 -1176 677 730 750 1349 1593 787 411 401 -80 1696 -447 1083 -1832 1752 882 168 -372 980 -305 -1900 -1288 -778 -363 1086 -905 -905 -1797 -2545 -585 -539 -262 -304 606 -750 -101 797 168 189 595 1940 685 448 459 -828 333 -130 -181 -371 -527 -1144 -722 -413 -572 484 -298 467 30 82 -84 -566 1485 102 145 -406 -94 -232 -183 -271 143 253 1312 2227 1147 387 -263 649 -568 146 746 28 -965 307 3 -314 -363 -728 292 -529 991 -461 -733 -1166 -266 -270 -921 567 -12 -1099 322 742 388 1151 861 583 -1015 376 -435 60 -365 -360 -370 -947 -468 -970 -257 -673 1026 21 225 1442 1021 -951 -746 736 -716 -277 -532 -197 860 -192 119 -688 434 -258 -643 174 868 494 722 1283 -213 -105 -902 522 568 582 1033 1219 619 340 349 -72 1502 -385 888 -1519 1484 806 162 -371 965 -295 -1779 -1128 -641 -291 889 -806 -866 -1835 -2723 -640 -613 -309 -370 748 -933 -123 922 185 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