File name: Pandora21s1_Bremen_20200525_L2Fit_fout2c2d20191026p1-8.txt File generation date: 20240830T035722.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v3d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200525_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1190 305.2593 305.3995 305.5398 305.6801 305.8203 305.9606 306.1008 306.2410 306.3812 306.5214 306.6616 306.8018 306.9419 307.0821 307.2222 307.3624 307.5025 307.6426 307.7827 307.9228 308.0629 308.2029 308.3430 308.4830 308.6231 308.7631 308.9031 309.0431 309.1831 309.3231 309.4631 309.6031 309.7430 309.8830 310.0229 310.1628 310.3027 310.4426 310.5825 310.7224 310.8623 311.0021 311.1420 311.2818 311.4216 311.5615 311.7013 311.8411 311.9809 312.1206 312.2604 312.4002 312.5399 312.6796 312.8194 312.9591 313.0988 313.2385 313.3781 313.5178 313.6575 313.7971 313.9368 314.0764 314.2160 314.3556 314.4952 314.6348 314.7744 314.9139 315.0535 315.1930 315.3325 315.4721 315.6116 315.7511 315.8906 316.0300 316.1695 316.3090 316.4484 316.5879 316.7273 316.8667 317.0061 317.1455 317.2849 317.4242 317.5636 317.7030 317.8423 317.9816 318.1209 318.2603 318.3995 318.5388 318.6781 318.8174 318.9566 319.0959 319.2351 319.3743 319.5135 319.6527 319.7919 319.9311 320.0703 320.2094 320.3486 320.4877 320.6268 320.7659 320.9050 321.0441 321.1832 321.3223 321.4613 321.6004 321.7394 321.8785 322.0175 322.1565 322.2955 322.4345 322.5734 322.7124 322.8513 322.9903 323.1292 323.2681 323.4070 323.5459 323.6848 323.8237 323.9625 324.1014 324.2402 324.3791 324.5179 324.6567 324.7955 324.9343 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200525T104629.9Z 7450.448957 600 1 27.73 2 32.72 164.66 44.01 115.15 0.00 1 0.00 1 0 17 9.407e-03 5.802e-03 5.184e-03 2.734e-03 1.939716e-01 1.449614e-03 2.563338e-03 -6.000000e+00 5.669822e-03 231.98 -2.00 3.88 -2.00 315.97 0.00e+00 2.341895e-04 1.374883e-04 3.046932e-05 -6.000000e+00 2.250645e-04 277.50 -2.00 20.00 -2.00 315.66 0.00e+00 1.188 0.000 302.00 328.00 3 6.0206e+00 3.7950e-03 1.6412e-02 -6.0000e+00 1.4325e-02 5.5707e-02 4.2092e-03 1.1082e-02 -6.0000e+00 1.5539e-02 -3.0069e-03 2.4170e-03 5.4215e-03 -6.0000e+00 9.1036e-03 -1.6125e-03 1.0825e-03 1.5045e-03 -6.0000e+00 3.7330e-03 3.1280e-04 2.5222e-04 8.4907e-05 2.0312e-05 -6.0000e+00 2.8319e-04 -3.8430e-03 2.0502e-04 12 1 1 12 1 1 99.95 22.43 0.17 -0.00384 -0.00195 9 4 1 5 0 2754.909 25.39 20.00 22.43 20.06 16.9 997.15 808 -2201 -612 -3543 -362 -3445 2082 1257 -374 -2204 -459 76 -981 1905 -264 1920 -640 1570 259 -698 452 316 1280 328 2601 -983 -735 -1597 1359 426 612 2434 202 -1592 -1858 -564 -1174 710 -565 511 -641 -551 -776 -1488 -291 -1010 -551 -546 -1062 -207 607 951 937 1127 807 1089 90 872 38 701 1526 1083 1133 430 306 -236 -430 -915 558 25 862 221 20 -79 -423 -144 -1099 -61 -777 -891 -663 -867 -1773 -945 -274 -293 121 55 624 10 198 -38 105 158 -235 162 291 845 -251 454 110 -199 -180 -374 -1105 -747 -373 -318 191 448 524 6 447 -375 -322 65 -481 342 -527 -139 -280 548 87 744 540 278 435 487 185 165 271 44 334 -207 -249 -200 647 -22 -296 159 -338 -420 -445 177 -520 -141 -774 -71 -679 415 278 -90 -553 -113 19 -274 575 -89 671 -235 581 100 -277 179 125 513 138 1112 -441 -322 -669 526 164 243 1003 88 -708 -796 -239 -542 369 -340 339 -457 -405 -581 -1125 -217 -752 -400 -386 -740 -144 433 707 724 898 657 898 75 723 31 578 1282 961 1057 415 292 -213 -366 -769 485 23 859 228 21 -80 -406 -127 -910 -48 -634 -784 -632 -884 -1905 -1049 -317 -356 152 71 798 13 235 -42 110 159 -245 179 345 1061 -329 587 137 -236 -207 -440 -1372 -965 -496 -434 269 651 783 9 653 -524 -424 82 -601 436 -708 -195 -401 779 122 1011 710 353 533 593 233 217 366 61 463 -295 -368 -305 1004 -36 -471 249 -523 -636 -665 SS 20200525T105133.9Z 7450.452476 603 1 7.82 2 32.53 166.82 43.34 116.47 0.00 1 0.00 1 0 17 8.238e-03 5.741e-03 3.521e-03 2.262e-03 1.825501e-01 1.210378e-03 2.410953e-03 -6.000000e+00 4.966155e-03 231.98 -2.00 3.88 -2.00 315.22 0.00e+00 2.168125e-04 9.808382e-05 2.242579e-05 -6.000000e+00 1.971060e-04 277.50 -2.00 20.00 -2.00 314.93 0.00e+00 1.185 0.000 302.00 328.00 3 4.7902e+00 3.1475e-03 1.5892e-02 -6.0000e+00 1.2547e-02 2.3477e-02 3.4832e-03 1.0391e-02 -6.0000e+00 1.3610e-02 4.6221e-03 1.9831e-03 5.0752e-03 -6.0000e+00 7.9735e-03 -2.8318e-03 8.5941e-04 1.4037e-03 -6.0000e+00 3.2700e-03 1.1106e-03 2.6649e-04 6.9628e-05 1.9964e-05 -6.0000e+00 2.4801e-04 -4.6871e-03 2.0416e-04 12 1 1 12 1 1 99.95 22.44 0.23 -0.00469 -0.00268 8 12 1 5 0 849.381 25.39 20.00 22.44 20.43 16.9 999.72 -647 -2234 -2310 -2818 -2380 984 -97 2987 -832 639 -1556 253 260 801 1047 -406 837 -10 1479 293 267 692 790 380 9 -571 -1301 -401 397 1020 1139 2184 451 -1088 -700 -336 185 468 644 -449 -273 -712 -749 -1178 -1133 -1017 -1394 -606 -447 518 207 1104 517 862 1031 649 465 250 987 827 1367 974 1430 491 -484 15 -227 -295 400 288 82 44 -125 -429 -149 -18 -254 -95 333 -788 -584 -1320 -1371 -1271 -1039 -484 -409 -47 205 202 261 488 383 513 335 600 868 205 -210 -135 -283 -272 189 -248 -676 -679 -544 -368 -136 131 -456 224 0 194 -252 709 567 295 129 -272 -323 67 199 549 733 484 833 794 272 564 69 -25 -45 268 -286 -223 -41 7 -158 -319 -215 -482 -286 -192 -700 -716 -820 -641 253 -26 871 -266 206 -508 84 93 310 437 -179 375 -5 688 140 129 333 386 192 5 -304 -685 -201 189 476 546 1085 235 -572 -355 -170 100 281 433 -331 -212 -568 -606 -960 -921 -820 -1108 -468 -340 392 161 885 430 734 890 568 410 220 860 722 1216 905 1381 488 -478 14 -203 -260 364 280 84 46 -132 -443 -147 -17 -222 -80 286 -725 -573 -1372 -1480 -1416 -1201 -581 -506 -59 258 249 308 543 404 528 353 663 1015 253 -267 -171 -346 -320 216 -289 -825 -857 -704 -488 -185 183 -653 320 1 261 -323 871 692 368 167 -367 -445 92 270 726 940 604 1008 955 337 720 91 -34 -61 366 -404 -323 -61 10 -237 -477 -315 -698 -409 SS 20200525T111302.2Z 7450.467387 612 1 26.47 2 32.05 176.16 40.59 122.33 0.00 1 0.00 1 0 17 8.347e-03 5.255e-03 4.597e-03 2.409e-03 1.881307e-01 1.276412e-03 2.475745e-03 -6.000000e+00 5.031984e-03 231.98 -2.00 3.88 -2.00 316.01 0.00e+00 2.497530e-04 1.217350e-04 2.989235e-05 -6.000000e+00 1.997116e-04 277.50 -2.00 20.00 -2.00 315.69 0.00e+00 1.179 0.000 302.00 328.00 3 5.7505e+00 3.3432e-03 1.6090e-02 -6.0000e+00 1.2714e-02 4.3102e-02 3.7083e-03 1.0724e-02 -6.0000e+00 1.3790e-02 1.2646e-03 2.1299e-03 5.2439e-03 -6.0000e+00 8.0792e-03 -3.3582e-03 9.5398e-04 1.4562e-03 -6.0000e+00 3.3134e-03 4.1993e-04 4.0313e-04 7.4978e-05 1.9504e-05 -6.0000e+00 2.5129e-04 -4.4684e-03 2.1849e-04 12 1 1 12 1 1 99.97 22.44 0.07 -0.00447 -0.00144 17 7 1 5 0 1460.952 25.39 20.00 22.44 21.09 16.8 1001.09 -2145 -660 -3072 -1822 -1274 440 608 1264 635 1425 -156 -1054 3509 -524 1002 -1033 785 633 82 8 472 817 -199 1151 107 -892 -2067 -1456 -529 521 2166 628 1533 -1326 -383 -797 581 283 380 -192 -945 -368 -240 -646 -257 -241 -922 -1916 -897 28 464 1014 1187 307 157 683 495 156 725 272 1291 1583 1040 466 52 567 -1049 82 380 827 334 367 82 -533 329 -449 -203 -857 36 -655 -1012 -831 -1488 -1198 -969 -322 -186 242 149 478 98 73 464 219 318 175 603 246 62 3 -282 -521 -111 134 -1001 -294 -535 -300 47 -99 48 334 164 70 134 -297 -127 -129 18 -308 159 49 201 720 340 695 521 452 -165 235 143 261 114 293 112 -84 132 33 3 -104 -423 -626 -362 -482 -153 -719 -391 -250 83 122 279 151 345 -38 -268 934 -160 332 -368 283 234 31 3 186 320 -80 477 47 -397 -910 -604 -207 198 840 260 658 -582 -160 -335 262 146 225 -128 -671 -269 -178 -483 -191 -178 -669 -1362 -621 19 329 749 911 245 128 562 411 129 593 224 1083 1394 968 449 49 507 -893 68 329 773 333 378 84 -537 313 -397 -166 -676 29 -572 -961 -843 -1590 -1329 -1125 -391 -235 311 191 597 116 81 479 220 328 193 711 310 81 4 -352 -617 -127 156 -1242 -379 -713 -411 66 -145 72 502 241 98 176 -373 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