File name: Pandora21s1_Bremen_20200702_L2Fit_fwvt1c14d20191026p1-8.txt File generation date: 20250507T103534.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v14d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200702_L1_smca1c14d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1712 1862 Nominal wavelengths inside fitting window [nm]: 492.0415 492.1620 492.2825 492.4029 492.5233 492.6437 492.7641 492.8844 493.0048 493.1251 493.2454 493.3657 493.4860 493.6063 493.7265 493.8468 493.9670 494.0872 494.2074 494.3275 494.4477 494.5678 494.6879 494.8081 494.9281 495.0482 495.1683 495.2883 495.4083 495.5283 495.6483 495.7683 495.8883 496.0082 496.1281 496.2480 496.3679 496.4878 496.6077 496.7275 496.8474 496.9672 497.0870 497.2067 497.3265 497.4463 497.5660 497.6857 497.8054 497.9251 498.0448 498.1644 498.2840 498.4037 498.5233 498.6429 498.7624 498.8820 499.0015 499.1210 499.2405 499.3600 499.4795 499.5990 499.7184 499.8378 499.9572 500.0766 500.1960 500.3154 500.4347 500.5540 500.6734 500.7927 500.9119 501.0312 501.1504 501.2697 501.3889 501.5081 501.6273 501.7464 501.8656 501.9847 502.1039 502.2230 502.3420 502.4611 502.5802 502.6992 502.8182 502.9372 503.0562 503.1752 503.2942 503.4131 503.5320 503.6509 503.7698 503.8887 504.0076 504.1264 504.2452 504.3641 504.4829 504.6016 504.7204 504.8391 504.9579 505.0766 505.1953 505.3140 505.4327 505.5513 505.6699 505.7886 505.9072 506.0258 506.1443 506.2629 506.3814 506.4999 506.6185 506.7369 506.8554 506.9739 507.0923 507.2107 507.3292 507.4476 507.5659 507.6843 507.8026 507.9210 508.0393 508.1576 508.2759 508.3941 508.5124 508.6306 508.7488 508.8670 508.9852 509.1034 509.2215 509.3397 509.4578 509.5759 509.6940 509.8121 509.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20200702T064039.9Z 7488.278240 240 1 49.83 2 61.15 89.48 138.18 312.22 0.00 1 0.00 1 0 15 2.868e-03 2.855e-03 1.002e-03 9.996e-04 2.997710e+03 5.836689e+01 2.210651e+02 -6.000000e+00 1.522665e+02 281.61 -2.00 20.00 -2.00 505.27 0.00e+00 6.640637e-04 2.694742e-05 3.862546e-05 -6.000000e+00 7.881605e-05 281.61 -2.00 20.00 -2.00 500.42 0.00e+00 1.662429e-01 1.952245e-02 2.143210e-02 -6.000000e+00 5.620911e-02 233.88 -2.00 3.88 -2.00 502.03 0.00e+00 2.062 0.000 489.00 513.00 1 7.9845e+00 1.4931e-03 3.5729e-03 -6.0000e+00 4.2938e-03 -7.3085e-03 3.9025e-04 5.4011e-04 -6.0000e+00 1.1316e-03 4.8593e-04 2.6681e-03 8.5132e-05 3.0078e-05 -6.0000e+00 2.5147e-04 1.3610e-03 -6.2338e-05 10 0 0 10 0 0 96.83 22.43 1.44 0.00136 0.01987 14 3 1 4 0 3558.935 25.39 20.00 22.43 23.26 17.9 981.00 -587 -300 -465 24 119 423 635 279 429 355 95 -138 -23 -145 -552 -333 -113 -34 30 186 324 152 107 -62 265 475 403 203 -166 -164 -391 -92 -135 112 44 310 246 -47 -64 -211 -21 48 -71 10 202 55 197 -32 189 -188 -291 -692 -660 -426 -292 -251 137 239 232 232 267 104 384 308 253 162 27 16 -192 -317 -537 -481 -339 42 52 -175 -76 -115 -253 -222 -466 -427 -458 -294 63 -72 44 89 -123 -145 -86 270 46 339 381 238 43 33 -328 -429 -562 -542 -263 -337 -254 -8 91 -225 -390 -209 -359 -112 143 302 244 447 319 557 458 391 54 288 163 96 185 234 196 237 93 138 385 167 178 -184 -103 -108 81 8 221 177 317 259 -17 151 -74 17 -44 -107 -390 -712 -500 -564 -292 -469 24 120 437 668 298 456 373 99 -141 -23 -144 -547 -331 -113 -35 32 200 348 163 115 -67 286 514 435 217 -175 -166 -386 -91 -136 116 45 321 253 -47 -68 -220 -22 50 -72 10 208 57 203 -33 189 -194 -292 -676 -633 -408 -286 -255 135 240 233 232 266 105 387 312 255 161 27 16 -193 -314 -527 -471 -335 42 50 -169 -76 -113 -245 -213 -450 -416 -450 -290 63 -70 42 86 -118 -140 -83 264 46 341 380 234 41 31 -317 -406 -524 -509 -254 -322 -252 -8 91 -221 -377 -201 -351 -111 144 307 250 459 330 578 475 401 54 285 160 94 182 231 194 234 92 136 378 163 170 -173 -96 -101 77 8 220 179 307 251 -17 149 -74 17 -43 -107 -382 -686 -482 SQ 20200702T070357.6Z 7488.294417 253 1 17.28 2 57.65 94.21 140.55 319.41 0.00 1 0.00 1 0 15 3.142e-03 3.115e-03 1.674e-03 1.670e-03 2.905061e+03 9.732036e+01 2.162652e+02 -6.000000e+00 1.668164e+02 281.62 -2.00 20.00 -2.00 505.25 0.00e+00 6.946023e-04 4.493494e-05 3.859553e-05 -6.000000e+00 8.634615e-05 281.62 -2.00 20.00 -2.00 500.38 0.00e+00 1.724585e-01 3.264903e-02 2.006300e-02 -6.000000e+00 6.156769e-02 233.88 -2.00 3.88 -2.00 501.98 0.00e+00 1.862 0.000 489.00 513.00 1 7.9837e+00 2.4937e-03 3.2859e-03 -6.0000e+00 4.7034e-03 7.9352e-03 6.5321e-04 5.0844e-04 -6.0000e+00 1.2392e-03 4.9994e-04 2.3108e-03 1.4229e-04 3.0221e-05 -6.0000e+00 2.7548e-04 -5.7546e-04 -3.2373e-05 12 1 1 12 1 1 99.84 22.45 1.49 -0.00058 0.01545 4 3 1 4 0 3421.922 25.39 20.00 22.45 24.32 17.9 985.00 -721 -273 -812 -264 172 454 504 424 323 314 -56 -65 -135 -26 -567 -423 212 180 156 384 285 169 70 199 -69 371 249 266 -149 40 -642 -17 53 -103 255 402 332 19 -242 -73 -142 -167 -34 -15 113 90 104 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-77 396 119 568 44 282 277 88 7 -141 -281 -657 -443 -679 SQ 20200702T070823.3Z 7488.297492 256 1 2.67 2 56.99 95.13 140.97 320.84 0.00 1 0.00 1 0 15 3.765e-03 3.745e-03 2.835e-03 2.830e-03 2.529105e+03 1.625677e+02 1.972516e+02 -6.000000e+00 1.999044e+02 281.62 -2.00 20.00 -2.00 505.25 0.00e+00 6.083195e-04 7.613331e-05 3.628547e-05 -6.000000e+00 1.034730e-04 281.62 -2.00 20.00 -2.00 500.41 0.00e+00 7.609476e-02 5.520345e-02 1.585548e-02 -6.000000e+00 7.376579e-02 233.88 -2.00 3.88 -2.00 502.01 0.00e+00 1.829 0.000 489.00 513.00 1 6.8039e+00 4.2163e-03 3.0661e-03 -6.0000e+00 5.6355e-03 1.1266e-02 1.1056e-03 4.2779e-04 -6.0000e+00 1.4843e-03 1.6492e-03 2.0423e-03 2.4139e-04 2.8125e-05 -6.0000e+00 3.3011e-04 -3.3394e-03 2.1600e-06 12 1 1 12 1 1 999.00 22.45 1.51 -0.00334 0.01083 1 8 1 4 0 1248.140 25.39 20.00 22.45 24.33 17.9 984.84 -525 -131 -512 203 435 376 286 150 409 203 -364 244 -165 -313 -515 -361 -229 369 123 58 530 580 -3 -64 -28 473 481 12 -25 -61 -261 -151 -141 -576 -107 318 335 424 315 -253 -166 -75 129 203 271 186 336 125 -90 -407 -305 -1340 -383 -1182 -267 21 -19 720 -74 605 -635 784 191 22 354 -54 -112 -474 -255 104 -170 -521 -163 -99 -164 12 241 491 -785 283 -538 -200 -119 111 -130 -294 -85 273 41 120 68 -30 291 304 255 418 34 143 -427 -265 -473 -737 9 -603 -254 -517 -319 21 -520 -427 -393 303 441 95 119 845 201 264 246 342 104 -83 341 31 -43 592 413 29 661 320 112 -471 301 -325 -274 85 -337 84 128 600 786 79 -125 75 -282 319 -440 52 -452 -551 -286 -513 -128 -513 206 447 391 300 158 430 212 -378 251 -168 -317 -521 -365 -233 378 128 61 557 608 -3 -67 -30 497 504 12 -26 -62 -261 -151 -142 -593 -112 334 350 439 324 -260 -170 -77 133 211 282 194 350 129 -92 -414 -304 -1324 -373 -1156 -263 22 -19 734 -76 616 -649 798 196 22 361 -55 -112 -472 -252 102 -165 -507 -159 -97 -162 12 237 475 -760 271 -518 -193 -116 108 -127 -290 -83 269 40 118 67 -29 292 306 256 415 34 139 -409 -251 -444 -696 9 -589 -252 -517 -317 21 -507 -415 -384 297 437 94 119 844 202 266 247 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