File name: Pandora21s1_Bremen_20210124_L2Fit_fout2c1d20201116p1-8.txt File generation date: 20240830T061607.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v1d20201116.txt Level 1 file used: Pandora21s1_Bremen_20210124_L1_smca1c1d20201116p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20210124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.0633 305.2039 305.3445 305.4851 305.6257 305.7662 305.9068 306.0473 306.1878 306.3283 306.4688 306.6093 306.7497 306.8902 307.0306 307.1711 307.3115 307.4519 307.5923 307.7326 307.8730 308.0134 308.1537 308.2940 308.4343 308.5747 308.7149 308.8552 308.9955 309.1357 309.2760 309.4162 309.5564 309.6966 309.8368 309.9770 310.1172 310.2573 310.3975 310.5376 310.6777 310.8178 310.9579 311.0980 311.2380 311.3781 311.5181 311.6582 311.7982 311.9382 312.0782 312.2182 312.3581 312.4981 312.6380 312.7779 312.9179 313.0578 313.1976 313.3375 313.4774 313.6172 313.7571 313.8969 314.0367 314.1765 314.3163 314.4561 314.5959 314.7356 314.8754 315.0151 315.1548 315.2945 315.4342 315.5739 315.7135 315.8532 315.9928 316.1325 316.2721 316.4117 316.5513 316.6908 316.8304 316.9700 317.1095 317.2490 317.3885 317.5280 317.6675 317.8070 317.9465 318.0859 318.2254 318.3648 318.5042 318.6436 318.7830 318.9224 319.0617 319.2011 319.3404 319.4798 319.6191 319.7584 319.8977 320.0369 320.1762 320.3155 320.4547 320.5939 320.7331 320.8723 321.0115 321.1507 321.2899 321.4290 321.5682 321.7073 321.8464 321.9855 322.1246 322.2637 322.4028 322.5418 322.6808 322.8199 322.9589 323.0979 323.2369 323.3759 323.5148 323.6538 323.7927 323.9317 324.0706 324.2095 324.3484 324.4872 324.6261 324.7650 324.9038 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210124T093800.8Z 7694.401398 258 1 49.51 2 76.63 151.22 102.80 24.20 0.00 1 0.00 1 0 25 3.278e-01 7.787e-03 2.374e-01 5.874e-03 6.657018e-01 3.161424e-03 8.268930e-03 -6.000000e+00 1.910090e-01 222.01 -2.00 3.88 -2.00 321.02 0.00e+00 2.475209e-03 1.176075e-03 6.859286e-04 -6.000000e+00 7.853947e-03 265.76 -2.00 20.00 -2.00 320.71 0.00e+00 4.221 0.002 302.00 328.00 3 3.7500e+00 9.3154e-03 5.6278e-02 -6.0000e+00 4.7166e-01 1.4977e-01 1.2560e-02 3.8413e-02 -6.0000e+00 5.1478e-01 -1.0910e-01 1.4465e-02 2.1598e-02 -6.0000e+00 3.0390e-01 3.2954e-02 7.3467e-03 7.2650e-03 -6.0000e+00 1.2747e-01 8.6942e-05 -9.6850e-04 1.7797e-04 9.6136e-05 -6.0000e+00 9.8305e-03 1.9522e-03 1.1133e-05 11 8 0 10 0 0 95.88 22.15 0.23 0.00195 -0.00533 28 5 1 5 0 1767.967 25.17 20.00 22.15 9.23 22.0 979.41 -124306 -49115 -138119 -110982 -100362 -64188 -142489 -123186 -115501 -123540 -85483 7596 -12847 -44329 -33076 26605 18119 -8588 -23553 -24097 -29696 6815 -15788 -22372 26656 -6181 -9506 -7091 -26372 -13493 21418 9420 12134 -5202 6257 27536 5432 -12352 -10521 7609 -3718 -547 -4525 50 8121 -6949 4936 -465 3562 -4239 7650 2419 -3104 3359 -2079 1607 5893 -3471 -1065 443 2186 3662 1608 -522 2631 2638 -1052 1571 1943 2379 -611 953 2167 2298 1074 407 -122 2182 -2527 4870 -425 -941 -1242 -1414 -2805 -507 237 50 171 -265 934 515 -1153 139 -367 1273 28 1081 -403 -98 -821 -195 -516 1235 -242 -811 -734 35 -863 -950 -538 -381 499 519 311 -412 400 150 -97 -243 -638 575 -316 -189 262 734 1910 1220 -103 170 461 -104 -65 -171 130 77 319 168 -494 -170 -177 -266 -61 -1104 -281 -1716 -1075 -843 -386 -1842 -1501 -1462 -1817 -966 44 -106 -609 -506 284 235 -155 -522 -564 -752 127 -373 -603 502 -164 -264 -191 -848 -415 559 321 460 -247 266 971 252 -787 -791 569 -348 -54 -485 5 811 -817 533 -55 424 -582 1033 382 -567 626 -433 338 1221 -787 -231 93 465 835 420 -155 806 810 -332 497 668 919 -267 430 961 970 423 147 -41 725 -964 2011 -215 -543 -789 -960 -2045 -383 186 40 139 -209 688 358 -783 95 -276 1073 27 1180 -484 -120 -964 -209 -509 1175 -244 -868 -825 41 -1116 -1355 -837 -628 828 844 484 -621 593 228 -156 -403 -1063 923 -493 -284 380 1025 2568 1680 -157 286 846 -204 -133 -370 294 184 777 416 -1226 -412 -409 -583 -129 SS 20210124T094518.2Z 7694.406460 262 1 50.31 2 76.12 152.91 102.34 25.81 0.00 1 0.00 1 0 25 3.804e-01 9.097e-03 2.347e-01 5.865e-03 6.456530e-01 3.168126e-03 8.071445e-03 -6.000000e+00 2.243001e-01 222.01 -2.00 3.88 -2.00 320.87 0.00e+00 1.879948e-03 1.143223e-03 6.236419e-04 -6.000000e+00 9.254881e-03 265.76 -2.00 20.00 -2.00 320.57 0.00e+00 4.075 0.001 302.00 328.00 3 4.0284e+00 9.2397e-03 5.4389e-02 -6.0000e+00 5.5531e-01 1.6529e-01 1.2206e-02 3.7083e-02 -6.0000e+00 6.0702e-01 -1.1361e-01 1.3776e-02 2.0647e-02 -6.0000e+00 3.5719e-01 3.4197e-02 7.0538e-03 6.8729e-03 -6.0000e+00 1.4924e-01 7.6349e-05 -1.0379e-03 1.7979e-04 9.1119e-05 -6.0000e+00 1.1601e-02 1.6229e-03 9.5218e-06 11 9 0 11 8 0 63.16 22.15 0.32 0.00162 -0.00618 23 5 1 5 0 2187.114 25.17 20.00 22.15 9.53 22.1 981.39 -60555 -71729 900000 -75974 -130208 -74974 -184689 900000 -122792 133865 -100524 -60623 -24927 -43266 88200 -38411 900000 -53223 207926 12157 -2090 -36157 72501 -14977 -19262 39044 -19674 33288 -29528 21849 -25465 16936 12657 -2138 19491 -14662 36110 -24430 14437 -17110 10879 1335 5578 1129 320 10030 2304 16547 635 3489 -744 6359 4847 6755 3539 2347 -811 -49 1870 672 5928 178 3654 793 928 579 -2740 1841 260 1398 143 -1166 636 1511 909 -2124 -1434 -2961 909 -2670 287 -2176 -374 -1295 -1628 -805 -295 161 -110 1272 479 1793 -249 1614 731 208 614 -32 380 -850 -225 -369 497 285 -170 -1478 -675 -433 -762 647 -344 -304 -553 113 -160 653 1042 474 246 -1004 -553 307 212 -244 1045 299 370 680 -143 761 -69 378 72 260 -117 -12 -267 -305 165 -200 178 -342 -81 -371 -564 900000 -655 -1740 -602 -4251 900000 -2026 765 -1577 -752 -274 -699 532 -856 900000 -1674 1189 240 -48 -1146 903 -440 -634 802 -696 722 -1129 560 -1152 611 539 -111 828 -853 1425 -1962 970 -1820 1001 145 611 133 38 1121 284 1834 86 490 -119 1057 897 1328 761 533 -195 -12 429 154 1320 45 1009 250 310 194 -936 617 96 576 65 -566 302 679 380 -830 -519 -1087 351 -1236 150 -1317 -244 -908 -1213 -629 -240 135 -92 1020 366 1269 -172 1116 556 180 604 -36 457 -1051 -265 -399 491 277 -174 -1610 -766 -520 -991 912 -534 -500 -921 183 -249 966 1522 715 389 -1658 -912 490 327 -365 1496 416 501 931 -214 1252 -125 722 144 545 -259 -27 -635 -734 395 -471 399 -732 -167 SS 20210124T095059.3Z 7694.410409 265 1 50.67 2 75.73 154.24 101.97 27.05 0.00 1 0.00 1 0 25 2.765e-01 8.635e-03 2.487e-01 6.597e-03 6.353777e-01 3.591975e-03 7.961163e-03 -6.000000e+00 1.634490e-01 222.01 -2.00 3.88 -2.00 320.86 0.00e+00 1.612803e-03 1.293034e-03 6.100098e-04 -6.000000e+00 7.180815e-03 265.76 -2.00 20.00 -2.00 320.56 0.00e+00 3.973 0.001 302.00 328.00 3 4.1441e+00 1.0469e-02 5.3278e-02 -6.0000e+00 4.0346e-01 1.3264e-01 1.3823e-02 3.6522e-02 -6.0000e+00 4.4134e-01 -5.2552e-02 1.5712e-02 2.0350e-02 -6.0000e+00 2.5816e-01 6.3962e-03 8.0615e-03 6.7790e-03 -6.0000e+00 1.0959e-01 7.5558e-05 -1.0628e-03 2.0487e-04 8.9593e-05 -6.0000e+00 8.4805e-03 1.3621e-03 2.3614e-05 11 8 0 10 0 0 99.15 22.16 0.18 0.00136 -0.00662 35 7 1 5 0 1447.664 25.17 20.00 22.16 9.75 22.1 982.75 900000 900000 -120845 -83707 -8265 900000 900000 -49059 3891 -131426 900000 -34333 28490 -86868 50655 -13501 109802 42293 -28612 136372 6751 -2525 -10380 68769 -26918 42946 28069 12028 40695 -35273 2674 -11366 21204 18268 10504 6454 -2675 10318 -7458 5316 -10980 3230 -1988 -1495 5519 7984 834 -4563 -2353 -8007 3454 2878 5381 -4677 4714 -993 3842 1384 3703 6520 1615 4270 -5727 3141 -1643 2888 -1990 187 4069 -1724 -699 55 2582 -3548 2224 -1616 1540 1836 -3508 -640 -1620 1151 -1589 21 -1284 875 -803 -334 -49 -210 1655 759 1675 -721 550 -1107 945 926 323 -276 -698 791 -177 845 -2138 -431 -1298 498 581 90 -90 -709 300 -747 791 -375 628 4 572 -828 -583 95 -350 180 28 1033 15 1129 -108 709 61 -243 117 194 259 -424 200 -74 -210 -309 460 40 -418 900000 900000 -1597 -803 -53 900000 900000 -399 25 -2576 900000 -358 210 -2088 464 -247 795 593 -782 971 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