File name: Pandora21s1_Bremen_20220412_L2Fit_fout2c6d20211128p1-8.txt File generation date: 20240903T113612.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v6d20211128.txt Level 1 file used: Pandora21s1_Bremen_20220412_L1_smca1c6d20211128p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20220412 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.0476 305.1881 305.3286 305.4691 305.6096 305.7501 305.8905 306.0309 306.1714 306.3118 306.4522 306.5926 306.7329 306.8733 307.0137 307.1540 307.2943 307.4346 307.5749 307.7152 307.8555 307.9958 308.1361 308.2763 308.4165 308.5568 308.6970 308.8372 308.9774 309.1176 309.2577 309.3979 309.5380 309.6781 309.8183 309.9584 310.0985 310.2386 310.3786 310.5187 310.6587 310.7988 310.9388 311.0788 311.2188 311.3588 311.4988 311.6387 311.7787 311.9186 312.0586 312.1985 312.3384 312.4783 312.6182 312.7581 312.8979 313.0378 313.1776 313.3174 313.4572 313.5970 313.7368 313.8766 314.0164 314.1561 314.2959 314.4356 314.5753 314.7150 314.8547 314.9944 315.1341 315.2737 315.4134 315.5530 315.6927 315.8323 315.9719 316.1115 316.2510 316.3906 316.5302 316.6697 316.8092 316.9487 317.0883 317.2277 317.3672 317.5067 317.6462 317.7856 317.9250 318.0645 318.2039 318.3433 318.4827 318.6220 318.7614 318.9008 319.0401 319.1794 319.3187 319.4581 319.5973 319.7366 319.8759 320.0152 320.1544 320.2936 320.4329 320.5721 320.7113 320.8505 320.9896 321.1288 321.2679 321.4071 321.5462 321.6853 321.8244 321.9635 322.1026 322.2417 322.3807 322.5198 322.6588 322.7978 322.9368 323.0758 323.2148 323.3538 323.4927 323.6317 323.7706 323.9095 324.0484 324.1873 324.3262 324.4651 324.6040 324.7428 324.8817 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220412T063753.3Z 8137.276312 258 1 50.05 2 72.24 99.32 107.71 338.73 0.00 1 0.00 1 0 25 8.737e-02 5.926e-03 7.832e-02 4.161e-03 4.542684e-01 2.201841e-03 5.887518e-03 -6.000000e+00 5.205853e-02 227.36 -2.00 3.88 -2.00 319.95 0.00e+00 1.167697e-03 6.079610e-04 2.768278e-04 -6.000000e+00 2.092378e-03 271.79 -2.00 20.00 -2.00 319.65 0.00e+00 3.234 0.001 302.00 328.00 3 4.3152e+00 6.1614e-03 4.1547e-02 -6.0000e+00 1.3012e-01 3.6366e-02 7.2458e-03 2.6250e-02 -6.0000e+00 1.4134e-01 -9.1986e-03 6.6286e-03 1.3642e-02 -6.0000e+00 8.3113e-02 -2.5143e-03 3.5354e-03 4.2004e-03 -6.0000e+00 3.4615e-02 1.6254e-04 -9.0600e-04 1.3345e-04 5.2930e-05 -6.0000e+00 2.6213e-03 2.0338e-03 0.0000e+00 11 1 0 11 8 0 95.96 22.22 0.26 0.00203 -0.00477 28 5 1 5 0 1787.223 25.28 20.00 22.22 13.59 28.6 1012.31 -30938 412 -31214 8948 12036 -62667 -13747 -6616 -13319 -17931 -1123 40162 4069 19141 -23769 6308 -1080 4284 -1497 -11050 -1528 10632 -2576 -16750 3673 6669 -2009 -8474 457 7652 -2884 7686 909 1938 2092 5816 600 -3639 -160 -5030 -1558 -896 -2026 84 349 470 -401 -206 2180 -2516 -2232 264 846 -287 1859 -851 1863 762 371 1278 362 1861 287 177 543 327 2241 184 880 531 -334 549 138 237 552 567 31 2068 -385 -407 46 -1143 -284 -1313 -1251 -1410 -612 236 -308 233 272 480 1679 1191 747 764 1321 -122 -411 268 -173 -576 -14 -243 -1170 -580 -749 -769 532 -506 51 -120 -214 382 -373 339 57 456 304 -259 -655 -202 -341 74 297 232 720 1476 514 363 0 119 548 352 72 -180 -162 -160 -24 -308 -205 -357 168 -527 6 -638 126 156 -1535 -229 -115 -274 -412 -23 620 100 488 -1060 245 -49 200 -79 -665 -87 547 -155 -1223 237 441 -146 -642 31 495 -225 615 86 194 207 550 64 -466 -24 -921 -310 -190 -455 19 80 108 -94 -49 511 -639 -604 76 262 -96 643 -314 687 286 138 466 136 737 127 85 272 161 1041 86 435 293 -204 353 90 150 327 307 16 981 -196 -232 30 -835 -224 -1110 -1119 -1342 -609 242 -319 235 261 429 1395 974 643 726 1397 -145 -529 351 -220 -682 -15 -264 -1341 -701 -949 -1023 741 -762 81 -201 -360 621 -579 497 82 669 468 -420 -1090 -333 -547 116 445 335 999 2021 748 573 0 212 1004 670 144 -378 -351 -352 -52 -675 -435 -730 331 SS 20220412T064859.4Z 8137.284021 261 1 48.80 2 70.60 101.64 108.29 341.34 0.00 1 0.00 1 0 25 2.701e-02 4.784e-03 8.229e-03 6.686e-04 4.194300e-01 3.498230e-04 5.479236e-03 -6.000000e+00 1.609467e-02 227.36 -2.00 3.88 -2.00 319.37 0.00e+00 5.629775e-04 8.261660e-05 2.092269e-04 -6.000000e+00 6.468642e-04 271.79 -2.00 20.00 -2.00 319.07 0.00e+00 2.976 0.001 302.00 328.00 3 1.5586e+00 9.5856e-04 3.8214e-02 -6.0000e+00 4.0228e-02 1.5238e-02 1.0992e-03 2.4049e-02 -6.0000e+00 4.3697e-02 -5.6290e-03 9.0389e-04 1.2303e-02 -6.0000e+00 2.5695e-02 -4.1713e-03 4.8605e-04 3.7019e-03 -6.0000e+00 1.0702e-02 3.4687e-03 -4.8040e-04 2.1110e-05 4.5199e-05 -6.0000e+00 8.1036e-04 1.7157e-03 0.0000e+00 10 0 0 10 0 0 51.86 22.23 0.19 0.00172 -0.00189 448 88 1 5 0 108.895 25.28 20.00 22.23 14.34 28.5 1015.68 -13159 -6098 -9127 -8730 -6170 -11835 -3318 -8651 -7328 -9512 -5051 -8814 -4212 -2393 -2061 -2516 -1292 922 -744 -426 -2116 533 -723 -134 -1487 -1560 -1378 -1785 -818 -1612 1072 -173 -622 -1972 -1103 -1129 -1341 -669 -1041 -959 -1785 -1150 -1336 -467 -707 -505 -185 -844 131 327 769 623 1223 553 881 678 737 483 663 1012 1031 1556 1282 1109 224 466 475 662 1138 590 6 -20 -163 -225 63 72 163 504 364 -43 -481 -940 -1440 -1200 -1120 -791 -501 -246 -111 -107 465 590 934 1104 1139 637 813 351 -309 -403 -387 -405 160 289 -737 -730 -715 -377 -77 -44 -118 -153 -51 -42 221 600 666 308 72 -467 -616 -271 -284 -80 155 302 819 1100 724 376 267 116 176 278 -47 -215 13 -18 -342 -188 -176 -161 -50 -300 -147 -237 -221 -144 -282 -77 -236 -219 -311 -165 -319 -167 -110 -111 -155 -86 64 -56 -33 -174 43 -61 -12 -144 -159 -142 -180 -79 -159 112 -21 -82 -277 -152 -154 -196 -112 -209 -225 -471 -323 -391 -139 -213 -153 -56 -257 40 103 256 224 471 228 379 302 337 222 301 455 472 755 678 633 133 270 265 364 657 378 4 -15 -122 -163 43 46 95 283 213 -28 -352 -764 -1265 -1110 -1090 -811 -537 -271 -123 -116 481 572 854 986 1060 648 910 431 -406 -540 -502 -494 184 328 -880 -918 -937 -513 -110 -66 -188 -253 -85 -67 337 873 951 449 110 -746 -1005 -439 -451 -123 231 436 1142 1522 1049 583 439 198 309 504 -88 -422 26 -37 -706 -384 -351 -311 -93 SS 20220412T065924.8Z 8137.291259 264 1 48.91 2 69.07 103.85 108.77 343.81 0.00 1 0.00 1 0 25 1.805e-02 4.583e-03 6.359e-03 6.154e-04 3.937392e-01 3.210205e-04 5.165147e-03 -6.000000e+00 1.075505e-02 227.36 -2.00 3.88 -2.00 319.17 0.00e+00 4.766679e-04 7.128201e-05 1.803813e-04 -6.000000e+00 4.322938e-04 271.79 -2.00 20.00 -2.00 318.87 0.00e+00 2.772 0.000 302.00 328.00 3 1.5955e+00 8.7419e-04 3.5696e-02 -6.0000e+00 2.6882e-02 1.3033e-02 9.9512e-04 2.2524e-02 -6.0000e+00 2.9201e-02 -2.8126e-03 7.8079e-04 1.1464e-02 -6.0000e+00 1.7171e-02 -5.7214e-03 4.1948e-04 3.4280e-03 -6.0000e+00 7.1509e-03 4.2016e-03 -5.1583e-04 1.9483e-05 4.1903e-05 -6.0000e+00 5.4159e-04 2.4412e-03 0.0000e+00 10 0 0 10 0 0 97.84 22.23 0.21 0.00244 -0.00143 556 109 1 5 0 87.153 25.28 20.00 22.23 14.83 28.6 1018.67 676 -6902 -4694 -8097 -3780 -6344 -5970 -1999 -6523 1585 -6579 290 -5271 -705 -574 -1520 194 -1115 1070 -1186 1904 -1480 1684 -1972 -771 -1604 -2824 -1888 -1190 457 -1570 1894 -578 -1542 -1862 -1561 -1567 -832 -618 -1569 -983 -1463 -864 -1303 -431 -751 -610 -592 -404 711 314 1037 914 1059 535 958 614 322 872 1060 1479 1317 1635 760 334 435 564 721 880 631 -39 85 -299 -86 -118 172 207 274 391 -326 -392 -1037 -1261 -1296 -848 -823 -433 -235 -140 -37 181 432 599 956 769 737 803 508 -272 -358 -319 -551 182 32 -642 -786 -608 -491 -37 128 0 -6 -30 117 101 610 420 292 78 -406 -584 -209 -231 -164 276 261 880 995 652 368 189 50 67 260 -184 -122 -29 93 -321 -151 -147 -243 -16 18 -204 -142 -246 -110 -183 -181 -65 -232 56 -261 11 -253 -38 -37 -112 15 -95 94 -112 179 -146 165 -213 -88 -194 -350 -224 -135 51 -194 252 -87 -247 -294 -243 -261 -160 -142 -400 -280 -448 -274 -423 -140 -246 -199 -193 -132 236 111 394 375 463 247 455 300 158 419 504 716 682 924 469 214 270 332 417 536 431 -28 64 -228 -63 -86 115 126 159 235 -221 -303 -848 -1126 -1232 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