File name: Pandora21s1_Bremen_20240823_L2Fit_fout2c10d20231020p1-8.txt File generation date: 20250501T012310.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v10d20231020.txt Level 1 file used: Pandora21s1_Bremen_20240823_L1_smca1c10d20231020p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20240823 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 287 429 Nominal wavelengths inside fitting window [nm]: 305.1299 305.2716 305.4132 305.5548 305.6963 305.8379 305.9793 306.1208 306.2622 306.4035 306.5448 306.6861 306.8274 306.9686 307.1098 307.2510 307.3921 307.5332 307.6742 307.8153 307.9563 308.0972 308.2382 308.3791 308.5199 308.6608 308.8016 308.9424 309.0831 309.2239 309.3646 309.5053 309.6459 309.7865 309.9271 310.0677 310.2082 310.3487 310.4892 310.6297 310.7701 310.9106 311.0509 311.1913 311.3317 311.4720 311.6123 311.7525 311.8928 312.0330 312.1732 312.3134 312.4536 312.5937 312.7338 312.8739 313.0140 313.1540 313.2941 313.4341 313.5741 313.7140 313.8540 313.9939 314.1338 314.2737 314.4136 314.5534 314.6933 314.8331 314.9729 315.1127 315.2524 315.3922 315.5319 315.6716 315.8113 315.9510 316.0906 316.2303 316.3699 316.5095 316.6491 316.7886 316.9282 317.0677 317.2073 317.3468 317.4863 317.6257 317.7652 317.9046 318.0441 318.1835 318.3229 318.4623 318.6016 318.7410 318.8803 319.0196 319.1589 319.2982 319.4375 319.5768 319.7160 319.8553 319.9945 320.1337 320.2729 320.4121 320.5513 320.6904 320.8296 320.9687 321.1078 321.2469 321.3860 321.5251 321.6641 321.8032 321.9422 322.0812 322.2202 322.3592 322.4982 322.6372 322.7762 322.9151 323.0540 323.1930 323.3319 323.4708 323.6096 323.7485 323.8874 324.0262 324.1651 324.3039 324.4427 324.5815 324.7203 324.8591 324.9978 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240823T062504.8Z 9001.267417 248 1 5.22 2 72.38 94.71 66.19 250.10 0.00 1 0.00 1 0 25 7.157e-02 8.750e-03 5.155e-02 5.418e-03 4.236790e-01 2.816052e-03 5.441116e-03 -6.000000e+00 4.267860e-02 231.50 -2.00 3.88 -2.00 318.97 0.00e+00 9.711004e-04 5.916921e-04 1.789413e-04 -6.000000e+00 1.712808e-03 281.90 -2.00 20.00 -2.00 318.63 0.00e+00 3.256 0.001 302.00 328.00 3 3.5286e+00 7.6802e-03 4.0715e-02 -6.0000e+00 1.0766e-01 3.9721e-02 8.7074e-03 2.4448e-02 -6.0000e+00 1.1723e-01 -9.8293e-03 6.5320e-03 1.2084e-02 -6.0000e+00 6.8717e-02 6.7197e-05 3.4618e-03 3.4174e-03 -6.0000e+00 2.7812e-02 3.6862e-04 -1.2726e-03 1.6665e-04 4.0485e-05 -6.0000e+00 2.1558e-03 2.0037e-03 0.0000e+00 12 9 1 12 1 1 76.55 23.02 0.31 0.00200 -0.00756 4 9 1 5 0 1037.280 26.00 20.01 23.02 26.29 36.0 1005.45 -18718 14529 -34125 -20559 -22618 -31995 -4229 -13872 32097 -7330 18001 -21657 1808 -10539 6275 3731 -4452 8259 -7850 5782 -5831 9518 244 4451 -4598 -9644 857 -12024 9069 -8070 7301 -4776 4736 -3728 -2551 -2886 1955 -402 -2909 2402 -4571 1727 -1095 3074 -1068 -360 638 -2644 2687 -249 3857 421 2997 -520 1818 729 584 -281 -51 3672 364 2022 410 1497 484 164 -293 863 1171 -1280 -77 -1531 1014 55 -197 711 -773 222 484 -1157 -1364 -1429 -1750 -1296 -1040 330 -979 349 -144 589 1653 402 1594 339 1163 1098 730 -823 87 -650 -1268 -428 718 -703 -1800 -635 49 -109 53 75 -17 -267 -216 30 966 720 286 545 -269 -923 -801 159 -13 -32 -87 1521 498 1904 89 149 -44 64 399 315 -134 -336 160 -330 342 107 -96 -448 -811 -605 378 -1389 -704 -750 -1177 -133 -532 885 -302 620 -1194 95 -732 431 290 -401 704 -816 551 -628 909 27 501 -594 -1336 106 -1625 1009 -1115 978 -793 772 -657 -437 -518 380 -94 -812 717 -1555 581 -387 1062 -386 -130 229 -983 976 -97 1564 188 1389 -259 919 381 308 -148 -26 1881 201 1185 261 982 317 103 -183 552 812 -979 -62 -1253 801 42 -141 469 -496 144 341 -912 -1176 -1320 -1699 -1309 -1099 361 -1111 396 -162 638 1687 394 1506 332 1208 1239 893 -1079 116 -855 -1593 -508 832 -848 -2283 -827 65 -152 77 116 -26 -428 -339 46 1391 1017 410 805 -415 -1461 -1267 247 -20 -47 -125 2110 687 2678 134 236 -72 108 684 559 -247 -635 306 -636 655 201 -175 -804 -1453 SS 20240823T063526.2Z 9001.274609 251 1 6.26 2 70.83 96.84 67.58 252.34 0.00 1 0.00 1 0 25 2.134e-02 5.445e-03 1.225e-02 1.730e-03 3.937911e-01 8.990447e-04 5.096455e-03 -6.000000e+00 1.272624e-02 231.49 -2.00 3.88 -2.00 318.55 0.00e+00 6.226548e-04 1.674282e-04 1.462635e-04 -6.000000e+00 5.106295e-04 281.90 -2.00 20.00 -2.00 318.21 0.00e+00 3.009 0.001 302.00 328.00 3 2.0007e+00 2.4322e-03 3.7711e-02 -6.0000e+00 3.2103e-02 2.3166e-02 2.7365e-03 2.2707e-02 -6.0000e+00 3.4953e-02 -8.3291e-03 1.9132e-03 1.1174e-02 -6.0000e+00 2.0489e-02 -1.5513e-03 1.0017e-03 3.1333e-03 -6.0000e+00 8.2945e-03 2.2599e-03 -8.1102e-04 5.3219e-05 3.7135e-05 -6.0000e+00 6.4269e-04 5.4776e-04 0.0000e+00 12 1 1 12 1 1 98.78 23.02 0.24 0.00055 -0.00555 34 55 1 5 0 178.706 26.00 20.01 23.02 26.36 35.9 1006.08 -416 -11850 -699 -5924 -100 -8681 -4610 -1300 -9035 134 -3906 -10364 -7594 -2531 -2538 -688 -1202 -614 524 -751 804 -1494 701 -3103 226 -828 667 259 1284 -533 -133 1385 -1167 -1121 398 -71 -1415 -426 -1352 -1035 -957 -1339 261 -951 126 26 281 192 759 324 515 827 173 598 404 1036 191 911 1522 1127 1090 1232 664 84 750 474 1082 1188 504 -74 -234 -388 -351 -213 -317 -129 28 810 -421 -131 -1277 -1444 -791 -1301 -763 -531 -579 -132 -176 263 380 887 981 1074 566 1036 463 -459 -438 -672 -488 -60 287 -580 -664 -592 -463 -54 -11 30 -194 -130 94 307 575 657 466 232 -394 -604 -309 -468 -126 76 251 813 1477 671 647 287 213 188 247 3 -258 -32 164 -431 -357 -100 -264 -87 -234 -16 -557 -30 -247 -4 -356 -200 -62 -507 7 -228 -721 -607 -228 -246 -72 -136 -74 65 -98 105 -203 98 -485 36 -137 106 40 193 -86 -24 273 -252 -241 82 -15 -334 -119 -454 -368 -368 -542 107 -397 53 11 116 80 320 145 248 405 91 331 232 607 114 533 875 660 677 789 465 62 538 323 714 815 366 -60 -193 -327 -289 -174 -236 -92 19 553 -322 -108 -1139 -1347 -783 -1374 -818 -604 -657 -152 -207 292 409 880 978 1051 611 1193 574 -602 -591 -881 -618 -70 342 -698 -855 -769 -633 -74 -16 46 -301 -204 147 448 815 900 650 342 -596 -951 -486 -719 -186 112 353 1133 2002 955 959 444 335 307 419 6 -455 -59 308 -796 -655 -183 -463 -151 -408 SS 20240823T064513.8Z 9001.281409 254 1 6.95 2 69.38 98.87 68.92 254.43 0.00 1 0.00 1 0 25 2.227e-02 5.238e-03 1.268e-02 2.106e-03 3.721231e-01 1.093887e-03 4.819093e-03 -6.000000e+00 1.328068e-02 231.49 -2.00 3.88 -2.00 318.35 0.00e+00 9.158666e-04 1.915664e-04 1.295778e-04 -6.000000e+00 5.329321e-04 281.90 -2.00 20.00 -2.00 318.00 0.00e+00 2.810 0.000 302.00 328.00 3 2.6865e+00 2.9496e-03 3.5361e-02 -6.0000e+00 3.3501e-02 1.7918e-02 3.3124e-03 2.1413e-02 -6.0000e+00 3.6477e-02 -1.3132e-02 2.2347e-03 1.0524e-02 -6.0000e+00 2.1383e-02 1.3988e-03 1.1563e-03 2.9439e-03 -6.0000e+00 8.6553e-03 1.4207e-03 -9.3956e-04 6.5184e-05 3.4836e-05 -6.0000e+00 6.7076e-04 1.2226e-03 0.0000e+00 12 1 1 12 1 1 54.30 23.03 0.22 0.00122 -0.00584 21 31 1 5 0 315.304 26.00 19.99 23.03 26.57 36.0 1007.62 4405 -7772 1423 -7917 -1738 -9063 -1967 -1112 -9917 -5953 -10081 2387 -8130 -1708 -2502 2629 -1266 -1521 603 -1709 2885 -1112 2027 -1893 219 -2543 1365 199 -1666 2151 -938 2085 -2645 -274 -2673 -861 -2345 -1498 -1405 -1316 -270 -1826 106 -802 253 14 675 -139 -89 915 1434 1529 1138 1544 625 1543 366 1044 708 1437 1527 1547 1214 -47 250 -71 858 386 520 153 -66 -626 201 -14 -7 -273 -803 -404 -994 -599 -1013 -1669 -1145 -814 -327 -512 148 -136 -84 -234 -33 -260 -125 385 220 872 783 40 -379 -280 -885 -214 167 -818 -512 -525 -50 -30 153 148 159 288 127 359 430 663 133 225 -381 -553 -219 39 -4 145 366 550 1044 592 482 233 277 -25 -147 -152 -364 -125 12 -156 17 -45 -232 -91 -280 200 -431 72 -411 -80 -452 -100 -63 -671 -403 -740 172 -765 -178 -282 310 -166 -211 86 -258 422 -172 319 -331 40 -481 242 34 -287 376 -188 448 -635 -64 -622 -206 -609 -461 -512 -510 -112 -804 47 -362 114 6 300 -62 -40 432 727 789 629 892 377 946 217 642 432 883 941 1040 888 -34 178 -50 588 276 391 128 -56 -549 171 -11 -6 -202 -562 -286 -743 -508 -922 -1598 -1162 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