File name: Pandora21s1_Bremen_20241117_L2Fit_fwvt1c7d20231020p1-8.txt File generation date: 20241119T083604.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v7d20231020.txt Level 1 file used: Pandora21s1_Bremen_20241117_L1_smca1c7d20231020p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20241117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1712 1862 Nominal wavelengths inside fitting window [nm]: 492.0069 492.1275 492.2480 492.3685 492.4890 492.6094 492.7299 492.8503 492.9707 493.0911 493.2115 493.3319 493.4522 493.5725 493.6929 493.8131 493.9334 494.0537 494.1739 494.2942 494.4144 494.5346 494.6547 494.7749 494.8950 495.0152 495.1353 495.2554 495.3754 495.4955 495.6155 495.7355 495.8555 495.9755 496.0955 496.2155 496.3354 496.4553 496.5752 496.6951 496.8150 496.9348 497.0547 497.1745 497.2943 497.4141 497.5338 497.6536 497.7733 497.8930 498.0127 498.1324 498.2521 498.3717 498.4913 498.6109 498.7305 498.8501 498.9697 499.0892 499.2087 499.3282 499.4477 499.5672 499.6867 499.8061 499.9255 500.0449 500.1643 500.2837 500.4031 500.5224 500.6417 500.7610 500.8803 500.9996 501.1188 501.2381 501.3573 501.4765 501.5957 501.7148 501.8340 501.9531 502.0722 502.1913 502.3104 502.4294 502.5485 502.6675 502.7865 502.9055 503.0245 503.1435 503.2624 503.3813 503.5002 503.6191 503.7380 503.8569 503.9757 504.0945 504.2133 504.3321 504.4509 504.5696 504.6884 504.8071 504.9258 505.0445 505.1632 505.2818 505.4004 505.5191 505.6377 505.7562 505.8748 505.9934 506.1119 506.2304 506.3489 506.4674 506.5858 506.7043 506.8227 506.9411 507.0595 507.1779 507.2963 507.4146 507.5329 507.6512 507.7695 507.8878 508.0061 508.1243 508.2425 508.3607 508.4789 508.5971 508.7152 508.8334 508.9515 509.0696 509.1877 509.3057 509.4238 509.5418 509.6599 509.7779 509.8958 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241117T074718.1Z 9087.324516 312 1 18.89 2 84.37 132.79 79.96 301.35 0.00 1 0.00 1 0 22 3.236e-03 3.205e-03 1.705e-04 1.703e-04 5.525770e+03 9.970736e+00 4.076522e+02 -6.000000e+00 1.640653e+02 270.51 -2.00 20.00 -2.00 505.30 0.00e+00 8.683298e-04 4.479423e-06 5.460097e-05 -6.000000e+00 8.667797e-05 270.51 -2.00 20.00 -2.00 500.56 0.00e+00 9.022638e-01 3.282733e-03 4.148960e-02 -6.000000e+00 6.288002e-02 220.60 -2.00 3.88 -2.00 502.14 0.00e+00 8.999 0.016 489.00 513.00 1 2.5769e+00 2.4978e-04 1.3498e-02 -6.0000e+00 4.7904e-03 3.1096e-04 6.5147e-05 1.2426e-03 -6.0000e+00 1.2656e-03 3.8328e-02 2.7081e-04 1.4299e-05 6.6206e-05 -6.0000e+00 2.8347e-04 -1.0460e-03 1.0002e-05 12 1 1 12 1 1 99.93 22.95 1.13 -0.00105 0.00083 322 171 1 4 0 57.569 26.00 20.00 22.95 11.92 35.2 996.52 -720 -663 -404 -88 288 451 531 552 416 377 161 -4 -81 -177 -179 -209 -57 59 188 298 345 222 240 252 267 364 353 292 56 -137 -514 -563 -409 -223 87 222 253 10 -70 -213 -201 -187 -57 69 181 229 230 263 97 -112 -323 -622 -747 -700 -559 -271 33 238 229 234 299 299 394 376 389 259 155 -9 -217 -314 -427 -479 -365 -261 -115 -30 -51 -166 -327 -387 -405 -526 -422 -376 -280 -122 -44 -22 -25 -109 -36 72 186 322 392 337 187 71 -210 -395 -624 -721 -538 -415 -173 -35 -6 -106 -268 -337 -306 -139 6 227 377 475 521 574 527 443 319 169 164 119 208 269 326 241 274 230 224 185 67 -47 -207 -181 -121 -6 142 235 241 196 187 111 144 126 -6 -242 -412 -603 -618 -679 -630 -383 -87 284 455 533 562 426 383 162 -4 -82 -175 -175 -204 -57 60 191 308 359 231 251 262 274 375 362 298 58 -136 -512 -558 -410 -224 89 232 263 10 -71 -214 -206 -188 -58 71 189 240 241 272 99 -113 -325 -607 -732 -682 -554 -270 33 243 235 239 304 305 405 388 400 264 156 -9 -213 -312 -419 -468 -359 -260 -113 -30 -50 -164 -317 -372 -389 -509 -412 -370 -278 -120 -43 -22 -24 -107 -36 71 188 321 390 338 183 69 -201 -368 -589 -680 -505 -405 -172 -35 -6 -105 -261 -334 -298 -138 6 231 376 475 525 583 540 451 320 171 163 118 207 269 328 242 275 231 225 184 66 -46 -198 -173 -118 -6 141 237 246 197 190 113 147 130 -6 -243 -414 -594 -607 SQ 20241117T075813.2Z 9087.332097 315 1 6.52 2 83.19 135.10 81.28 303.29 0.00 1 0.00 1 0 15 2.977e-03 2.947e-03 8.684e-05 8.674e-05 4.529327e+03 4.982589e+00 3.391009e+02 -6.000000e+00 1.509704e+02 270.51 -2.00 20.00 -2.00 505.29 0.00e+00 7.670150e-04 2.280930e-06 4.714803e-05 -6.000000e+00 7.976093e-05 270.51 -2.00 20.00 -2.00 500.54 0.00e+00 7.784041e-01 1.671125e-03 3.415238e-02 -6.000000e+00 5.786487e-02 220.60 -2.00 3.88 -2.00 502.13 0.00e+00 7.718 0.010 489.00 513.00 1 2.0540e-01 1.2715e-04 1.1467e-02 -6.0000e+00 4.4082e-03 -9.5821e-04 3.3251e-05 1.0350e-03 -6.0000e+00 1.1647e-03 4.9811e-01 4.7231e-04 7.3277e-06 5.4911e-05 -6.0000e+00 2.6083e-04 -2.1636e-03 1.1689e-05 10 0 0 10 0 0 21.17 22.95 1.22 -0.00216 0.00111 1121 220 1 4 0 5.227 26.00 20.00 22.95 12.12 35.4 997.89 -616 -549 -328 -63 265 397 519 515 425 375 153 24 -57 -205 -241 -277 -120 -35 114 298 318 240 248 228 263 376 405 271 77 -49 -367 -396 -291 -153 62 185 201 -26 -158 -253 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533 463 325 187 194 124 171 255 286 261 257 273 255 206 74 -73 -192 -201 -126 -22 112 202 218 201 174 142 121 114 -20 -216 -386 -529 -562 SQ 20241117T075820.7Z 9087.332184 315 2 7.02 2 83.18 135.12 81.29 303.32 0.00 1 0.00 1 0 15 3.083e-03 3.052e-03 8.460e-05 8.450e-05 4.516497e+03 4.864030e+00 3.358854e+02 -6.000000e+00 1.563351e+02 270.51 -2.00 20.00 -2.00 505.30 0.00e+00 7.742038e-04 2.223456e-06 4.753687e-05 -6.000000e+00 8.259532e-05 270.51 -2.00 20.00 -2.00 500.56 0.00e+00 7.741590e-01 1.626972e-03 3.469757e-02 -6.000000e+00 5.992164e-02 220.60 -2.00 3.88 -2.00 502.13 0.00e+00 7.705 0.010 489.00 513.00 1 1.5761e-01 1.2382e-04 1.1460e-02 -6.0000e+00 4.5649e-03 -1.0599e-03 3.2295e-05 1.0403e-03 -6.0000e+00 1.2061e-03 5.2355e-01 4.9324e-04 7.1363e-06 5.4375e-05 -6.0000e+00 2.7009e-04 -2.2858e-03 1.1581e-05 10 0 0 10 0 0 22.46 22.95 1.23 -0.00229 0.00114 1121 220 1 4 0 5.227 26.00 20.00 22.95 12.12 35.4 997.89 -659 -587 -373 -72 279 403 515 542 445 372 128 19 -77 -221 -251 -291 -128 -38 110 290 326 269 248 234 298 373 411 283 80 -64 -409 -433 -275 -163 69 199 202 -9 -151 -270 -243 -216 -76 77 184 242 225 199 31 -137 -307 -574 -671 -654 -496 -214 25 193 214 268 267 284 331 341 333 236 119 -20 -213 -288 -364 -444 -353 -223 -100 -46 -58 -166 -365 -379 -397 -438 -376 -296 -229 -159 -133 -73 -80 -130 -52 28 163 255 407 340 188 47 -216 -386 -612 -700 -552 -429 -148 -9 -13 -127 -242 -306 -255 -152 41 250 341 463 531 548 538 462 342 200 169 132 189 279 320 286 282 245 267 187 55 -93 -235 -212 -138 -43 94 179 221 208 171 147 149 120 -11 -206 -408 -554 -597 -620 -556 -363 -70 281 401 523 559 462 382 129 19 -77 -222 -250 -290 -129 -38 113 303 332 274 253 239 306 385 423 290 84 -65 -401 -422 -271 -165 70 208 211 -9 -154 -272 -244 -217 -77 79 191 254 235 207 32 -138 -310 -563 -644 -624 -481 -215 25 197 220 273 272 290 341 351 343 240 120 -20 -208 -287 -359 -435 -348 -216 -99 -46 -57 -164 -356 -366 -383 -425 -369 -293 -221 -156 -132 -72 -79 -128 -51 28 165 254 404 342 186 45 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