File name: Pandora21s1_Bremen_20250224_L2Fit_fnvs4c10d20231020p1-8.txt File generation date: 20250501T022854.0Z Data description: Level 2 spectral fitting results file Data file version: fnvs4c10p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v10d20231020.txt Level 1 file used: Pandora21s1_Bremen_20250224_L1_smca1c10d20231020p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20250224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 984 1531 Nominal wavelengths inside fitting window [nm]: 400.1089 400.2406 400.3723 400.5039 400.6355 400.7671 400.8987 401.0303 401.1618 401.2934 401.4249 401.5565 401.6880 401.8195 401.9509 402.0824 402.2139 402.3453 402.4767 402.6081 402.7395 402.8709 403.0023 403.1336 403.2650 403.3963 403.5276 403.6589 403.7902 403.9215 404.0527 404.1840 404.3152 404.4464 404.5776 404.7088 404.8400 404.9711 405.1023 405.2334 405.3645 405.4956 405.6267 405.7578 405.8888 406.0199 406.1509 406.2819 406.4129 406.5439 406.6749 406.8058 406.9368 407.0677 407.1986 407.3295 407.4604 407.5913 407.7222 407.8530 407.9838 408.1146 408.2455 408.3762 408.5070 408.6378 408.7685 408.8992 409.0300 409.1607 409.2914 409.4220 409.5527 409.6833 409.8140 409.9446 410.0752 410.2058 410.3363 410.4669 410.5974 410.7280 410.8585 410.9890 411.1195 411.2499 411.3804 411.5108 411.6413 411.7717 411.9021 412.0325 412.1628 412.2932 412.4235 412.5538 412.6842 412.8145 412.9447 413.0750 413.2053 413.3355 413.4657 413.5959 413.7261 413.8563 413.9865 414.1166 414.2468 414.3769 414.5070 414.6371 414.7672 414.8972 415.0273 415.1573 415.2873 415.4173 415.5473 415.6773 415.8072 415.9372 416.0671 416.1970 416.3269 416.4568 416.5867 416.7165 416.8464 416.9762 417.1060 417.2358 417.3656 417.4954 417.6251 417.7549 417.8846 418.0143 418.1440 418.2737 418.4033 418.5330 418.6626 418.7922 418.9219 419.0514 419.1810 419.3106 419.4401 419.5697 419.6992 419.8287 419.9582 420.0876 420.2171 420.3465 420.4759 420.6054 420.7348 420.8641 420.9935 421.1229 421.2522 421.3815 421.5108 421.6401 421.7694 421.8987 422.0279 422.1571 422.2863 422.4155 422.5447 422.6739 422.8031 422.9322 423.0613 423.1904 423.3195 423.4486 423.5777 423.7067 423.8358 423.9648 424.0938 424.2228 424.3518 424.4807 424.6097 424.7386 424.8675 424.9964 425.1253 425.2542 425.3830 425.5119 425.6407 425.7695 425.8983 426.0271 426.1559 426.2846 426.4133 426.5421 426.6708 426.7995 426.9281 427.0568 427.1854 427.3141 427.4427 427.5713 427.6999 427.8284 427.9570 428.0855 428.2140 428.3425 428.4710 428.5995 428.7280 428.8564 428.9849 429.1133 429.2417 429.3701 429.4984 429.6268 429.7551 429.8834 430.0118 430.1401 430.2683 430.3966 430.5248 430.6531 430.7813 430.9095 431.0377 431.1659 431.2940 431.4222 431.5503 431.6784 431.8065 431.9346 432.0627 432.1907 432.3187 432.4468 432.5748 432.7028 432.8307 432.9587 433.0866 433.2146 433.3425 433.4704 433.5983 433.7261 433.8540 433.9818 434.1096 434.2375 434.3652 434.4930 434.6208 434.7485 434.8763 435.0040 435.1317 435.2594 435.3870 435.5147 435.6423 435.7700 435.8976 436.0252 436.1527 436.2803 436.4079 436.5354 436.6629 436.7904 436.9179 437.0454 437.1728 437.3003 437.4277 437.5551 437.6825 437.8099 437.9373 438.0646 438.1919 438.3193 438.4466 438.5738 438.7011 438.8284 438.9556 439.0829 439.2101 439.3373 439.4644 439.5916 439.7188 439.8459 439.9730 440.1001 440.2272 440.3543 440.4814 440.6084 440.7354 440.8625 440.9895 441.1164 441.2434 441.3704 441.4973 441.6242 441.7511 441.8780 442.0049 442.1318 442.2586 442.3854 442.5123 442.6391 442.7658 442.8926 443.0194 443.1461 443.2728 443.3996 443.5262 443.6529 443.7796 443.9062 444.0329 444.1595 444.2861 444.4127 444.5393 444.6658 444.7924 444.9189 445.0454 445.1719 445.2984 445.4249 445.5513 445.6777 445.8042 445.9306 446.0570 446.1833 446.3097 446.4360 446.5624 446.6887 446.8150 446.9413 447.0675 447.1938 447.3200 447.4463 447.5725 447.6987 447.8248 447.9510 448.0772 448.2033 448.3294 448.4555 448.5816 448.7077 448.8337 448.9598 449.0858 449.2118 449.3378 449.4638 449.5897 449.7157 449.8416 449.9676 450.0935 450.2194 450.3452 450.4711 450.5969 450.7228 450.8486 450.9744 451.1002 451.2259 451.3517 451.4774 451.6031 451.7289 451.8545 451.9802 452.1059 452.2315 452.3572 452.4828 452.6084 452.7340 452.8595 452.9851 453.1106 453.2362 453.3617 453.4872 453.6127 453.7381 453.8636 453.9890 454.1144 454.2398 454.3652 454.4906 454.6160 454.7413 454.8666 454.9920 455.1173 455.2425 455.3678 455.4931 455.6183 455.7435 455.8687 455.9939 456.1191 456.2443 456.3694 456.4946 456.6197 456.7448 456.8699 456.9949 457.1200 457.2450 457.3701 457.4951 457.6201 457.7451 457.8700 457.9950 458.1199 458.2448 458.3697 458.4946 458.6195 458.7444 458.8692 458.9940 459.1188 459.2436 459.3684 459.4932 459.6180 459.7427 459.8674 459.9921 460.1168 460.2415 460.3662 460.4908 460.6154 460.7401 460.8647 460.9892 461.1138 461.2384 461.3629 461.4874 461.6119 461.7364 461.8609 461.9854 462.1098 462.2343 462.3587 462.4831 462.6075 462.7319 462.8562 462.9806 463.1049 463.2292 463.3535 463.4778 463.6021 463.7263 463.8505 463.9748 464.0990 464.2232 464.3473 464.4715 464.5956 464.7198 464.8439 464.9680 465.0921 465.2161 465.3402 465.4642 465.5882 465.7123 465.8362 465.9602 466.0842 466.2081 466.3321 466.4560 466.5799 466.7038 466.8276 466.9515 467.0753 467.1991 467.3230 467.4467 467.5705 467.6943 467.8180 467.9418 468.0655 468.1892 468.3129 468.4365 468.5602 468.6838 468.8074 468.9311 469.0546 469.1782 469.3018 469.4253 469.5489 469.6724 469.7959 469.9194 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-711: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 712-1259: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250224T071456.2Z 9186.302039 88 1 50.61 2 83.47 115.10 82.68 164.23 0.00 1 0.00 1 0 49 8.452e-04 6.426e-04 2.148e-04 1.845e-04 4.848074e+03 3.280640e+01 4.598672e+02 3.302868e+02 1.579266e+02 266.67 -2.00 20.00 -2.00 449.23 0.00e+00 4.366402e-04 2.184948e-05 3.317149e-05 1.545230e-05 8.946372e-05 266.67 -2.00 20.00 -2.00 457.79 0.00e+00 8.262881e-04 1.870531e-06 6.170257e-05 1.612124e-05 8.660683e-06 266.67 -2.00 20.00 -2.00 442.84 0.00e+00 2.583939e+06 2.455525e+04 1.068640e+05 2.147421e+05 1.202312e+05 250.66 -2.00 11.53 -2.00 459.37 0.00e+00 1.146227e+00 4.609056e-03 1.865835e-02 7.972488e-03 2.613742e-02 223.98 -2.00 3.88 -2.00 457.06 0.00e+00 6.481231e-07 5.923820e-07 1.578293e-06 1.091491e-06 3.199197e-06 266.67 -2.00 20.00 -2.00 457.66 0.00e+00 7.992 0.011 397.00 473.00 4 2.9856e+00 2.0735e-04 2.0472e-02 3.8004e-04 8.6775e-04 3.1811e-03 2.6952e-04 4.2445e-03 2.4641e-04 1.0992e-03 -3.0793e-03 1.3594e-04 5.6178e-04 9.4097e-05 5.5852e-04 8.9637e-04 5.1346e-05 9.3826e-05 2.4299e-05 2.0739e-04 -5.7476e-04 2.6230e-05 5.9838e-05 1.5592e-05 1.0234e-04 1.4720e-02 -3.0621e-02 1.0968e-04 1.8529e-04 3.5797e-05 4.2197e-04 -4.7382e-05 1.8820e-06 9.9023e-07 3.0085e-07 8.3095e-06 4.2118e-05 2.7138e-06 1.5828e-06 4.1941e-07 1.1452e-05 -5.9772e-03 3.0785e-05 1.5933e-01 1.8994e-02 5.9820e-03 2.4268e-03 7.5609e-02 10 0 0 10 0 0 99.54 22.94 1.11 -0.00598 -0.01060 795 156 1 4 0 63.095 25.90 20.00 22.94 16.73 36.2 1022.18 -197 -209 -259 -347 -336 -332 -163 -123 -145 -110 -127 -85 -147 -66 -133 -25 -66 -58 42 80 46 29 -45 -221 -230 -248 -26 -27 82 112 66 72 -105 -190 -260 -193 -74 123 161 135 108 33 25 40 67 15 67 -3 -37 -50 25 71 112 90 124 101 12 73 41 75 154 127 156 117 113 100 148 149 190 157 154 164 123 174 145 190 198 144 180 274 238 246 158 167 137 125 154 173 163 95 117 97 129 94 122 68 132 104 17 114 18 44 -2 77 81 94 96 32 -36 -64 -27 -49 -20 6 -56 -57 -66 -53 -80 -107 -75 -45 -75 -117 -59 -126 -109 -93 -84 -50 -74 -42 -79 -133 -83 -19 -67 -52 -93 -40 -70 -22 -58 10 12 26 16 -10 -28 -39 -47 -115 -104 -83 -43 10 -16 -20 -7 27 -13 1 -61 -5 -65 -38 -37 -15 -55 -28 -76 -109 -129 -210 -156 -35 -29 1 -88 -77 -79 -127 -95 -108 -93 -50 -40 -103 -101 -98 -75 -164 -91 -96 -30 -17 -5 -57 -100 -84 -98 -62 -70 3 3 -42 -52 -91 -139 -125 -179 -103 -133 -125 -153 -161 -118 -150 -94 -92 -44 -75 -84 -35 -60 -41 26 60 14 -49 -10 -7 -5 -73 24 -93 -70 -66 -36 -84 -15 6 -28 -55 -50 -14 -41 5 25 -7 -33 31 11 20 42 47 24 23 151 132 192 205 219 266 185 189 101 84 55 95 38 49 43 47 47 42 56 65 55 39 45 48 9 25 75 41 43 68 50 80 13 72 71 138 120 121 132 122 71 52 79 7 26 18 18 47 31 34 68 60 21 74 72 92 57 57 73 40 77 44 98 102 64 1 24 -17 -18 -6 -45 3 30 -24 32 39 20 46 43 -7 -15 -19 10 -16 22 -33 -8 -18 9 -9 33 -9 6 74 26 27 16 38 23 20 28 -9 23 27 6 5 -21 -32 -43 -49 -89 -45 -57 -48 -50 -31 -42 -44 -49 -39 -33 10 -15 -30 -21 -5 19 -20 -43 -30 -28 -38 -74 -90 -73 -86 -80 -60 -44 -30 -23 -43 -12 -29 -21 -16 -16 0 33 19 29 39 76 75 32 54 18 22 -16 -18 -40 -43 -34 -41 -20 -14 -1 -10 60 23 55 7 25 5 13 -32 -33 -44 -69 -53 -37 -13 -2 -13 -59 -62 -9 -47 -33 -24 -48 -41 -2 17 31 13 18 56 32 14 -18 1 -19 14 41 33 42 32 11 25 7 -4 4 -8 -32 -44 -40 8 -22 -4 -16 24 16 26 23 16 23 14 0 -11 -11 -23 9 -20 2 -34 -51 8 -17 2 -16 -18 -25 -31 -36 -6 34 16 47 38 5 -9 26 11 26 2 -6 -32 -75 -46 -16 60 94 121 105 80 56 13 12 10 -18 -25 -17 -7 11 2 5 -35 -23 -11 -31 -4 -23 -1 -18 2 -36 -7 21 50 -106 -112 -134 -176 -170 -171 -88 -68 -81 -63 -73 -48 -84 -38 -77 -15 -39 -34 25 48 28 17 -25 -120 -122 -135 -15 -16 51 71 42 44 -60 -103 -139 -105 -44 77 102 84 66 20 14 24 40 9 39 -2 -21 -29 15 45 70 57 78 63 8 45 25 47 100 85 106 79 77 70 100 103 131 108 111 115 85 116 92 114 114 82 107 175 163 174 114 113 95 89 112 128 121 70 85 70 94 69 90 50 96 75 12 80 12 31 -2 57 62 75 75 24 -26 -46 -20 -37 -15 5 -43 -43 -50 -40 -60 -81 -58 -36 -58 -92 -47 -100 -85 -72 -64 -40 -58 -32 -60 -101 -64 -14 -50 -39 -71 -31 -53 -16 -43 7 9 20 13 -8 -23 -30 -35 -84 -76 -61 -33 8 -13 -17 -6 22 -11 0 -50 -4 -54 -32 -31 -12 -46 -23 -63 -83 -91 -148 -115 -28 -24 1 -72 -61 -65 -104 -74 -87 -76 -42 -34 -87 -85 -79 -59 -130 -73 -78 -25 -14 -4 -47 -81 -67 -80 -53 -60 3 3 -36 -42 -70 -109 -97 -139 -85 -115 -110 -128 -141 -102 -130 -81 -78 -36 -60 -68 -28 -50 -35 22 48 10 -36 -7 -5 -4 -52 17 -63 -46 -43 -25 -63 -12 5 -26 -51 -49 -14 -39 4 21 -6 -26 26 10 19 40 45 23 21 136 115 152 163 177 216 164 170 95 81 53 88 35 44 39 44 46 41 53 62 54 39 46 48 9 24 73 39 40 63 49 74 12 70 69 128 108 102 109 105 65 47 73 6 25 17 18 47 32 34 68 59 20 69 67 86 56 58 74 41 80 44 98 101 65 1 26 -18 -19 -7 -47 3 32 -26 34 41 21 47 45 -8 -16 -20 11 -17 22 -34 -8 -19 9 -10 35 -9 6 74 26 26 16 37 23 20 29 -10 24 28 6 5 -22 -35 -47 -53 -97 -49 -63 -52 -52 -32 -45 -48 -54 -43 -36 11 -16 -32 -23 -5 21 -22 -48 -34 -32 -44 -87 -104 -85 -99 -92 -69 -50 -35 -26 -49 -14 -33 -25 -19 -19 0 38 22 31 43 83 83 35 61 20 24 -18 -21 -48 -52 -41 -49 -23 -16 -1 -11 68 27 63 9 30 6 16 -39 -41 -54 -84 -67 -46 -16 -2 -17 -75 -79 -11 -59 -42 -31 -62 -52 -3 21 37 16 22 68 39 18 -23 1 -25 18 52 43 54 41 14 33 9 -5 6 -10 -42 -58 -54 10 -29 -6 -22 32 22 34 31 22 31 19 0 -14 -15 -32 13 -28 2 -48 -72 12 -23 3 -23 -25 -35 -44 -51 -8 47 22 64 52 7 -13 37 16 37 3 -9 -49 -113 -68 -23 84 133 168 147 114 79 19 17 14 -27 -37 -24 -10 16 3 7 -52 -34 -17 -46 -6 -34 -2 -27 2 -55 -10 31 72 SQ 20250224T072707.9Z 9186.310509 91 1 50.67 2 81.83 117.64 82.22 166.83 0.00 1 0.00 1 0 33 1.942e-03 1.686e-03 1.744e-03 1.484e-03 4.499588e+03 2.687076e+02 4.296483e+02 3.302788e+02 3.627665e+02 266.67 -2.00 20.00 -2.00 449.64 0.00e+00 3.183844e-04 1.791341e-04 2.974023e-05 1.627505e-05 2.068226e-04 266.67 -2.00 20.00 -2.00 458.16 0.00e+00 7.725671e-04 1.510609e-05 5.795140e-05 1.612256e-05 1.987693e-05 266.67 -2.00 20.00 -2.00 443.23 0.00e+00 1.806309e+06 1.986826e+05 1.001355e+05 2.147935e+05 2.762342e+05 250.66 -2.00 11.53 -2.00 459.76 0.00e+00 1.020399e+00 3.691001e-02 1.783364e-02 7.832738e-03 6.009898e-02 223.98 -2.00 3.88 -2.00 457.42 0.00e+00 -4.599950e-06 4.737585e-06 1.403064e-06 1.093577e-06 7.352380e-06 266.67 -2.00 20.00 -2.00 458.03 0.00e+00 6.603 0.006 397.00 473.00 4 7.1488e+00 1.7068e-03 1.6863e-02 3.8036e-04 2.0016e-03 -2.2802e-02 2.1973e-03 3.4886e-03 2.5861e-04 2.5348e-03 -1.4235e-02 1.1323e-03 4.6098e-04 1.0071e-04 1.3076e-03 6.0248e-03 4.0913e-04 7.7572e-05 2.4748e-05 4.6870e-04 -7.0337e-04 2.1056e-04 4.6399e-05 1.5525e-05 2.3444e-04 3.2935e-04 -4.1899e-02 9.3184e-04 1.9066e-04 4.3181e-05 1.0366e-03 -3.6860e-05 1.5455e-05 9.0801e-07 3.0175e-07 1.9084e-05 -2.8383e-06 2.1902e-05 1.4470e-06 4.1896e-07 2.6255e-05 -1.0160e-02 6.4797e-05 6.9052e-01 1.5675e-01 5.8930e-03 2.4168e-03 1.7463e-01 12 8 8 10 0 0 95.39 22.94 1.20 -0.01016 -0.01073 23 5 1 4 0 2202.679 25.90 20.00 22.94 17.12 35.9 1022.98 165 -175 229 -193 -336 -291 137 -198 -695 -73 -304 538 353 -293 5 117 -355 254 -448 393 170 9 -247 181 -210 178 -344 -242 -300 666 1 15 -15 80 -9 356 195 -136 558 -306 -101 47 -50 -247 -84 -313 369 -319 79 151 -271 -240 -217 268 169 -380 535 250 117 -102 -179 643 8 116 92 -201 -13 -110 -86 545 344 37 -181 105 93 -52 -347 59 -29 -185 23 232 154 42 71 79 67 515 358 81 -54 -77 216 -103 -207 -8 -46 184 497 162 19 -170 257 128 13 270 191 -35 26 -309 481 -242 46 -299 62 21 -197 -203 72 -125 -413 -269 -338 21 113 -38 -119 -310 -185 -225 167 36 -166 -87 245 418 -236 -318 230 414 -196 -21 -11 15 167 161 79 -15 48 3 338 -241 -244 -83 -189 255 -64 -140 436 -85 -332 -92 -322 19 -139 205 41 191 -191 -177 -12 -353 -57 -202 -169 -195 -19 127 -180 282 -140 -44 44 -14 -79 -283 263 -445 -320 206 -66 -272 -503 -303 645 -293 87 -245 -94 365 -112 120 -130 225 149 8 150 46 -110 -14 -124 1 -43 61 -31 -442 84 -79 -197 49 75 -125 145 44 351 38 -405 -16 365 18 137 153 25 -181 -32 103 7 -87 -186 -126 377 554 -2 240 300 113 340 -95 160 -84 20 174 -24 217 -165 -53 10 -46 -44 -14 -37 182 -484 -226 -192 -152 -28 93 8 -5 -103 36 -149 252 25 468 53 15 55 -139 25 -4 188 202 31 -105 479 -136 265 -46 -62 -255 -187 6 91 -94 -216 54 -85 58 75 193 226 -427 -152 -97 -14 -49 155 -87 -233 60 294 81 124 59 242 -6 167 103 104 41 142 -199 103 -131 -49 -86 -191 -108 142 69 150 173 -130 115 -129 -164 108 -20 -13 -31 -53 71 -1 -235 -292 47 67 120 34 139 -169 86 168 203 -209 -48 -136 209 321 340 -58 90 -337 17 -253 45 130 -174 -56 88 -8 80 16 -161 -68 -297 -88 -64 46 -97 198 -81 -67 -180 -166 122 -81 120 -295 -139 -127 -50 261 26 -18 -10 -65 85 -133 82 101 123 -21 161 188 111 -164 58 -58 -48 -157 63 -267 -87 -81 153 -294 -123 -9 167 -35 83 -17 7 -219 -60 120 333 152 -82 115 363 81 23 -234 -86 1 126 -40 -244 -113 62 61 -138 -8 123 108 -224 29 -26 204 -45 -62 99 76 205 71 -378 19 -87 17 120 -34 88 161 -117 54 265 -180 158 0 -139 12 -13 15 -59 115 -225 -23 24 156 46 -134 -39 -35 -89 -20 -164 158 -240 85 70 -61 142 8 61 170 87 -173 223 -215 -27 -8 99 81 174 -54 -58 -47 -147 83 -170 -114 49 17 -58 34 105 124 22 201 -64 -131 -47 239 -130 33 -68 49 -132 94 210 -159 12 -92 -228 -80 -55 30 -137 253 146 50 -54 -113 130 90 -95 121 -100 -173 -153 75 -112 -399 -42 -175 307 202 -170 3 69 -210 150 -268 236 102 5 -140 98 -112 97 -198 -147 -187 417 1 9 -8 43 -5 192 113 -84 347 -190 -61 28 -29 -145 -50 -185 212 -182 44 85 -162 -148 -133 164 104 -232 323 150 69 -62 -113 417 5 76 60 -136 -9 -78 -62 383 238 25 -120 67 57 -33 -210 35 -18 -114 15 157 105 29 50 57 50 387 269 60 -40 -56 159 -77 -154 -6 -34 134 355 114 13 -118 183 95 10 215 150 -27 19 -224 349 -183 35 -232 48 16 -149 -152 54 -94 -320 -214 -277 18 88 -29 -98 -253 -149 -178 129 27 -124 -65 187 325 -186 -251 182 327 -155 -16 -9 11 122 122 62 -12 37 2 243 -171 -185 -59 -138 192 -50 -113 357 -71 -278 -77 -270 16 -112 164 33 159 -161 -148 -10 -258 -38 -136 -120 -150 -15 106 -149 225 -110 -34 34 -11 -65 -240 226 -383 -271 168 -52 -216 -407 -247 535 -249 73 -203 -76 291 -91 102 -109 191 125 6 121 36 -81 -10 -96 0 -35 50 -25 -360 68 -64 -158 39 61 -99 116 35 270 30 -317 -13 268 12 90 98 16 -120 -21 66 4 -54 -119 -88 290 446 -2 229 279 106 325 -85 131 -65 16 142 -21 206 -151 -49 9 -42 -40 -12 -28 134 -360 -178 -165 -139 -25 85 8 -4 -89 33 -128 225 23 431 50 14 53 -138 25 -4 186 196 30 -100 450 -126 241 -42 -58 -246 -181 5 77 -80 -181 44 -73 53 69 180 212 -406 -147 -96 -14 -49 153 -85 -219 55 271 75 118 59 238 -6 169 102 101 40 141 -206 108 -137 -50 -88 -194 -111 146 72 155 177 -131 114 -129 -169 114 -22 -14 -32 -55 74 -1 -243 -304 48 69 122 35 140 -168 84 165 200 -210 -47 -134 212 331 350 -59 94 -356 19 -279 50 146 -196 -62 94 -9 83 17 -179 -73 -317 -98 -70 50 -107 220 -85 -72 -194 -181 133 -91 135 -338 -161 -148 -58 304 30 -21 -11 -73 96 -149 92 115 141 -24 183 210 121 -183 63 -63 -52 -173 70 -298 -99 -89 174 -343 -145 -10 194 -40 95 -19 8 -258 -71 142 393 182 -99 133 427 98 29 -288 -105 1 158 -51 -295 -138 80 78 -179 -10 161 142 -292 38 -32 251 -55 -77 123 96 262 92 -494 25 -111 22 153 -43 112 205 -150 70 340 -234 207 0 -188 16 -17 20 -80 155 -306 -31 33 213 62 -185 -55 -49 -124 -28 -228 220 -336 125 103 -90 208 12 88 245 126 -254 327 -316 -38 -11 139 114 250 -79 -86 -69 -218 123 -256 -174 77 26 -89 51 151 174 31 278 -91 -191 -71 360 -199 51 -103 74 -197 139 313 -241 18 -143 -354 -123 -84 45 -211 390 227 78 -84 -173 195