File name: Pandora21s1_Bremen_20250624_L2Fit_fwvt1c10d20231020p1-8.txt
File generation date: 20250624T233237.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c10p1-8
Local principal investigator: Tom Hanisco
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 21
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora21_OF_v4d20190904.txt
Instrument calibration file used: Pandora21s1_CF_v10d20231020.txt
Level 1 file used: Pandora21s1_Bremen_20250624_L1_smca1c10d20231020p1-8.txt
Full location name: Bremen University
Short location name: Bremen
Country of location: Germany
Location latitude [deg]: 53.0813
Location longitude [deg]: 8.8126
Location altitude [m]: 50
Local noon date: 20250624
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1712 1862
Nominal wavelengths inside fitting window [nm]: 492.0069 492.1275 492.2480 492.3685 492.4890 492.6094 492.7299 492.8503 492.9707 493.0911 493.2115 493.3319 493.4522 493.5725 493.6929 493.8131 493.9334 494.0537 494.1739 494.2942 494.4144 494.5346 494.6547 494.7749 494.8950 495.0152 495.1353 495.2554 495.3754 495.4955 495.6155 495.7355 495.8555 495.9755 496.0955 496.2155 496.3354 496.4553 496.5752 496.6951 496.8150 496.9348 497.0547 497.1745 497.2943 497.4141 497.5338 497.6536 497.7733 497.8930 498.0127 498.1324 498.2521 498.3717 498.4913 498.6109 498.7305 498.8501 498.9697 499.0892 499.2087 499.3282 499.4477 499.5672 499.6867 499.8061 499.9255 500.0449 500.1643 500.2837 500.4031 500.5224 500.6417 500.7610 500.8803 500.9996 501.1188 501.2381 501.3573 501.4765 501.5957 501.7148 501.8340 501.9531 502.0722 502.1913 502.3104 502.4294 502.5485 502.6675 502.7865 502.9055 503.0245 503.1435 503.2624 503.3813 503.5002 503.6191 503.7380 503.8569 503.9757 504.0945 504.2133 504.3321 504.4509 504.5696 504.6884 504.8071 504.9258 505.0445 505.1632 505.2818 505.4004 505.5191 505.6377 505.7562 505.8748 505.9934 506.1119 506.2304 506.3489 506.4674 506.5858 506.7043 506.8227 506.9411 507.0595 507.1779 507.2963 507.4146 507.5329 507.6512 507.7695 507.8878 508.0061 508.1243 508.2425 508.3607 508.4789 508.5971 508.7152 508.8334 508.9515 509.0696 509.1877 509.3057 509.4238 509.5418 509.6599 509.7779 509.8958
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250624T081541.5Z 9306.344230 279 1 50.57 2 46.60 110.42 34.61 125.41 0.00 1 0.00 1 0 15 2.755e-03 2.726e-03 1.059e-03 1.055e-03 3.504563e+03 6.267543e+01 2.555030e+02 -6.000000e+00 1.458552e+02 280.80 -2.00 20.00 -2.00 505.23 0.00e+00 5.526136e-04 2.835976e-05 3.269740e-05 -6.000000e+00 7.562734e-05 280.80 -2.00 20.00 -2.00 500.28 0.00e+00 7.960947e-02 2.082978e-02 2.385023e-02 -6.000000e+00 5.413621e-02 233.73 -2.00 3.88 -2.00 501.89 0.00e+00 1.453 0.000 489.00 513.00 1 7.9414e+00 1.5914e-03 3.0039e-03 -6.0000e+00 4.1327e-03 5.6460e-03 4.1710e-04 5.9228e-04 -6.0000e+00 1.0921e-03 5.5694e-04 1.0182e-03 8.9856e-05 3.5488e-05 -6.0000e+00 2.4153e-04 -9.4672e-03 3.7163e-05 10 0 0 10 0 0 85.45 22.97 1.58 -0.00947 -0.00240 13 3 1 4 0 3889.400 26.00 19.99 22.97 22.32 37.0 1003.51 -728 -364 -365 -444 124 335 470 403 421 112 99 14 -155 50 -373 -265 -251 289 69 231 343 130 179 -50 327 294 434 123 186 -195 -454 -233 -138 32 67 215 237 60 13 -211 -482 2 -177 -57 312 -34 123 -91 187 47 -153 -496 -594 -311 -129 -167 -54 179 55 225 182 269 294 157 293 198 292 -17 -355 -297 -577 -502 -144 -198 54 132 -194 214 -497 -301 -392 -307 -89 -52 -311 -42 267 -26 63 -274 -29 2 368 172 133 352 55 209 -267 -276 -324 -472 -571 -285 -417 -90 201 -141 -235 -402 -205 -220 160 44 428 262 318 594 381 211 147 477 62 92 334 147 37 213 -45 78 407 221 205 -165 -56 -85 -67 -63 119 153 184 127 -49 30 -79 44 117 -75 -466 -621 -307 -705 -354 -365 -462 125 345 494 430 450 119 103 15 -158 50 -370 -262 -251 293 72 247 368 140 192 -54 352 318 468 132 196 -199 -450 -228 -137 32 72 233 256 64 14 -220 -501 2 -186 -60 334 -36 133 -97 196 49 -153 -483 -566 -294 -124 -166 -55 186 58 234 189 280 308 165 307 205 297 -18 -353 -292 -560 -484 -139 -194 53 132 -193 207 -475 -285 -371 -292 -85 -50 -304 -42 266 -26 63 -273 -29 2 375 169 131 358 55 204 -253 -256 -295 -429 -531 -275 -400 -88 196 -136 -222 -377 -194 -212 156 44 424 261 318 597 385 212 145 460 59 87 318 141 35 204 -43 74 388 209 191 -159 -54 -81 -61 -59 114 149 180 125 -49 30 -80 44 116 -73 -444 -579 -284
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SQ 20250624T083109.6Z 9306.354972 286 1 48.73 2 44.45 114.38 32.81 130.45 0.00 1 0.00 1 0 15 2.825e-03 2.803e-03 1.091e-03 1.088e-03 3.696307e+03 6.472373e+01 2.677323e+02 -6.000000e+00 1.495568e+02 280.80 -2.00 20.00 -2.00 505.26 0.00e+00 5.437175e-04 2.933320e-05 3.438441e-05 -6.000000e+00 7.754444e-05 280.80 -2.00 20.00 -2.00 500.32 0.00e+00 8.013525e-02 2.140329e-02 2.634677e-02 -6.000000e+00 5.550238e-02 233.73 -2.00 3.88 -2.00 501.94 0.00e+00 1.399 0.000 489.00 513.00 1 7.9380e+00 1.6364e-03 3.1050e-03 -6.0000e+00 4.2372e-03 4.8866e-03 4.2737e-04 6.4404e-04 -6.0000e+00 1.1195e-03 5.6295e-04 5.7430e-04 9.2358e-05 3.5274e-05 -6.0000e+00 2.4768e-04 -9.6085e-03 5.1434e-05 10 0 0 10 0 0 99.16 22.97 1.62 -0.00961 -0.00562 14 3 1 4 0 3479.758 26.00 19.99 22.97 22.19 37.3 1004.57 -550 -377 -400 -228 213 167 434 406 309 171 200 78 -34 232 -376 -386 21 277 -213 446 127 87 79 233 224 477 208 27 -12 -52 -368 -130 -36 -17 -131 212 233 -59 -235 -306 -153 -10 -172 8 266 103 214 92 182 -35 -129 -417 -478 -484 -257 -285 -62 65 206 205 138 310 369 350 399 -3 233 -32 -63 -236 -700 -716 -155 -310 -197 232 -262 -29 -446 -277 -178 -335 -133 -91 18 -28 15 -9 -41 -346 5 165 331 38 212 341 54 131 -326 -348 -583 -429 -478 -362 -304 58 212 -24 -257 -492 -330 -172 -71 117 353 471 524 515 410 281 16 251 109 153 340 258 162 139 268 187 462 131 212 -340 -92 -192 -162 9 126 -14 432 30 122 184 79 113 -31 -154 -221 -497 -737 -545 -375 -387 -229 219 175 465 442 338 185 213 82 -35 236 -380 -390 22 287 -229 485 139 95 82 242 234 498 217 28 -13 -54 -371 -130 -36 -18 -135 222 243 -61 -240 -326 -162 -10 -175 8 275 108 223 95 185 -35 -132 -414 -464 -467 -251 -289 -62 65 208 206 139 311 373 355 404 -3 229 -31 -64 -236 -695 -706 -153 -311 -190 224 -251 -28 -435 -267 -171 -325 -131 -89 18 -27 14 -8 -39 -333 5 160 326 38 212 334 52 123 -316 -328 -542 -398 -453 -337 -296 58 210 -24 -247 -471 -318 -168 -70 117 356 476 532 527 422 287 17 247 106 148 329 251 158 135 261 181 447 126 200 -316 -85 -177 -151 8 122 -14 429 31 123 187 80 110 -32 -153 -213 -471 -696
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