File name: Pandora134s1_BristolPA_20231111_L2Fit_fout2c2d20210612p1-8.txt File generation date: 20231112T052823.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v2d20210612.txt Level 1 file used: Pandora134s1_BristolPA_20231111_L1_smca1c2d20210612p1-8.txt Full location name: Bristol, Pennsylvania; Philadelphia-Camden-Wilmington, PA-NJ-DE-MD; A420170012 Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20231111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0874 305.2288 305.3702 305.5115 305.6529 305.7942 305.9356 306.0769 306.2182 306.3595 306.5008 306.6420 306.7833 306.9246 307.0658 307.2070 307.3482 307.4894 307.6306 307.7718 307.9130 308.0541 308.1953 308.3364 308.4775 308.6187 308.7598 308.9008 309.0419 309.1830 309.3240 309.4651 309.6061 309.7471 309.8881 310.0291 310.1701 310.3111 310.4521 310.5930 310.7340 310.8749 311.0158 311.1567 311.2976 311.4385 311.5793 311.7202 311.8610 312.0019 312.1427 312.2835 312.4243 312.5651 312.7059 312.8466 312.9874 313.1281 313.2689 313.4096 313.5503 313.6910 313.8317 313.9724 314.1130 314.2537 314.3943 314.5349 314.6755 314.8161 314.9567 315.0973 315.2379 315.3784 315.5190 315.6595 315.8000 315.9406 316.0811 316.2215 316.3620 316.5025 316.6429 316.7834 316.9238 317.0642 317.2046 317.3450 317.4854 317.6258 317.7661 317.9065 318.0468 318.1871 318.3275 318.4678 318.6081 318.7483 318.8886 319.0289 319.1691 319.3093 319.4495 319.5898 319.7300 319.8701 320.0103 320.1505 320.2906 320.4308 320.5709 320.7110 320.8511 320.9912 321.1313 321.2713 321.4114 321.5514 321.6915 321.8315 321.9715 322.1115 322.2515 322.3915 322.5314 322.6714 322.8113 322.9513 323.0912 323.2311 323.3710 323.5109 323.6507 323.7906 323.9304 324.0703 324.2101 324.3499 324.4897 324.6295 324.7693 324.9090 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231111T122517.0Z 8715.517558 114 1 51.64 2 83.08 119.78 65.13 131.98 0.00 1 0.00 1 0 17 5.928e-01 3.943e-02 4.181e-01 3.375e-02 7.289263e-01 1.906776e-02 9.090499e-03 -6.000000e+00 3.325280e-01 223.75 -2.00 3.49 -2.00 321.95 0.00e+00 1.696511e-02 8.961624e-03 3.385995e-03 -6.000000e+00 1.600338e-02 281.63 -2.00 20.00 -2.00 321.43 0.00e+00 7.605 0.008 302.00 328.00 3 1.2778e+00 6.7328e-02 8.4551e-02 -6.0000e+00 8.1861e-01 1.0912e+00 8.2112e-02 3.8482e-02 -6.0000e+00 8.9212e-01 -1.4416e+00 5.9668e-02 2.2667e-02 -6.0000e+00 5.3197e-01 5.7814e-01 3.0346e-02 1.5132e-02 -6.0000e+00 2.3410e-01 3.4861e-05 -2.7656e-03 9.7358e-04 2.2752e-04 -6.0000e+00 1.5423e-02 6.7512e-03 -7.4890e-05 12 8 8 10 0 0 6.38 21.25 0.71 0.00675 -0.01403 22 4 1 5 0 2347.183 26.83 20.00 21.25 7.24 28.9 906.06 900000 130154 900000 -5686 -32505 900000 55747 -99653 -28055 426823 -71848 900000 -97490 -9500 27912 900000 -45288 190263 62880 215293 -75906 900000 -19791 900000 1790 17374 -43064 900000 -16125 900000 -31991 8125 -4322 88485 66707 148279 -2994 88707 22527 41781 32669 -15115 120306 59211 6905 20024 89376 98230 60331 73 47804 9315 62595 30313 80170 41627 20633 12104 36378 -1248 9219 20967 41688 37844 20575 41448 24571 39480 24374 29980 17912 13388 -6530 5717 -16285 1630 28218 -3906 -13128 8865 1738 -3362 -1452 -13488 -7082 1478 -870 5290 -4401 8002 -1341 -5350 3244 -11284 1848 -1171 -1185 -2206 -952 -6809 -2979 -2427 -541 -3014 -3901 -1557 4604 -4527 4220 -6963 3445 -2219 -2167 1455 4201 -3905 -860 186 2121 3293 4113 4305 1640 -316 -556 464 -453 3909 -2754 1232 -300 3298 -1889 1146 -1092 425 442 857 -95 -703 -2072 -758 900000 4276 900000 -269 -1629 900000 1831 -7357 -990 14021 -3404 900000 -8507 -455 1144 900000 -4588 6250 2361 7072 -9843 900000 -1272 900000 86 693 -2907 900000 -798 900000 -2510 507 -340 2907 2292 4871 -203 2914 1548 2619 2356 -1789 3952 3506 683 1782 4124 4264 3894 9 4046 1242 5249 3624 5988 4488 2687 1633 3699 -180 1268 2893 5429 5713 3705 5868 4074 5867 4756 6187 4417 3462 -1951 1393 -4324 331 4307 -873 -3789 2475 606 -1375 -622 -6849 -3591 727 -457 2645 -2383 3658 -624 -2446 1369 -5970 1009 -781 -917 -1977 -892 -6539 -2526 -1805 -378 -2261 -3188 -1309 3904 -4609 4475 -9443 4649 -3251 -3176 1970 5276 -5268 -1177 269 3194 4952 5986 5977 2278 -434 -743 590 -585 5468 -4799 2326 -619 6930 -4443 2810 -2918 1152 1216 2366 -256 -1820 -5047 -1719 SS 20231111T123555.3Z 8715.524946 117 1 51.59 2 81.34 121.64 63.72 134.34 0.00 1 0.00 1 0 17 5.807e-01 2.820e-02 4.159e-01 2.090e-02 6.433269e-01 1.145290e-02 7.233858e-03 -6.000000e+00 3.284669e-01 223.75 -2.00 3.49 -2.00 321.62 0.00e+00 4.422476e-03 5.763888e-03 9.614868e-04 -6.000000e+00 1.568194e-02 281.62 -2.00 20.00 -2.00 321.10 0.00e+00 6.265 0.004 302.00 328.00 3 2.2524e+00 4.0684e-02 7.0704e-02 -6.0000e+00 8.0860e-01 4.5432e-01 5.2500e-02 3.4384e-02 -6.0000e+00 8.8160e-01 -6.5761e-01 4.6577e-02 1.8090e-02 -6.0000e+00 5.2310e-01 2.7245e-01 2.2386e-02 7.5985e-03 -6.0000e+00 2.2773e-01 5.7830e-05 -8.4454e-04 6.1091e-04 9.6083e-05 -6.0000e+00 1.5476e-02 5.3318e-03 1.4089e-04 12 8 8 10 0 0 99.82 21.25 0.44 0.00533 -0.00101 21 4 1 5 0 2456.344 26.83 19.99 21.25 8.67 28.7 914.32 -122765 900000 -176601 900000 -137680 900000 900000 3548 -96047 -67779 -140580 -72782 -82020 8881 343056 900000 -14056 -57959 64432 98818 900000 -68487 81374 -29018 79563 -26818 900000 -52058 900000 -40766 -36508 81193 158662 48506 100200 88547 15410 123736 132082 -1996 195398 41302 55886 91332 70209 31455 6301 30574 -7490 21322 -14581 51148 25798 24238 14000 26066 41115 53346 -7402 25079 5786 35175 3512 21777 7952 17007 982 7166 16269 12080 1487 -2127 3766 907 -3152 -17110 -3249 -2639 -3426 -4846 -881 -3411 5963 -4498 2241 -3093 4502 -4440 4950 -706 231 -3575 -6104 -1773 -5903 -4087 2206 -140 78 -110 -3242 -1788 -1676 634 12 -33 -1294 -364 -1758 172 -927 -198 518 264 -2762 -2081 -2124 -1016 864 859 1570 2138 3961 4286 2940 -2013 -1415 920 -651 196 1916 180 1260 -1217 1495 -686 521 1077 47 -1081 -865 -2409 -3631 900000 -9855 900000 -4225 900000 900000 72 -2326 -1379 -5311 -1609 -2476 181 6981 900000 -418 -2808 1311 2011 900000 -3703 1656 -1174 1619 -1137 900000 -2593 900000 -1946 -1988 1681 3229 1573 2039 1802 691 2518 2760 -173 3976 2695 3278 3832 3632 2386 613 2429 -887 2052 -2199 4540 3132 3194 2109 3610 4984 5604 -1339 3294 963 4942 759 4361 1837 3456 231 1672 3960 3488 509 -766 1234 284 -924 -5173 -830 -710 -1084 -1846 -372 -1664 2836 -2502 1255 -1931 2734 -2990 2993 -427 129 -1957 -3382 -1021 -4086 -3226 1893 -139 80 -110 -3053 -1486 -1342 531 11 -31 -1329 -401 -2199 236 -1405 -305 777 378 -3876 -2859 -3039 -1530 1356 1367 2415 3138 5577 5828 3918 -2696 -1897 1340 -1099 363 3755 375 2747 -2903 3697 -1776 1361 2825 121 -2665 -2000 -5397 SS 20231111T125014.8Z 8715.534894 122 1 51.03 2 79.04 124.20 61.90 137.63 0.00 1 0.00 1 0 25 2.886e-01 6.851e-03 1.317e-01 3.516e-03 5.591003e-01 1.823445e-03 6.639053e-03 -6.000000e+00 1.597988e-01 223.75 -2.00 3.49 -2.00 321.08 0.00e+00 -1.108644e-03 8.398182e-04 2.901216e-03 -6.000000e+00 7.107943e-03 281.62 -2.00 20.00 -2.00 320.53 0.00e+00 5.069 0.002 302.00 328.00 3 8.9156e-01 6.0772e-03 5.9883e-02 -6.0000e+00 3.9391e-01 -2.0279e-02 8.2600e-03 3.5369e-02 -6.0000e+00 4.2882e-01 -3.8998e-02 8.3857e-03 1.7132e-02 -6.0000e+00 2.5590e-01 1.6590e-02 4.0606e-03 4.7236e-03 -6.0000e+00 1.1108e-01 8.3484e-04 -1.0489e-03 1.0045e-04 7.1558e-05 -6.0000e+00 7.3313e-03 4.8139e-03 1.2766e-05 11 8 0 10 0 0 99.01 21.25 0.30 0.00481 -0.00307 152 27 1 5 0 335.656 26.83 20.00 21.25 9.51 28.9 919.93 -128569 -118472 -115969 -80944 -99273 -69461 -97613 -76845 -100521 -58527 -62068 -70992 -56848 -41717 -18575 -830 -15477 -17397 -6730 -17826 -9315 -32205 -7673 -25193 6026 -12079 -11017 -9168 -6629 -14200 -1602 -12188 4841 -7594 -4991 -11929 -1916 -4544 3815 1567 3184 1429 1532 37 167 6399 -397 54 -2802 594 2013 903 1265 3410 2099 4796 1422 769 1185 141 744 3585 3226 2976 8 1908 -583 1246 -974 1144 366 1159 1038 876 528 -616 -2518 -4294 -2208 -3277 -946 -1803 -1877 -2114 -627 -195 1059 491 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