File name: Pandora134s1_BristolPA_20231116_L2Fit_fout2c5d20230501p1-8.txt File generation date: 20240825T100411.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v5d20230501.txt Level 1 file used: Pandora134s1_BristolPA_20231116_L1_smca1c5d20230501p1-8.txt Full location name: Bristol, Pennsylvania; Philadelphia-Camden-Wilmington, PA-NJ-DE-MD; A420170012 Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20231116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 3 for VP from 20230501 First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0892 305.2306 305.3720 305.5133 305.6546 305.7959 305.9373 306.0785 306.2198 306.3611 306.5024 306.6436 306.7849 306.9261 307.0673 307.2085 307.3497 307.4909 307.6320 307.7732 307.9144 308.0555 308.1966 308.3377 308.4788 308.6199 308.7610 308.9021 309.0431 309.1842 309.3252 309.4662 309.6073 309.7483 309.8893 310.0302 310.1712 310.3122 310.4531 310.5940 310.7350 310.8759 311.0168 311.1577 311.2985 311.4394 311.5803 311.7211 311.8619 312.0027 312.1436 312.2844 312.4251 312.5659 312.7067 312.8474 312.9882 313.1289 313.2696 313.4103 313.5510 313.6917 313.8324 313.9730 314.1137 314.2543 314.3950 314.5356 314.6762 314.8168 314.9574 315.0979 315.2385 315.3790 315.5196 315.6601 315.8006 315.9411 316.0816 316.2221 316.3625 316.5030 316.6435 316.7839 316.9243 317.0647 317.2051 317.3455 317.4859 317.6262 317.7666 317.9069 318.0473 318.1876 318.3279 318.4682 318.6085 318.7488 318.8890 319.0293 319.1695 319.3097 319.4500 319.5902 319.7304 319.8705 320.0107 320.1509 320.2910 320.4312 320.5713 320.7114 320.8515 320.9916 321.1317 321.2717 321.4118 321.5518 321.6919 321.8319 321.9719 322.1119 322.2519 322.3919 322.5318 322.6718 322.8117 322.9516 323.0916 323.2315 323.3714 323.5112 323.6511 323.7910 323.9308 324.0707 324.2105 324.3503 324.4901 324.6299 324.7697 324.9094 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231116T123134.4Z 8720.521926 60 1 51.26 2 83.12 121.66 119.38 104.26 0.00 1 0.00 1 0 17 6.958e-01 4.316e-02 5.030e-01 3.520e-02 9.005731e-01 2.112538e-02 1.350920e-02 -6.000000e+00 4.041177e-01 223.39 -2.00 3.49 -2.00 322.25 0.00e+00 -2.865294e-02 1.152780e-02 1.779249e-02 -6.000000e+00 2.171759e-02 281.03 -2.00 20.00 -2.00 321.79 0.00e+00 7.639 0.008 302.00 328.00 3 1.8843e+00 8.3416e-02 1.2055e-01 -6.0000e+00 1.0056e+00 9.8563e-01 1.0676e-01 1.0268e-01 -6.0000e+00 1.1073e+00 -1.4838e+00 8.5871e-02 5.6128e-02 -6.0000e+00 6.4789e-01 6.1310e-01 4.1546e-02 2.0205e-02 -6.0000e+00 2.8006e-01 1.8207e-05 -1.8052e-03 1.0281e-03 5.7119e-04 -6.0000e+00 1.9638e-02 1.8777e-03 0.0000e+00 12 8 8 10 0 0 43.88 21.26 0.74 0.00188 -0.01169 22 4 1 5 0 2329.803 26.83 20.00 21.26 9.71 29.0 928.57 10833 900000 900000 -127921 900000 -150293 900000 -73580 900000 -43591 900000 900000 11257 -50839 900000 900000 900000 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2106 1778 1195 -828 3227 2002 4095 -1316 3362 900000 9419 4604 5050 9654 -1899 1850 -2477 6963 -2814 3526 2170 4912 -954 4130 2570 4876 3455 6579 1110 2179 -4963 -530 -8034 1812 238 -3124 -2900 3217 844 -5371 4468 3925 4336 -764 3380 -3368 5781 -1360 8478 3143 4112 -3985 4515 -5461 3516 -5825 3363 -1526 4123 1222 2530 -1477 -5369 -2005 -6082 -1893 -57 -3738 -6512 1933 -6782 2311 -4464 -1920 -4847 -2905 4078 1902 4766 7352 1478 8511 516 6689 -5423 6926 -2417 -71 352 5228 -3369 2313 2835 3969 749 673 -1327 -6723 -6079 SS 20231116T124206.5Z 8720.529242 63 1 50.97 2 81.42 123.50 117.53 105.63 0.00 1 0.00 1 0 25 7.112e-01 2.306e-02 3.468e-01 1.045e-02 7.823566e-01 5.950581e-03 8.713472e-03 -6.000000e+00 4.020291e-01 223.39 -2.00 3.49 -2.00 321.96 0.00e+00 5.723508e-03 3.358760e-03 1.105281e-03 -6.000000e+00 1.987133e-02 281.03 -2.00 20.00 -2.00 321.50 0.00e+00 6.322 0.004 302.00 328.00 3 1.4646e+00 2.2718e-02 7.6095e-02 -6.0000e+00 9.9719e-01 5.3041e-01 3.2019e-02 4.5584e-02 -6.0000e+00 1.0910e+00 -8.0504e-01 3.1583e-02 2.3415e-02 -6.0000e+00 6.4590e-01 3.4216e-01 1.4624e-02 9.4314e-03 -6.0000e+00 2.7831e-01 1.0239e-04 -1.7468e-03 2.9743e-04 1.1306e-04 -6.0000e+00 1.9034e-02 2.2496e-03 0.0000e+00 12 8 8 10 0 0 39.75 21.26 0.52 0.00225 -0.01088 65 11 1 5 0 784.059 26.83 20.00 21.26 11.13 28.8 937.33 -58449 67469 -81986 900000 -213057 -95539 -93730 900000 44293 900000 -182472 900000 -160089 900000 -126440 900000 -62729 900000 -92966 900000 -90371 900000 -27120 900000 -68301 143854 -42476 315353 -69146 -95 27254 46821 91376 -8293 44355 -25733 191038 -31804 447137 -12054 187706 -3601 70703 -2860 59419 14079 104120 3692 59704 20516 48273 12259 59519 25292 27521 19049 27367 19992 19268 11874 20656 7502 16533 26879 16858 30381 2848 17758 -7267 17789 -3274 12148 985 20528 -6058 13363 -10975 7898 -808 -1312 -3303 323 -363 1009 1841 2799 369 1540 2708 -1909 4486 -5516 -2926 -5583 659 -5208 289 -2457 1151 -2497 1311 -5084 1580 -6154 108 -5333 113 -3834 1175 -956 1081 141 -79 -743 -982 -712 -396 -296 -3 1369 539 2730 92 3115 -27 3187 -555 1682 -237 1878 -566 957 -737 370 -491 234 568 729 -441 -127 -1161 -1530 -594 686 -861 900000 -6396 -971 -953 900000 450 900000 -4788 900000 -5041 900000 -4721 900000 -1637 900000 -3657 900000 -3476 900000 -561 900000 -2319 1463 -1124 3207 -2255 -2 481 833 1195 -294 870 -982 1942 -1662 4547 -727 1909 -230 2298 -191 2179 814 2599 254 2526 1372 2805 1117 3750 2373 2631 2042 2719 2068 1945 1266 2123 978 2283 3774 2694 4209 516 2946 -1775 3868 -942 3034 263 4193 -1409 2341 -2395 1544 -206 -398 -1201 129 -157 456 881 1402 198 824 1404 -979 2046 -2648 -1376 -2979 382 -3788 233 -2327 1111 -2416 1105 -4026 1124 -4999 89 -4782 105 -3973 1320 -1256 1540 211 -118 -1070 -1352 -965 -557 -441 -5 2116 804 3863 129 4129 -35 3928 -717 2402 -403 3466 -1164 2057 -1715 900 -1281 621 1524 1962 -1164 -316 -2708 -3371 SS 20231116T125705.1Z 8720.539642 68 1 51.01 2 79.08 126.20 114.92 107.57 0.00 1 0.00 1 0 25 4.195e-01 7.491e-03 2.082e-01 3.377e-03 6.533246e-01 1.797909e-03 7.457684e-03 -6.000000e+00 2.328727e-01 223.39 -2.00 3.49 -2.00 321.41 0.00e+00 1.451096e-03 9.101377e-04 3.194601e-03 -6.000000e+00 1.034221e-02 281.03 -2.00 20.00 -2.00 320.90 0.00e+00 5.085 0.002 302.00 328.00 3 1.1750e+00 6.2898e-03 6.3823e-02 -6.0000e+00 5.7365e-01 2.3122e-02 9.0633e-03 4.3356e-02 -6.0000e+00 6.2454e-01 -7.9746e-02 9.7183e-03 1.9711e-02 -6.0000e+00 3.7267e-01 3.3660e-02 4.5839e-03 6.8394e-03 -6.0000e+00 1.6169e-01 5.4026e-04 -9.3078e-04 9.4833e-05 7.1587e-05 -6.0000e+00 1.0772e-02 1.7308e-03 0.0000e+00 11 8 0 10 0 0 26.77 21.25 0.28 0.00173 -0.00526 176 31 1 5 0 289.807 26.73 20.00 21.25 13.14 29.1 951.08 -180857 65061 -199630 -17822 -168798 -122083 -160922 -30603 -170577 -130811 -118353 -42762 -92761 -73658 -50160 -41251 -13779 -31412 -8256 -29516 7831 -31791 2994 -37137 -1380 -21800 7334 -36339 6958 -44561 5777 -9291 10127 -13736 2860 -20855 11429 -3989 1751 2164 2803 760 4292 2347 -4156 4140 -842 429 -2809 6993 253 6057 3033 5967 16 5415 1180 2814 -1155 7420 -854 6807 3335 5765 1436 3783 -1368 1223 1933 1233 -402 39 -449 -1814 1197 -1560 -2002 -4639 -851 -2368 -1127 -2722 -1165 -2169 840 -572 1105 250 1955 898 1163 -657 494 43 -399 356 667 663 387 -159 -493 160 -164 -578 -1130 -651 -1243 -316 209 380 40 322 134 -107 -53 -232 -804 -359 -915 -394 -149 486 768 623 343 68 971 411 363 -55 54 -271 121 -110 -16 50 699 114 146 -277 -201 -817 -1521 214 -2494 -59 -1394 -648 -1397 -101 -2163 -1231 -1041 -212 -960 -818 -560 -502 -145 -434 -99 -458 87 -518 38 -764 -22 -448 116 -837 107 -1245 121 -269 282 -496 84 -783 359 -176 91 132 189 56 320 181 -349 330 -72 38 -271 670 29 740 417 867 3 874 204 472 -195 1149 -152 1273 739 1382 366 915 -349 322 582 427 -152 15 -168 -644 375 -453 -567 -1434 -295 -992 -539 -1486 -673 -1343 542 -395 785 181 1376 606 731 -398 293 28 -296 304 653 728 443 -176 -501 145 -144 -540 -1144 -684 -1397 -379 278 561 63 527 215 -165 -78 -333 -1203 -565 -1522 -659 -242 752 1157 911 487 93 1320 619 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