File name: Pandora134s1_BristolPA_20231213_L2Fit_fout2c2d20210612p1-8.txt File generation date: 20240123T191410.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v2d20210612.txt Level 1 file used: Pandora134s1_BristolPA_20231213_L1_smca1c2d20210612p1-8.txt Full location name: Bristol, Pennsylvania; Philadelphia-Camden-Wilmington, PA-NJ-DE-MD; A420170012 Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20231213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0874 305.2288 305.3702 305.5115 305.6529 305.7942 305.9356 306.0769 306.2182 306.3595 306.5008 306.6420 306.7833 306.9246 307.0658 307.2070 307.3482 307.4894 307.6306 307.7718 307.9130 308.0541 308.1953 308.3364 308.4775 308.6187 308.7598 308.9008 309.0419 309.1830 309.3240 309.4651 309.6061 309.7471 309.8881 310.0291 310.1701 310.3111 310.4521 310.5930 310.7340 310.8749 311.0158 311.1567 311.2976 311.4385 311.5793 311.7202 311.8610 312.0019 312.1427 312.2835 312.4243 312.5651 312.7059 312.8466 312.9874 313.1281 313.2689 313.4096 313.5503 313.6910 313.8317 313.9724 314.1130 314.2537 314.3943 314.5349 314.6755 314.8161 314.9567 315.0973 315.2379 315.3784 315.5190 315.6595 315.8000 315.9406 316.0811 316.2215 316.3620 316.5025 316.6429 316.7834 316.9238 317.0642 317.2046 317.3450 317.4854 317.6258 317.7661 317.9065 318.0468 318.1871 318.3275 318.4678 318.6081 318.7483 318.8886 319.0289 319.1691 319.3093 319.4495 319.5898 319.7300 319.8701 320.0103 320.1505 320.2906 320.4308 320.5709 320.7110 320.8511 320.9912 321.1313 321.2713 321.4114 321.5514 321.6915 321.8315 321.9715 322.1115 322.2515 322.3915 322.5314 322.6714 322.8113 322.9513 323.0912 323.2311 323.3710 323.5109 323.6507 323.7906 323.9304 324.0703 324.2101 324.3499 324.4897 324.6295 324.7693 324.9090 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231213T125939.9Z 8747.541434 62 1 51.27 2 83.44 127.90 92.83 126.01 0.00 1 0.00 1 0 25 5.162e-01 2.852e-02 4.645e-01 2.476e-02 9.605067e-01 1.430368e-02 1.174602e-02 -6.000000e+00 2.932475e-01 222.98 -2.00 3.49 -2.00 322.36 0.00e+00 4.504666e-03 7.764676e-03 1.592107e-02 -6.000000e+00 1.329450e-02 278.09 -2.00 20.00 -2.00 321.91 0.00e+00 7.948 0.009 302.00 328.00 3 2.0642e-01 5.4982e-02 1.3097e-01 -6.0000e+00 7.2655e-01 1.3971e+00 7.0293e-02 1.2921e-01 -6.0000e+00 7.9683e-01 -1.8059e+00 5.8025e-02 5.0789e-02 -6.0000e+00 4.6762e-01 7.1502e-01 2.8345e-02 8.7946e-03 -6.0000e+00 1.9926e-01 5.5502e-05 -4.3616e-03 6.5186e-04 2.7813e-04 -6.0000e+00 1.3704e-02 9.3094e-03 -2.8812e-04 12 8 8 10 0 0 53.37 21.36 0.55 0.00931 -0.02347 44 8 1 5 0 1165.075 26.94 20.01 21.36 6.92 29.0 931.71 20433 -15720 74003 -57805 900000 -41144 900000 -90609 900000 -107318 -49501 38706 -29633 -82507 -53450 101267 122462 5560 900000 900000 129351 100709 900000 171127 -77413 638 -33891 -33937 26014 -3896 48579 41633 -44197 900000 -40260 -36133 -55372 156227 20106 -6354 112855 91061 50562 190777 54194 139933 59779 900000 -2982 186713 43855 40215 38567 70789 24785 71465 37155 44906 33766 50731 40117 -5995 83782 1347 40522 5825 7916 3440 22155 15890 19398 12713 39514 45951 5804 68999 -19950 8009 -15199 -4889 6104 3625 1756 1970 -2528 4777 11528 10834 1088 4677 -4671 -6559 -12674 -9360 -5266 -6744 -5966 -679 -1014 421 -2262 -1989 -6941 -303 1764 -2110 -1906 559 -1938 339 1363 -1904 -194 1259 493 -2084 -1215 -2198 957 -2836 3583 -35 2044 92 4077 3027 2334 -368 1242 946 -594 449 1062 254 -608 -39 1265 504 -26 -57 -1316 -2292 493 -525 1784 -2358 900000 -992 900000 -3529 900000 -4777 -1193 933 -893 -4896 -2875 2441 2952 223 900000 900000 3119 2428 900000 4126 -5599 21 -1430 -1295 627 -117 1171 1171 -3285 900000 -2507 -2033 -4005 3766 929 -434 2721 2794 2327 4599 2257 3374 2358 900000 -222 4501 2691 2820 2958 4189 2390 4386 3176 3346 2590 3113 2814 -749 4958 207 4352 868 1180 573 3496 3030 3784 2647 5889 5741 941 5293 -3673 1229 -3564 -1264 1672 1168 623 734 -1042 1916 4472 4250 458 1783 -1822 -2516 -5306 -4288 -2782 -4346 -4147 -519 -829 329 -1784 -1356 -4594 -197 1206 -1577 -1529 486 -2013 405 1670 -2563 -260 1766 671 -2887 -1740 -3368 1489 -4544 5081 -48 2697 121 5004 3623 2865 -538 2136 1883 -1331 1070 2485 646 -1666 -108 3512 1411 -72 -156 -3314 -5411 SS 20231213T131010.2Z 8747.548730 65 1 51.07 2 81.87 129.76 91.29 127.62 0.00 1 0.00 1 0 39 5.642e-01 1.869e-02 3.396e-01 9.267e-03 8.355575e-01 5.163819e-03 9.237906e-03 -6.000000e+00 3.113686e-01 222.98 -2.00 3.49 -2.00 322.10 0.00e+00 1.125294e-02 2.875757e-03 5.924991e-03 -6.000000e+00 1.369070e-02 278.09 -2.00 20.00 -2.00 321.67 0.00e+00 6.630 0.005 302.00 328.00 3 3.1776e-01 1.9572e-02 9.0806e-02 -6.0000e+00 7.6716e-01 6.6491e-01 2.7400e-02 7.6680e-02 -6.0000e+00 8.3617e-01 -9.4372e-01 2.7242e-02 2.6451e-02 -6.0000e+00 4.9823e-01 4.0048e-01 1.2644e-02 1.3984e-02 -6.0000e+00 2.1589e-01 2.1790e-04 -2.2521e-03 2.5099e-04 1.1707e-04 -6.0000e+00 1.4328e-02 7.4767e-03 7.0010e-05 12 8 8 10 0 0 99.82 21.37 0.28 0.00748 -0.00945 94 17 1 5 0 543.198 26.94 20.00 21.37 8.68 28.9 944.50 -121900 -170046 -126319 -215988 -22302 -177792 -92035 -161758 -122141 -170795 -24015 -128623 21807 -98804 -57521 -72525 14180 -5906 -11067 28055 -60455 -24870 -5838 152920 223497 -32824 -85538 -63019 -58478 -30655 -34248 25053 78080 133284 -6907 156689 -16336 81208 8410 41132 46930 24082 9267 41247 16305 37010 27621 42226 39378 34999 18323 37415 39795 18665 36058 34089 25654 18247 16677 9760 23339 10090 17655 20258 22204 15624 12253 2492 17472 11258 12818 8183 6687 -310 6515 -2956 748 -1959 -388 -212 -529 -2034 -915 1143 -1770 2906 576 -503 645 1170 -2498 1590 -3982 -1378 -4079 -1992 -2106 -732 -401 1123 -3059 1154 -2559 -1535 -3357 -2309 -2583 -965 -983 -777 -783 -715 -648 339 -1635 -1059 -320 -152 625 -210 1715 2078 1802 2566 2166 796 1557 470 641 711 562 310 136 -278 225 -25 572 -3 11 179 -1172 -2055 -1652 -4225 -2093 -7969 -202 -3481 -832 -3056 -1605 -3648 -217 -2113 197 -2191 -1087 -1906 175 -97 -200 346 -1738 -470 -91 1382 2020 -701 -3021 -1708 -1537 -705 -1041 515 1199 1204 -210 1416 -577 1394 325 1318 1542 1048 487 1592 817 1551 1316 1838 1876 1898 1325 2490 2811 1748 2932 2884 2360 1739 1534 946 2090 1177 2233 2846 3174 2336 1922 458 3172 2488 2980 2010 1582 -72 1242 -556 133 -393 -92 -61 -181 -807 -387 499 -848 1401 296 -265 329 559 -1153 673 -1799 -676 -2443 -1394 -1740 -686 -398 1061 -2719 859 -1848 -1157 -2772 -1982 -2383 -965 -1128 -1028 -1154 -1101 -994 496 -2331 -1484 -463 -232 1001 -338 2581 2951 2493 3413 2806 1004 1972 687 1101 1387 1201 706 330 -730 626 -70 1642 -9 30 464 -2833 -4692 SS 20231213T132117.6Z 8747.556453 68 1 51.12 2 80.26 131.76 89.70 129.35 0.00 1 0.00 1 0 17 5.892e-01 9.344e-03 3.185e-01 5.692e-03 7.408906e-01 3.103395e-03 8.130132e-03 -6.000000e+00 3.252510e-01 222.98 -2.00 3.49 -2.00 321.76 0.00e+00 2.963898e-03 1.654320e-03 2.466466e-03 -6.000000e+00 1.473682e-02 278.09 -2.00 20.00 -2.00 321.30 0.00e+00 5.647 0.003 302.00 328.00 3 7.8508e-01 1.1237e-02 7.0628e-02 -6.0000e+00 8.0141e-01 1.6506e-01 1.6980e-02 4.7329e-02 -6.0000e+00 8.7351e-01 -2.3987e-01 1.8941e-02 2.3092e-02 -6.0000e+00 5.2045e-01 9.9098e-02 8.7800e-03 9.1919e-03 -6.0000e+00 2.2593e-01 4.1464e-04 -5.4488e-04 1.5784e-04 8.9999e-05 -6.0000e+00 1.4963e-02 7.4497e-03 1.0726e-04 12 8 8 10 0 0 99.98 21.36 0.28 0.00745 0.00336 123 22 1 5 0 415.583 26.94 20.00 21.36 10.16 28.8 953.83 -217608 -202411 -177522 -91321 -170552 -192805 -151510 -174634 -124916 -191556 -167128 900000 -148176 -68998 -102744 -2977 -100322 159244 -120404 -36191 -98226 73871 -24709 -14166 -48045 -40043 -30700 -20375 -74678 129339 20763 36744 1277 -18914 2860 -14560 2381 11334 3873 -1599 10058 -3494 14262 -12729 3566 -4079 16408 5781 23976 -7222 18521 3523 13743 11121 6854 5267 8003 1384 2880 4408 8522 4753 6798 3553 4948 1384 -2223 4130 -179 4273 -647 1897 1653 3694 -1012 -559 -4866 1267 -2948 -1111 -1772 -2209 -2045 -146 -437 2130 925 1385 1735 1203 -544 -1711 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