File name: Pandora134s1_BristolPA_20240507_L2Fit_fout2c2d20210612p1-8.txt File generation date: 20240511T131053.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v2d20210612.txt Level 1 file used: Pandora134s1_BristolPA_20240507_L1_smca1c2d20210612p1-8.txt Full location name: Bristol, Pennsylvania; Philadelphia-Camden-Wilmington, PA-NJ-DE-MD; A420170012 Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20240507 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0874 305.2288 305.3702 305.5115 305.6529 305.7942 305.9356 306.0769 306.2182 306.3595 306.5008 306.6420 306.7833 306.9246 307.0658 307.2070 307.3482 307.4894 307.6306 307.7718 307.9130 308.0541 308.1953 308.3364 308.4775 308.6187 308.7598 308.9008 309.0419 309.1830 309.3240 309.4651 309.6061 309.7471 309.8881 310.0291 310.1701 310.3111 310.4521 310.5930 310.7340 310.8749 311.0158 311.1567 311.2976 311.4385 311.5793 311.7202 311.8610 312.0019 312.1427 312.2835 312.4243 312.5651 312.7059 312.8466 312.9874 313.1281 313.2689 313.4096 313.5503 313.6910 313.8317 313.9724 314.1130 314.2537 314.3943 314.5349 314.6755 314.8161 314.9567 315.0973 315.2379 315.3784 315.5190 315.6595 315.8000 315.9406 316.0811 316.2215 316.3620 316.5025 316.6429 316.7834 316.9238 317.0642 317.2046 317.3450 317.4854 317.6258 317.7661 317.9065 318.0468 318.1871 318.3275 318.4678 318.6081 318.7483 318.8886 319.0289 319.1691 319.3093 319.4495 319.5898 319.7300 319.8701 320.0103 320.1505 320.2906 320.4308 320.5709 320.7110 320.8511 320.9912 321.1313 321.2713 321.4114 321.5514 321.6915 321.8315 321.9715 322.1115 322.2515 322.3915 322.5314 322.6714 322.8113 322.9513 323.0912 323.2311 323.3710 323.5109 323.6507 323.7906 323.9304 324.0703 324.2101 324.3499 324.4897 324.6295 324.7693 324.9090 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240507T110916.7Z 8893.464777 79 1 50.86 2 76.67 78.83 70.77 85.51 0.00 1 0.00 1 0 17 3.774e-01 1.568e-02 3.572e-01 1.241e-02 5.997315e-01 6.723905e-03 6.951085e-03 -6.000000e+00 2.150246e-01 230.56 -2.00 3.49 -2.00 321.08 0.00e+00 -5.057743e-03 3.034448e-03 2.572640e-03 -6.000000e+00 1.028430e-02 283.36 -2.00 20.00 -2.00 320.49 0.00e+00 4.229 0.001 302.00 328.00 3 3.5267e+00 2.2489e-02 5.4109e-02 -6.0000e+00 5.3762e-01 4.9328e-02 3.0470e-02 3.5101e-02 -6.0000e+00 5.8243e-01 -6.6355e-02 3.0000e-02 1.9731e-02 -6.0000e+00 3.4593e-01 2.6499e-02 1.4428e-02 6.7352e-03 -6.0000e+00 1.5083e-01 1.1626e-04 -5.4954e-04 3.5578e-04 8.6864e-05 -6.0000e+00 9.8212e-03 3.3257e-03 1.5788e-04 12 8 8 10 0 0 99.95 21.52 0.39 0.00333 -0.00080 22 4 1 5 0 2311.462 27.15 19.99 21.52 23.37 31.1 1058.19 900000 -93119 900000 -185682 900000 -96135 -13860 -124693 -39634 -85191 900000 -90252 -70887 -101865 -67456 80881 -26144 -17691 177380 62460 113539 -8690 95389 -51756 -13039 68939 -22511 2698 58409 -13029 10509 -23305 20277 17264 -17062 -10820 17824 3957 -21317 11534 8971 -1672 -3818 -2846 1124 7151 13949 9162 14915 24524 8518 10109 9107 1743 -4114 4282 4424 -3467 8021 8079 3378 4957 -716 -1144 890 -283 -1100 621 -1552 517 1149 2098 4930 -5192 -2016 -1387 -260 -3731 -1232 -2598 126 -3945 1639 -13249 -503 4135 -859 4626 2667 1852 747 -676 2894 2808 -2462 -234 1174 -204 957 1339 -2146 79 -861 -1818 1539 -1188 -477 119 -144 -44 800 1478 165 -577 -1313 -1218 -210 -1283 733 182 616 -192 406 273 -297 -856 254 1014 225 -1030 18 115 -345 60 221 342 1254 -17 718 -1016 -684 -519 900000 -1126 900000 -3657 900000 -1162 -168 -1787 -479 -1080 900000 -1406 -1115 -2637 -1522 978 -506 -346 2144 755 1373 -184 1153 -2047 -398 1041 -805 72 887 -414 312 -1113 732 664 -858 -523 753 234 -1996 939 834 -183 -440 -325 124 755 1397 984 1581 2558 1164 1510 1504 335 -890 902 959 -801 1605 1589 729 1173 -202 -356 274 -84 -328 192 -561 210 501 933 2067 -2259 -769 -473 -84 -1296 -482 -1212 66 -2402 1016 -10020 -362 3021 -690 3576 2062 1366 518 -447 1803 1875 -1969 -210 1182 -232 1123 1507 -2283 74 -787 -1797 1584 -1309 -552 147 -197 -67 1287 2412 265 -884 -1912 -1741 -307 -2002 1190 302 988 -298 612 398 -417 -1156 336 1469 369 -1875 34 228 -724 134 524 828 3060 -42 1737 -2371 -1506 -1091 SS 20240507T113130.9Z 8893.480219 89 1 38.17 2 72.47 82.22 66.59 88.80 0.00 1 0.00 1 0 17 1.744e-01 8.074e-03 1.579e-01 4.752e-03 4.687336e-01 2.449326e-03 5.468622e-03 -6.000000e+00 9.909914e-02 230.56 -2.00 3.49 -2.00 320.12 0.00e+00 2.111918e-03 8.161920e-04 1.242887e-03 -6.000000e+00 4.325940e-03 283.36 -2.00 20.00 -2.00 319.47 0.00e+00 3.273 0.001 302.00 328.00 3 3.3076e+00 7.2561e-03 4.1811e-02 -6.0000e+00 2.4805e-01 3.6788e-02 8.8664e-03 2.7024e-02 -6.0000e+00 2.6853e-01 -2.4056e-02 7.8021e-03 1.2349e-02 -6.0000e+00 1.5955e-01 1.0021e-02 4.0250e-03 4.9222e-03 -6.0000e+00 6.8409e-02 4.0670e-04 -5.0378e-04 1.3372e-04 3.8776e-05 -6.0000e+00 4.4330e-03 2.4323e-03 1.3425e-04 12 9 1 12 1 1 99.78 21.51 0.27 0.00243 -0.00135 19 5 1 5 0 1908.369 27.15 20.00 21.51 23.64 31.4 1060.63 -52869 100658 -57610 25207 -35660 126585 3775 -16231 2717 -10348 -44062 4970 33737 2417 -2641 13544 12092 -7501 10623 -7451 6713 -9299 19332 -12269 24994 -9622 14375 -9752 20637 -6902 10198 -619 4539 -9629 -3087 -14423 2016 -4028 192 -3233 682 2022 -2601 2013 204 695 -3932 675 -2780 -410 -229 -1077 2571 2322 1566 1565 137 2261 -3871 1459 -1978 3721 1946 2362 397 1086 -2450 1558 1420 -43 439 -84 452 -45 727 -1311 53 -3382 -1554 -3401 -746 -2339 -2092 1687 -944 -542 972 1094 1602 517 959 -520 272 -337 650 -94 810 545 216 99 -92 156 -233 805 -1261 -649 -1007 -136 140 325 -77 380 -6 266 -1657 -10 -1027 -476 -429 -213 15 290 326 500 -43 -242 636 723 402 767 -48 -61 6 -269 -8 -9 718 291 546 -204 -277 -1346 -901 466 -1218 231 -526 587 41 -248 39 -177 -1054 83 519 62 -85 427 419 -339 431 -378 303 -489 812 -758 1156 -649 769 -628 968 -447 646 -50 394 -979 -276 -1455 196 -499 28 -564 125 388 -541 407 43 146 -870 145 -630 -96 -59 -307 760 735 519 536 48 775 -1373 493 -730 1434 851 1116 189 483 -1098 691 713 -25 271 -53 279 -26 386 -641 24 -1628 -832 -2138 -519 -1817 -1713 1405 -861 -522 966 1102 1586 490 840 -430 215 -281 598 -98 936 694 285 126 -108 168 -245 896 -1522 -810 -1324 -187 207 519 -129 641 -9 409 -2447 -14 -1526 -741 -708 -357 24 465 508 748 -63 -337 868 1055 647 1320 -87 -113 11 -546 -16 -20 1581 649 1198 -432 -562 -2667 SS 20240507T113619.2Z 8893.483556 92 1 50.89 2 71.56 82.95 65.69 89.52 0.00 1 0.00 1 0 25 4.667e-02 5.532e-03 1.272e-02 6.869e-04 4.487481e-01 3.536562e-04 5.317938e-03 -6.000000e+00 2.651313e-02 230.56 -2.00 3.49 -2.00 319.89 0.00e+00 6.189076e-04 1.087612e-04 1.187011e-03 -6.000000e+00 1.158130e-03 283.37 -2.00 20.00 -2.00 319.22 0.00e+00 3.121 0.000 302.00 328.00 3 1.9846e-01 1.0311e-03 3.9783e-02 -6.0000e+00 6.6362e-02 1.1993e-03 1.2403e-03 2.5216e-02 -6.0000e+00 7.1858e-02 -1.0493e-02 1.0498e-03 1.1857e-02 -6.0000e+00 4.2694e-02 2.0214e-03 5.4536e-04 3.5886e-03 -6.0000e+00 1.8295e-02 1.1082e-02 -7.6416e-04 1.9339e-05 3.6564e-05 -6.0000e+00 1.1874e-03 2.5464e-03 -2.1231e-05 10 0 0 10 0 0 63.52 21.52 0.18 0.00255 -0.00320 675 119 1 5 0 75.384 27.15 20.00 21.52 23.98 31.5 1064.04 -9822 -15779 -9562 -19441 -17080 -25173 -14100 -16122 -4790 -10226 -13629 -12873 -7683 -4478 1008 -4 922 1477 170 2886 -865 1268 429 1885 1384 1676 -452 -858 -3834 -1649 -422 315 1269 -937 -5324 -5774 -4296 -1377 -973 346 -865 -227 -214 388 466 -91 -508 -679 -1276 -372 475 351 875 949 669 956 911 409 196 30 1220 1357 2112 1877 445 -371 -840 -1167 364 83 310 156 372 57 -219 -760 -1674 -1773 -1323 -1416 -1352 -1661 -1818 -1258 -705 149 511 798 1098 1043 932 394 7 293 151 378 930 1052 500 209 -202 -445 -241 -1 -785 -596 -653 -468 183 285 365 154 125 -342 -463 -653 -713 -496 -379 -452 -171 4 379 288 567 -174 552 512 375 279 80 -109 -123 -31 91 103 645 362 126 -166 -440 -921 -137 -263 -156 -328 -253 -401 -223 -302 -91 -216 -301 -311 -214 -148 38 0 42 73 9 156 -50 71 25 121 96 121 -33 -60 -264 -117 -34 29 129 -99 -547 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