File name: Pandora134s1_BristolPA_20240607_L2Fit_fout2c2d20210612p1-8.txt File generation date: 20240608T060907.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v2d20210612.txt Level 1 file used: Pandora134s1_BristolPA_20240607_L1_smca1c2d20210612p1-8.txt Full location name: Bristol, Pennsylvania; Philadelphia-Camden-Wilmington, PA-NJ-DE-MD; A420170012 Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20240607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0874 305.2288 305.3702 305.5115 305.6529 305.7942 305.9356 306.0769 306.2182 306.3595 306.5008 306.6420 306.7833 306.9246 307.0658 307.2070 307.3482 307.4894 307.6306 307.7718 307.9130 308.0541 308.1953 308.3364 308.4775 308.6187 308.7598 308.9008 309.0419 309.1830 309.3240 309.4651 309.6061 309.7471 309.8881 310.0291 310.1701 310.3111 310.4521 310.5930 310.7340 310.8749 311.0158 311.1567 311.2976 311.4385 311.5793 311.7202 311.8610 312.0019 312.1427 312.2835 312.4243 312.5651 312.7059 312.8466 312.9874 313.1281 313.2689 313.4096 313.5503 313.6910 313.8317 313.9724 314.1130 314.2537 314.3943 314.5349 314.6755 314.8161 314.9567 315.0973 315.2379 315.3784 315.5190 315.6595 315.8000 315.9406 316.0811 316.2215 316.3620 316.5025 316.6429 316.7834 316.9238 317.0642 317.2046 317.3450 317.4854 317.6258 317.7661 317.9065 318.0468 318.1871 318.3275 318.4678 318.6081 318.7483 318.8886 319.0289 319.1691 319.3093 319.4495 319.5898 319.7300 319.8701 320.0103 320.1505 320.2906 320.4308 320.5709 320.7110 320.8511 320.9912 321.1313 321.2713 321.4114 321.5514 321.6915 321.8315 321.9715 322.1115 322.2515 322.3915 322.5314 322.6714 322.8113 322.9513 323.0912 323.2311 323.3710 323.5109 323.6507 323.7906 323.9304 324.0703 324.2101 324.3499 324.4897 324.6295 324.7693 324.9090 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240607T114824.7Z 8924.491953 118 1 2.64 2 66.29 79.40 73.74 67.09 0.00 1 0.00 1 0 17 3.815e-02 9.503e-03 3.185e-02 6.054e-03 3.433643e-01 3.070034e-03 4.088015e-03 -6.000000e+00 2.183755e-02 232.51 -2.00 3.49 -2.00 318.03 0.00e+00 1.491983e-03 5.428408e-04 3.747593e-04 -6.000000e+00 9.593244e-04 286.49 -2.00 20.00 -2.00 317.23 0.00e+00 2.469 0.000 302.00 328.00 3 2.7159e+00 8.3011e-03 3.0807e-02 -6.0000e+00 5.4864e-02 7.6420e-03 9.3794e-03 1.8431e-02 -6.0000e+00 5.9278e-02 7.4375e-03 6.0714e-03 8.7692e-03 -6.0000e+00 3.5227e-02 -2.7585e-03 3.1583e-03 2.8297e-03 -6.0000e+00 1.5086e-02 1.9058e-03 -6.7819e-04 1.6491e-04 2.6272e-05 -6.0000e+00 9.7090e-04 -2.3617e-03 -9.4894e-05 12 9 9 12 1 1 999.00 21.56 0.14 -0.00236 -0.00746 2 10 1 5 0 879.494 27.15 20.00 21.56 29.14 32.0 1061.91 -21218 9376 5860 545 -6089 -16201 3849 -3718 9916 -7333 1852 -11335 10552 989 8768 -1983 5526 1420 12278 -660 4860 -1162 6923 -3702 5338 -1024 754 -7738 235 -3984 1157 -2971 587 -868 -6176 -5195 -4244 -1686 -552 49 -2015 -36 -2067 2000 -10 -336 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-129 -494 -724 -592 812 814 1552 -876 594 520 772 1011 385 -840 42 -143 1396 706 1278 238 427 -1166 -796 -1978 SS 20240607T115252.9Z 8924.495056 121 1 7.13 2 65.45 80.05 72.98 67.68 0.00 1 0.00 1 0 17 1.593e-02 7.090e-03 8.664e-03 1.553e-03 3.393009e-01 7.886415e-04 4.042892e-03 -6.000000e+00 9.121228e-03 232.51 -2.00 3.49 -2.00 318.17 0.00e+00 7.950077e-04 1.450010e-04 3.730260e-04 -6.000000e+00 4.004585e-04 286.49 -2.00 20.00 -2.00 317.37 0.00e+00 2.390 0.000 302.00 328.00 3 1.3594e+00 2.1426e-03 3.0069e-02 -6.0000e+00 2.2916e-02 1.3984e-02 2.4277e-03 1.8141e-02 -6.0000e+00 2.4755e-02 -1.0170e-03 1.5894e-03 8.6860e-03 -6.0000e+00 1.4712e-02 -2.7620e-03 8.2911e-04 2.5871e-03 -6.0000e+00 6.3029e-03 8.0489e-03 -3.8370e-04 4.2568e-05 2.4511e-05 -6.0000e+00 4.0511e-04 -1.8688e-03 6.3903e-05 12 9 1 12 1 1 99.93 21.55 0.16 -0.00187 -0.00475 45 58 1 5 0 154.969 27.15 20.00 21.55 29.39 32.0 1063.84 302 -1147 -208 272 -6649 -7290 -2731 190 489 -3517 -934 -4570 365 -2555 3699 581 2154 889 2354 2502 3748 133 1143 1440 1791 1401 249 -841 -1461 802 228 1141 290 -2016 -4462 -4509 -4494 -2822 -1080 -147 -1230 -862 -113 177 -192 -329 -1117 -367 -1208 -155 389 747 542 1001 729 728 917 760 408 671 1077 1281 2074 1845 737 74 -1067 -871 127 122 367 176 354 -17 -273 -1163 -1431 -1674 -1406 -1539 -1227 -1603 -1840 -1583 -441 -163 409 783 1207 1013 714 199 104 401 225 485 1075 1442 382 304 -236 -581 -412 -117 -924 -519 -816 -320 104 546 547 103 163 -305 -740 -742 -841 -375 -452 -449 -318 -12 443 279 494 -260 524 826 531 164 100 -209 56 97 209 163 682 472 237 -296 -669 -1141 16 -67 -12 15 -345 -408 -159 12 32 -253 -71 -383 31 -265 422 76 292 129 353 392 589 21 189 256 337 275 49 -156 -258 141 45 247 70 -501 -1048 -1064 -1193 -884 -405 -58 -531 -387 -52 81 -89 -153 -516 -167 -550 -72 195 404 312 607 456 469 599 490 258 424 712 855 1510 1432 563 52 -720 -593 96 105 316 155 305 -15 -221 -843 -1038 -1212 -1042 -1314 -1093 -1576 -1912 -1731 -480 -189 493 957 1448 1149 797 203 99 393 244 551 1361 1881 519 395 -300 -677 -470 -144 -1157 -677 -1119 -458 149 845 887 165 249 -457 -1033 -1005 -1175 -555 -678 -700 -492 -18 679 407 687 -344 715 1122 792 247 157 -336 93 161 370 297 1265 890 442 -531 -1151 -1899 SS 20240607T120105.3Z 8924.500756 126 1 50.81 2 63.90 81.25 71.57 68.76 0.00 1 0.00 1 0 25 1.394e-02 6.387e-03 1.983e-03 3.098e-04 3.201379e-01 1.564958e-04 3.824418e-03 -6.000000e+00 7.980875e-03 232.51 -2.00 3.49 -2.00 318.58 0.00e+00 5.652509e-04 3.182482e-05 5.361449e-04 -6.000000e+00 3.504856e-04 286.49 -2.00 20.00 -2.00 317.77 0.00e+00 2.260 0.000 302.00 328.00 3 -1.5713e-01 4.2927e-04 2.8450e-02 -6.0000e+00 2.0051e-02 -1.5849e-03 4.8953e-04 1.7298e-02 -6.0000e+00 2.1662e-02 6.1325e-04 3.3055e-04 8.2341e-03 -6.0000e+00 1.2874e-02 -3.2331e-03 1.7342e-04 2.4268e-03 -6.0000e+00 5.5140e-03 4.3233e-02 -6.3814e-04 8.6963e-06 2.2849e-05 -6.0000e+00 3.5465e-04 -1.9251e-03 -1.7893e-05 10 0 0 10 0 0 22.44 21.55 0.18 -0.00193 -0.00672 1522 269 1 5 0 33.381 27.15 20.00 21.55 30.73 32.2 1073.42 718 -155 462 -4246 -4972 -5867 -2267 -759 991 -1561 -2428 -3294 -134 -179 2129 1998 2356 1710 2212 2307 1510 988 1527 1681 1103 1395 302 -605 -1713 -572 -399 712 785 -1732 -4205 -4172 -3909 -2041 -1032 -495 -716 -411 -458 -109 6 -333 -834 -795 -1371 -312 339 345 661 652 384 990 771 559 351 413 1099 1488 2099 1917 376 -244 -959 -963 231 -87 272 47 224 218 -149 -721 -1379 -1808 -1147 -1316 -1203 -1627 -1855 -1220 -590 -4 414 757 1091 891 858 286 154 350 321 528 1100 1234 601 324 -174 -501 -366 -14 -847 -629 -694 -542 140 306 331 151 121 -393 -679 -813 -836 -531 -406 -420 -286 -50 347 327 566 -121 594 685 483 377 186 -19 -42 76 185 96 608 389 135 -256 -500 -965 32 -8 23 -224 -234 -272 -110 -42 60 -101 -157 -226 -10 -16 221 229 282 217 293 319 214 139 221 262 184 241 52 -98 -264 -89 -68 133 161 -366 -837 -835 -878 -540 -329 -181 -284 -169 -194 -46 3 -142 -352 -330 -568 -132 154 169 343 357 217 572 453 324 200 235 653 964 1347 1308 253 -166 -620 -628 168 -66 219 39 181 167 -115 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