File name: Pandora134s1_BristolPA_20240726_L2Fit_fout2c5d20230501p1-8.txt File generation date: 20240825T115226.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v5d20230501.txt Level 1 file used: Pandora134s1_BristolPA_20240726_L1_smca1c5d20230501p1-8.txt Full location name: Bristol, Pennsylvania; Philadelphia-Camden-Wilmington, PA-NJ-DE-MD; A420170012 Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20240726 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 3 for VP from 20230501 First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0892 305.2306 305.3720 305.5133 305.6546 305.7959 305.9373 306.0785 306.2198 306.3611 306.5024 306.6436 306.7849 306.9261 307.0673 307.2085 307.3497 307.4909 307.6320 307.7732 307.9144 308.0555 308.1966 308.3377 308.4788 308.6199 308.7610 308.9021 309.0431 309.1842 309.3252 309.4662 309.6073 309.7483 309.8893 310.0302 310.1712 310.3122 310.4531 310.5940 310.7350 310.8759 311.0168 311.1577 311.2985 311.4394 311.5803 311.7211 311.8619 312.0027 312.1436 312.2844 312.4251 312.5659 312.7067 312.8474 312.9882 313.1289 313.2696 313.4103 313.5510 313.6917 313.8324 313.9730 314.1137 314.2543 314.3950 314.5356 314.6762 314.8168 314.9574 315.0979 315.2385 315.3790 315.5196 315.6601 315.8006 315.9411 316.0816 316.2221 316.3625 316.5030 316.6435 316.7839 316.9243 317.0647 317.2051 317.3455 317.4859 317.6262 317.7666 317.9069 318.0473 318.1876 318.3279 318.4682 318.6085 318.7488 318.8890 319.0293 319.1695 319.3097 319.4500 319.5902 319.7304 319.8705 320.0107 320.1509 320.2910 320.4312 320.5713 320.7114 320.8515 320.9916 321.1317 321.2717 321.4118 321.5518 321.6919 321.8319 321.9719 322.1119 322.2519 322.3919 322.5318 322.6718 322.8117 322.9516 323.0916 323.2315 323.3714 323.5112 323.6511 323.7910 323.9308 324.0707 324.2105 324.3503 324.4901 324.6299 324.7697 324.9094 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240726T104636.6Z 8973.449035 206 1 49.88 2 81.31 72.09 40.37 213.18 0.00 1 0.00 1 0 25 5.457e-01 2.971e-02 4.413e-01 2.319e-02 8.042149e-01 1.396416e-02 8.931569e-03 -6.000000e+00 3.286524e-01 232.44 -2.00 3.49 -2.00 321.99 0.00e+00 -6.193958e-03 8.114494e-03 1.442058e-03 -6.000000e+00 1.661740e-02 290.34 -2.00 20.00 -2.00 321.46 0.00e+00 6.238 0.004 302.00 328.00 3 2.7688e+00 5.6529e-02 7.7155e-02 -6.0000e+00 8.3418e-01 6.3712e-01 7.9155e-02 4.7912e-02 -6.0000e+00 9.1139e-01 -1.0204e+00 6.7794e-02 2.3272e-02 -6.0000e+00 5.2793e-01 4.5082e-01 3.0658e-02 8.0857e-03 -6.0000e+00 2.2399e-01 2.8723e-05 -8.5665e-04 6.7312e-04 8.7507e-05 -6.0000e+00 1.5238e-02 -4.4224e-03 0.0000e+00 12 8 8 10 0 0 -38.57 21.68 0.91 -0.00442 -0.01086 16 3 1 5 0 3117.034 27.35 20.00 21.68 25.22 32.0 985.86 900000 29772 900000 -108622 36262 -162481 900000 900000 900000 -55589 900000 -188224 -113932 900000 900000 900000 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3180 3398 540 3920 684 4426 333 4657 5060 748 2031 4130 1280 5374 2574 1741 197 -579 1329 -100 -2154 561 -173 861 -1173 4852 3015 664 316 531 1841 -776 -1058 -2771 11339 4137 17 -1161 3834 -6490 3129 -1098 -1501 -950 1241 -5163 2951 -3616 378 -2420 -875 -5175 -2668 1305 -1483 -583 -526 -351 -2418 -4000 -1162 151 605 2985 -1744 3666 -2784 -1502 1697 -88 1635 5015 -1351 4347 -2339 -572 1696 4554 -1632 4620 -958 2685 -3118 2380 -74 -1017 -792 -1020 544 1844 1937 -3633 -2818 SS 20240726T105948.0Z 8973.458194 211 1 51.32 2 78.90 74.09 41.75 217.61 0.00 1 0.00 1 0 17 4.887e-01 2.401e-02 3.474e-01 1.394e-02 6.739989e-01 7.907186e-03 7.635488e-03 -6.000000e+00 2.835553e-01 232.44 -2.00 3.49 -2.00 321.45 0.00e+00 4.806370e-03 4.024276e-03 9.013031e-04 -6.000000e+00 1.489845e-02 290.34 -2.00 20.00 -2.00 320.83 0.00e+00 5.005 0.002 302.00 328.00 3 3.3461e+00 2.8716e-02 6.2646e-02 -6.0000e+00 7.1070e-01 3.3851e-01 3.8484e-02 3.9560e-02 -6.0000e+00 7.6829e-01 -4.2777e-01 3.4177e-02 1.8762e-02 -6.0000e+00 4.5590e-01 1.7497e-01 1.6201e-02 9.3392e-03 -6.0000e+00 1.9716e-01 5.6670e-05 -1.4158e-03 3.9843e-04 8.7380e-05 -6.0000e+00 1.3164e-02 -5.3194e-03 0.0000e+00 12 8 8 10 0 0 99.84 21.66 0.40 -0.00532 -0.01596 21 4 1 5 0 2443.455 27.35 19.98 21.66 25.77 32.0 989.48 -243064 -32689 -5224 900000 -173971 900000 -139341 -40904 -207126 900000 900000 -122779 -89128 190431 900000 24738 -23015 -16811 97089 7004 900000 -51896 900000 14790 115633 -56335 900000 -47929 93945 -62639 133747 -9702 90634 -4110 25702 -15406 17220 -23233 19460 57906 25621 15154 8938 22347 48708 7946 -21474 1267 971 38938 16852 27646 16571 34377 -3526 23847 12162 27161 2171 25800 22505 11096 5793 12152 -71 14952 546 12548 10885 1909 2880 4738 6668 105 2630 -3322 1945 -12091 -938 -1063 6902 -3949 -3316 -8180 518 -1474 2720 -4184 5304 -3683 4447 -5489 -1145 -5330 -1412 -1405 481 -827 -505 -563 -960 675 784 -498 -2660 -698 -3198 56 -1779 1371 279 -428 -50 509 -1191 739 -1630 303 -2785 2851 112 3302 745 102 -154 2389 2505 1932 583 208 343 -61 50 -305 554 -317 968 -3 727 -1703 197 -2219 -10287 -444 -71 900000 -3859 900000 -2290 -555 -7959 900000 900000 -2569 -1716 2584 900000 336 -484 -365 1317 134 900000 -1713 900000 289 1569 -2367 900000 -1780 1275 -2913 1815 -391 1606 -185 816 -721 656 -1554 1050 2531 1667 1154 751 1675 2880 710 -2590 127 102 3074 1829 3008 2183 4096 -631 3409 1976 3745 367 3461 3271 2013 1262 2768 -19 3273 136 2930 2945 644 1036 1708 2284 36 789 -952 508 -3815 -309 -417 2894 -2076 -1862 -5079 317 -977 1807 -3023 3440 -2471 2570 -3289 -647 -3370 -990 -1145 444 -872 -559 -606 -946 587 646 -440 -2588 -699 -3472 63 -2289 1916 429 -682 -77 754 -1695 1016 -2374 459 -4595 4526 177 4851 1092 145 -212 3071 3213 2744 952 379 670 -124 107 -704 1350 -799 2446 -9 1814 -4119 440 -4817 SS 20240726T110512.5Z 8973.461951 214 1 15.29 2 77.90 74.90 42.35 219.36 0.00 1 0.00 1 0 25 4.895e-01 1.345e-02 3.346e-01 1.123e-02 6.319574e-01 6.171574e-03 7.162727e-03 -6.000000e+00 2.822011e-01 232.44 -2.00 3.49 -2.00 321.07 0.00e+00 2.820823e-03 2.880313e-03 1.054705e-03 -6.000000e+00 1.429772e-02 290.34 -2.00 20.00 -2.00 320.41 0.00e+00 4.625 0.002 302.00 328.00 3 3.1539e+00 2.1115e-02 5.7972e-02 -6.0000e+00 7.0775e-01 1.1537e-01 2.8383e-02 3.6091e-02 -6.0000e+00 7.6487e-01 -1.6560e-01 2.6881e-02 1.7366e-02 -6.0000e+00 4.5503e-01 7.2337e-02 1.3002e-02 7.5683e-03 -6.0000e+00 1.9734e-01 1.0896e-04 -6.5206e-04 3.1362e-04 6.3189e-05 -6.0000e+00 1.2846e-02 -5.9966e-03 0.0000e+00 12 9 9 12 1 1 -13.10 21.64 0.21 -0.00600 -0.01090 6 4 1 5 0 2182.889 27.26 20.00 21.64 25.85 31.9 989.65 -158247 -193569 900000 -48350 900000 -156136 -163757 -128320 -6713 -14680 900000 900000 -96603 -33858 -122372 4379 -54772 -28473 -58497 900000 -19663 286426 -16628 181062 6666 121210 -4942 91249 -8749 -1030 33139 -338 5682 -11106 38001 53501 -5576 545 14642 7189 -6728 1283 6069 -4550 -7055 3463 2574 8115 5141 2791 -488 -635 24163 -2818 13633 8036 5735 -3288 -1019 700 3272 2638 3635 4424 5085 -3902 3886 -1838 5355 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