File name: Pandora134s1_BristolPA_20250406_L2Fit_fwvt1c5d20230501p1-8.txt File generation date: 20250407T051529.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v5d20230501.txt Level 1 file used: Pandora134s1_BristolPA_20250406_L1_smca1c5d20230501p1-8.txt Full location name: Bristol, Pennsylvania; Philadelphia-Camden-Wilmington, PA-NJ-DE-MD; A420170012 Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20250406 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 3 for VP from 20230501 First and last pixel inside fitting window: 1648 1797 Nominal wavelengths inside fitting window [nm]: 492.0138 492.1355 492.2572 492.3789 492.5006 492.6223 492.7439 492.8656 492.9872 493.1088 493.2304 493.3519 493.4735 493.5950 493.7165 493.8380 493.9595 494.0810 494.2024 494.3239 494.4453 494.5667 494.6881 494.8094 494.9308 495.0521 495.1734 495.2947 495.4160 495.5373 495.6585 495.7798 495.9010 496.0222 496.1434 496.2646 496.3857 496.5068 496.6280 496.7491 496.8701 496.9912 497.1123 497.2333 497.3543 497.4753 497.5963 497.7173 497.8382 497.9592 498.0801 498.2010 498.3219 498.4427 498.5636 498.6844 498.8052 498.9260 499.0468 499.1676 499.2883 499.4091 499.5298 499.6505 499.7712 499.8919 500.0125 500.1331 500.2538 500.3744 500.4949 500.6155 500.7361 500.8566 500.9771 501.0976 501.2181 501.3386 501.4590 501.5794 501.6999 501.8203 501.9406 502.0610 502.1813 502.3017 502.4220 502.5423 502.6626 502.7828 502.9031 503.0233 503.1435 503.2637 503.3839 503.5041 503.6242 503.7443 503.8644 503.9845 504.1046 504.2247 504.3447 504.4648 504.5848 504.7048 504.8247 504.9447 505.0646 505.1846 505.3045 505.4244 505.5442 505.6641 505.7839 505.9038 506.0236 506.1433 506.2631 506.3829 506.5026 506.6223 506.7420 506.8617 506.9814 507.1010 507.2207 507.3403 507.4599 507.5795 507.6991 507.8186 507.9381 508.0577 508.1772 508.2966 508.4161 508.5355 508.6550 508.7744 508.8938 509.0132 509.1325 509.2519 509.3712 509.4905 509.6098 509.7291 509.8483 509.9676 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250406T155942.8Z 9227.666468 331 1 48.67 2 36.18 153.22 102.41 46.66 0.00 1 0.00 1 0 15 2.867e-03 2.854e-03 1.036e-03 1.032e-03 3.109802e+03 6.300842e+01 2.402983e+02 -6.000000e+00 1.588802e+02 279.94 -2.00 20.00 -2.00 505.22 0.00e+00 6.440354e-04 2.838679e-05 3.759280e-05 -6.000000e+00 8.021414e-05 279.94 -2.00 20.00 -2.00 500.29 0.00e+00 5.562989e-02 2.060542e-02 1.966965e-02 -6.000000e+00 5.700331e-02 227.99 -2.00 3.49 -2.00 501.90 0.00e+00 1.238 0.000 489.00 513.00 1 7.6119e+00 1.5846e-03 2.6204e-03 -6.0000e+00 4.3710e-03 7.8542e-03 4.0518e-04 5.1394e-04 -6.0000e+00 1.1256e-03 7.9783e-04 6.5924e-04 1.0280e-04 3.3682e-05 -6.0000e+00 2.9633e-04 4.4918e-03 -3.5520e-05 12 1 1 12 1 1 99.89 21.36 0.38 0.00449 0.00906 14 3 1 4 0 3244.595 27.05 20.00 21.36 18.83 32.6 1049.61 -340 63 -393 134 172 219 334 624 221 194 195 89 -199 2 -370 -62 -378 -226 -236 -409 -324 73 92 217 132 74 135 -111 207 19 392 48 -158 -195 -33 -249 -91 -119 223 -8 -6 -40 245 118 149 371 296 454 29 263 -343 17 -567 -455 -330 -249 -32 -182 148 305 368 577 166 252 94 180 -379 -130 -216 -347 -165 -51 -223 -342 -385 -470 29 -434 -392 -342 -319 -170 -390 117 -26 -39 135 155 272 340 679 635 580 556 154 -117 -102 -132 -21 -321 -256 -137 -382 -513 -655 -566 -31 118 47 70 -34 51 171 514 466 414 258 55 -112 -67 -167 -33 235 76 -5 72 134 -174 -44 -127 -197 -241 -95 -35 15 59 12 183 522 430 321 401 492 -86 39 -197 -490 -405 -251 -257 -321 59 -384 135 178 232 359 677 242 210 207 94 -207 2 -376 -63 -389 -238 -254 -448 -356 80 101 238 136 76 139 -121 219 20 394 49 -162 -207 -33 -257 -94 -121 238 -8 -6 -43 263 120 153 379 301 456 31 271 -346 16 -553 -446 -331 -257 -34 -181 147 302 364 572 166 251 92 188 -392 -132 -217 -344 -162 -50 -223 -346 -392 -476 29 -426 -381 -331 -310 -166 -385 117 -27 -39 137 157 275 345 647 613 566 542 149 -111 -101 -128 -20 -301 -240 -131 -379 -491 -640 -553 -29 111 44 67 -33 49 169 510 465 415 260 55 -112 -66 -161 -31 224 72 -5 69 128 -167 -42 -120 -186 -223 -87 -32 14 54 11 175 505 421 316 396 488 -85 39 -193 -471 -381 -233 -240 SQ 20250406T193215.4Z 9227.814068 471 1 8.48 2 47.34 235.50 67.97 79.71 0.00 1 0.00 1 0 15 3.343e-03 3.336e-03 2.215e-03 2.212e-03 2.738864e+03 1.336183e+02 2.198822e+02 -6.000000e+00 1.853127e+02 279.96 -2.00 20.00 -2.00 505.26 0.00e+00 7.154949e-04 6.061742e-05 4.017742e-05 -6.000000e+00 9.355054e-05 279.96 -2.00 20.00 -2.00 500.42 0.00e+00 7.261116e-02 4.385790e-02 1.651756e-02 -6.000000e+00 6.645594e-02 228.00 -2.00 3.49 -2.00 502.02 0.00e+00 1.473 0.000 489.00 513.00 1 7.3396e+00 3.3617e-03 2.7353e-03 -6.0000e+00 5.0962e-03 1.2893e-02 8.6152e-04 4.5014e-04 -6.0000e+00 1.3117e-03 1.0114e-03 2.3344e-04 2.2173e-04 3.2214e-05 -6.0000e+00 3.4562e-04 4.5268e-04 2.1110e-05 12 1 1 12 1 1 999.00 21.46 0.29 0.00045 0.00207 2 3 1 4 0 2825.255 27.15 19.99 21.46 16.39 32.8 1033.88 -421 -365 -124 -160 228 50 606 420 -48 299 324 203 140 -195 -236 127 -221 -348 -382 -178 -246 -21 -39 648 -77 56 136 -68 158 -61 25 437 -248 -461 152 -388 321 238 -72 -285 -133 -50 385 470 194 490 87 -193 58 -113 -553 17 -66 -371 -229 -81 270 -414 507 290 627 -159 -153 -79 14 244 -44 -362 141 -569 -378 -18 -426 -547 -134 190 301 -299 -597 -184 -492 -98 -191 100 69 23 -188 833 -132 509 642 817 506 135 157 -21 -12 127 18 -349 38 -329 -823 -347 -980 -426 -12 -52 292 -108 141 171 262 177 724 320 33 -171 -245 -78 103 -279 172 28 -133 30 -73 -139 -95 -138 90 -158 -103 241 -62 108 298 184 510 365 502 670 489 71 -558 -150 -618 -21 -757 -205 -412 -358 -123 -162 234 52 634 441 -51 313 337 209 143 -198 -238 128 -225 -358 -399 -187 -259 -22 -41 680 -81 59 143 -71 162 -62 25 436 -251 -475 159 -408 335 247 -74 -293 -137 -52 397 487 202 511 90 -200 59 -114 -551 17 -64 -363 -227 -82 274 -424 517 296 638 -163 -156 -81 14 246 -44 -360 139 -558 -369 -17 -419 -542 -132 187 294 -289 -576 -177 -475 -94 -185 97 67 23 -185 818 -130 501 633 811 507 135 156 -20 -12 122 17 -328 36 -313 -799 -342 -979 -424 -12 -50 284 -106 140 170 261 177 726 322 34 -172 -246 -78 101 -273 168 27 -131 29 -72 -137 -93 -135 87 -151 -98 228 -59 104 288 179 500 360 496 662 485 70 -556 -148 -603 -20 -724 -195 SQ 20250406T193646.3Z 9227.817202 474 1 50.75 2 48.06 236.67 67.16 80.36 0.00 1 0.00 1 0 15 3.011e-03 2.999e-03 1.316e-03 1.311e-03 2.617958e+03 8.019970e+01 1.977253e+02 -6.000000e+00 1.668785e+02 279.96 -2.00 20.00 -2.00 505.26 0.00e+00 6.505883e-04 3.588174e-05 3.703128e-05 -6.000000e+00 8.425326e-05 279.96 -2.00 20.00 -2.00 500.30 0.00e+00 6.179532e-02 2.618287e-02 1.806477e-02 -6.000000e+00 5.987775e-02 228.00 -2.00 3.49 -2.00 501.92 0.00e+00 1.494 0.000 489.00 513.00 1 7.5885e+00 2.0065e-03 2.7841e-03 -6.0000e+00 4.5913e-03 1.2592e-02 5.1465e-04 4.5816e-04 -6.0000e+00 1.1825e-03 7.8782e-04 9.8085e-04 1.3147e-04 2.7488e-05 -6.0000e+00 3.1122e-04 5.6198e-03 -5.2345e-05 10 0 0 10 0 0 99.99 21.46 0.27 0.00562 0.01242 70 12 1 4 0 724.961 27.15 20.00 21.46 17.22 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