File name: Pandora180s1_BronxNY_20230828_L2Fit_fout2c2d20210302p1-8.txt File generation date: 20230830T055658.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 180 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora180_OF_v3d20201002.txt Instrument calibration file used: Pandora180s1_CF_v2d20210302.txt Level 1 file used: Pandora180s1_BronxNY_20230828_L1_smca1c2d20210302p1-8.txt Full location name: New York State DEC Bronx-Pfizer PAMS station (36-005-0133) Short location name: BronxNY Country of location: USA Location latitude [deg]: 40.8679 Location longitude [deg]: -73.8781 Location altitude [m]: 31 Local noon date: 20230828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 364 Nominal wavelengths inside fitting window [nm]: 305.0771 305.2181 305.3590 305.5000 305.6409 305.7819 305.9228 306.0637 306.2046 306.3455 306.4864 306.6273 306.7681 306.9090 307.0498 307.1906 307.3315 307.4723 307.6131 307.7539 307.8946 308.0354 308.1762 308.3169 308.4577 308.5984 308.7391 308.8798 309.0205 309.1612 309.3019 309.4425 309.5832 309.7238 309.8644 310.0051 310.1457 310.2863 310.4269 310.5674 310.7080 310.8486 310.9891 311.1297 311.2702 311.4107 311.5512 311.6917 311.8322 311.9726 312.1131 312.2536 312.3940 312.5344 312.6749 312.8153 312.9557 313.0961 313.2364 313.3768 313.5172 313.6575 313.7978 313.9382 314.0785 314.2188 314.3591 314.4994 314.6396 314.7799 314.9201 315.0604 315.2006 315.3408 315.4810 315.6212 315.7614 315.9016 316.0418 316.1819 316.3221 316.4622 316.6023 316.7424 316.8825 317.0226 317.1627 317.3028 317.4428 317.5829 317.7229 317.8629 318.0029 318.1430 318.2829 318.4229 318.5629 318.7029 318.8428 318.9828 319.1227 319.2626 319.4025 319.5424 319.6823 319.8222 319.9620 320.1019 320.2417 320.3816 320.5214 320.6612 320.8010 320.9408 321.0806 321.2203 321.3601 321.4998 321.6396 321.7793 321.9190 322.0587 322.1984 322.3381 322.4778 322.6174 322.7571 322.8967 323.0363 323.1760 323.3156 323.4552 323.5947 323.7343 323.8739 324.0134 324.1530 324.2925 324.4320 324.5715 324.7110 324.8505 324.9900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230828T130820.6Z 8640.547460 197 1 47.77 2 59.03 105.07 155.94 302.40 0.00 1 0.00 1 0 17 1.374e-02 6.217e-03 5.895e-03 1.634e-03 2.436592e-01 8.450330e-04 2.866841e-03 -6.000000e+00 8.072319e-03 230.74 -2.00 3.51 -2.00 317.74 0.00e+00 7.152907e-04 1.368061e-04 2.959925e-04 -6.000000e+00 3.618089e-04 289.22 -2.00 20.00 -2.00 316.86 0.00e+00 1.935 0.000 302.00 328.00 3 4.2193e+00 2.2652e-03 2.3099e-02 -6.0000e+00 2.0149e-02 1.5697e-02 2.5577e-03 1.2630e-02 -6.0000e+00 2.1773e-02 8.4925e-03 1.5593e-03 6.1493e-03 -6.0000e+00 1.2987e-02 -1.0101e-02 7.7302e-04 1.7437e-03 -6.0000e+00 5.5418e-03 8.5006e-04 1.0242e-03 4.9584e-05 1.8969e-05 -6.0000e+00 3.8760e-04 6.9911e-02 5.8032e-05 10 0 0 10 0 0 99.99 24.27 0.20 0.06991 0.07761 85 21 1 5 0 561.960 28.21 20.01 24.27 30.87 35.9 1017.14 -1847 -814 211 -8097 -226 -5800 -545 -117 -3706 -4195 -2754 -2814 -2004 114 -53 1719 231 1032 290 305 526 239 637 -156 1474 215 -1405 -1086 -665 650 1394 1426 -1110 -2122 -3747 -3270 -1922 -109 529 -466 -526 -351 218 -719 187 -162 43 -848 -577 652 145 1083 794 814 432 987 221 339 708 391 1170 1955 2217 882 206 -539 -1171 450 581 850 425 535 550 209 -517 -1141 -1550 -1157 -812 -1395 -1072 -2029 -1616 -792 -341 170 394 668 873 262 98 -539 -593 -429 -110 159 978 136 -36 -639 -929 -871 -408 -869 -831 -800 -613 24 479 820 818 517 105 31 -110 -194 205 48 266 -2 173 428 362 478 184 170 301 255 5 170 -412 -468 45 -100 31 336 446 -47 -55 -144 -432 -650 900000 -172 -78 19 -728 -19 -530 -52 -12 -440 -503 -326 -363 -292 19 -10 326 46 212 62 67 115 53 147 -38 371 55 -352 -252 -148 148 339 374 -313 -581 -996 -913 -607 -40 229 -227 -271 -186 117 -390 101 -86 22 -432 -291 337 80 631 489 520 283 655 148 223 460 260 821 1475 1786 732 162 -392 -821 321 463 747 396 505 505 182 -410 -818 -1043 -786 -608 -1182 -1002 -2064 -1720 -809 -373 196 471 804 1021 288 109 -547 -572 -427 -119 190 1170 176 -47 -790 -1171 -1032 -486 -1121 -1038 -1046 -838 35 721 1296 1319 814 155 42 -154 -267 290 66 392 -2 262 634 516 710 261 229 401 359 8 246 -617 -714 71 -167 54 605 822 -88 -100 -256 -744 -1094 900000 SS 20230828T131336.2Z 8640.551114 200 1 44.43 2 58.07 106.10 156.71 304.42 0.00 1 0.00 1 0 17 1.167e-02 6.281e-03 9.375e-04 3.039e-04 2.385287e-01 1.568493e-04 2.852132e-03 -6.000000e+00 6.855094e-03 230.74 -2.00 3.51 -2.00 317.47 0.00e+00 5.289160e-04 2.356469e-05 2.604229e-04 -6.000000e+00 3.073940e-04 289.22 -2.00 20.00 -2.00 316.60 0.00e+00 1.884 0.000 302.00 328.00 3 1.2699e+00 4.1751e-04 2.2565e-02 -6.0000e+00 1.7110e-02 2.3477e-03 4.6936e-04 1.2443e-02 -6.0000e+00 1.8491e-02 2.9058e-03 2.8021e-04 6.0270e-03 -6.0000e+00 1.1029e-02 -8.0198e-03 1.3753e-04 1.6601e-03 -6.0000e+00 4.7051e-03 1.7377e-02 6.6464e-04 9.1675e-06 1.9644e-05 -6.0000e+00 3.2929e-04 7.0960e-02 1.3876e-05 11 1 0 11 8 0 99.30 24.27 0.22 0.07096 0.07595 1037 254 1 5 0 42.840 28.21 20.00 24.27 31.19 35.9 1019.91 -745 -398 -3092 -4875 -4153 -3398 -1048 -591 -1358 -3027 -2984 -2072 -1099 3 -17 259 212 646 776 922 229 785 630 423 641 209 -612 -1430 -660 65 881 1292 -472 -2719 -3387 -2973 -1891 -447 -30 -423 -399 -275 -275 54 141 -242 -303 -772 -406 507 685 1082 1266 913 938 951 491 429 368 812 1501 2072 2123 1037 183 -419 -804 249 903 773 685 467 426 114 -573 -1078 -1667 -1338 -1210 -1222 -1366 -1935 -1639 -1017 -613 -110 446 593 548 351 45 -485 -445 -147 -178 317 712 317 -83 -421 -1022 -984 -355 -764 -797 -774 -562 -93 551 662 594 473 220 -126 -86 -27 190 255 281 26 305 328 458 526 321 128 564 383 225 86 -220 -344 -96 -66 -36 152 346 41 0 -200 -512 -674 900000 -88 -49 -378 -543 -425 -353 -117 -74 -183 -417 -411 -307 -184 0 -3 57 48 153 190 231 58 198 166 118 186 62 -174 -381 -168 17 244 384 -150 -847 -1014 -936 -674 -187 -15 -212 -211 -150 -152 30 77 -132 -161 -442 -229 294 386 643 791 594 622 643 335 288 245 549 1069 1591 1741 873 146 -309 -570 180 727 690 648 448 398 101 -461 -786 -1255 -1017 -923 -1048 -1299 -1993 -1770 -1064 -687 -130 544 731 658 394 50 -499 -435 -148 -195 384 872 418 -110 -531 -1199 -1185 -430 -917 -1020 -1037 -787 -136 848 991 908 762 332 -176 -112 -34 250 358 423 40 475 498 670 729 425 176 764 503 316 127 -337 -539 -155 -113 -61 260 604 72 0 -339 -839 -1171 900000 SS 20230828T131852.3Z 8640.554772 203 1 43.57 2 57.12 107.14 157.47 306.55 0.00 1 0.00 1 0 17 1.137e-02 6.162e-03 1.023e-03 3.312e-04 2.330959e-01 1.707337e-04 2.781408e-03 -6.000000e+00 6.683425e-03 230.74 -2.00 3.51 -2.00 317.50 0.00e+00 4.441723e-04 2.586320e-05 2.632663e-04 -6.000000e+00 2.996013e-04 289.22 -2.00 20.00 -2.00 316.64 0.00e+00 1.835 0.000 302.00 328.00 3 1.3501e+00 4.5360e-04 2.1999e-02 -6.0000e+00 1.6682e-02 4.8471e-03 5.1003e-04 1.2150e-02 -6.0000e+00 1.8027e-02 3.6683e-03 3.0511e-04 5.8850e-03 -6.0000e+00 1.0752e-02 -8.2592e-03 1.5048e-04 1.6165e-03 -6.0000e+00 4.5879e-03 1.6944e-02 8.8488e-04 1.0030e-05 1.8758e-05 -6.0000e+00 3.2096e-04 7.0487e-02 5.2316e-05 10 0 0 10 0 0 99.92 24.26 0.22 0.07049 0.07714 1295 318 1 5 0 33.590 28.21 19.99 24.26 31.78 35.9 1024.70 -497 -712 -2566 -4496 -4102 -2736 -1452 -101 -1212 -2979 -2951 -2447 -994 269 123 -87 312 556 948 982 137 865 593 796 746 94 -1015 -1225 -567 180 1166 1302 -440 -2861 -3207 -3073 -1855 -438 -90 -403 -459 -160 -284 16 19 -242 -359 -731 -428 474 690 951 1223 881 963 974 534 431 356 791 1465 2056 2087 1112 81 -410 -773 283 950 727 690 479 533 74 -471 -1025 -1587 -1329 -1219 -1099 -1430 -1933 -1679 -1009 -575 -84 431 616 585 304 67 -529 -450 -201 -148 298 700 313 -110 -410 -1057 -932 -376 -722 -797 -789 -506 -103 580 655 653 483 200 -114 -106 -50 145 250 262 61 350 334 418 491 266 114 533 329 191 37 -226 -356 -88 -70 -8 166 336 48 -7 -178 -525 -671 900000 -59 -89 -314 -503 -422 -284 -164 -13 -164 -412 -407 -364 -165 50 26 -19 71 130 229 244 34 216 155 219 214 27 -286 -321 -142 46 316 379 -137 -874 -938 -947 -647 -179 -43 -216 -237 -85 -153 9 11 -141 -204 -406 -235 267 414 603 740 554 618 637 352 280 252 516 1009 1525 1652 902 62 -291 -580 217 734 623 626 441 478 63 -364 -788 -1144 -967 -978 -900 -1300 -1902 -1731 -1100 -671 -103 549 790 732 356 72 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