File name: Pandora180s1_BronxNY_20231116_L2Fit_fout2c2d20210302p1-8.txt File generation date: 20231117T072311.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 180 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora180_OF_v3d20201002.txt Instrument calibration file used: Pandora180s1_CF_v2d20210302.txt Level 1 file used: Pandora180s1_BronxNY_20231116_L1_smca1c2d20210302p1-8.txt Full location name: New York State DEC Bronx-Pfizer PAMS station (36-005-0133) Short location name: BronxNY Country of location: USA Location latitude [deg]: 40.8679 Location longitude [deg]: -73.8781 Location altitude [m]: 31 Local noon date: 20231116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 364 Nominal wavelengths inside fitting window [nm]: 305.0771 305.2181 305.3590 305.5000 305.6409 305.7819 305.9228 306.0637 306.2046 306.3455 306.4864 306.6273 306.7681 306.9090 307.0498 307.1906 307.3315 307.4723 307.6131 307.7539 307.8946 308.0354 308.1762 308.3169 308.4577 308.5984 308.7391 308.8798 309.0205 309.1612 309.3019 309.4425 309.5832 309.7238 309.8644 310.0051 310.1457 310.2863 310.4269 310.5674 310.7080 310.8486 310.9891 311.1297 311.2702 311.4107 311.5512 311.6917 311.8322 311.9726 312.1131 312.2536 312.3940 312.5344 312.6749 312.8153 312.9557 313.0961 313.2364 313.3768 313.5172 313.6575 313.7978 313.9382 314.0785 314.2188 314.3591 314.4994 314.6396 314.7799 314.9201 315.0604 315.2006 315.3408 315.4810 315.6212 315.7614 315.9016 316.0418 316.1819 316.3221 316.4622 316.6023 316.7424 316.8825 317.0226 317.1627 317.3028 317.4428 317.5829 317.7229 317.8629 318.0029 318.1430 318.2829 318.4229 318.5629 318.7029 318.8428 318.9828 319.1227 319.2626 319.4025 319.5424 319.6823 319.8222 319.9620 320.1019 320.2417 320.3816 320.5214 320.6612 320.8010 320.9408 321.0806 321.2203 321.3601 321.4998 321.6396 321.7793 321.9190 322.0587 322.1984 322.3381 322.4778 322.6174 322.7571 322.8967 323.0363 323.1760 323.3156 323.4552 323.5947 323.7343 323.8739 324.0134 324.1530 324.2925 324.4320 324.5715 324.7110 324.8505 324.9900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231116T122952.5Z 8720.520747 62 1 48.23 2 83.15 122.14 119.13 104.19 0.00 1 0.00 1 0 25 6.126e-01 2.744e-02 4.448e-01 2.072e-02 9.084179e-01 1.236686e-02 1.021308e-02 -6.000000e+00 3.506208e-01 223.23 -2.00 3.51 -2.00 322.36 0.00e+00 1.405833e-02 7.352408e-03 1.359836e-03 -6.000000e+00 1.757288e-02 280.29 -2.00 20.00 -2.00 321.93 0.00e+00 7.666 0.008 302.00 328.00 3 1.2318e+00 4.9384e-02 9.1885e-02 -6.0000e+00 8.6373e-01 1.2411e+00 6.5980e-02 5.7073e-02 -6.0000e+00 9.4324e-01 -1.5245e+00 5.7385e-02 2.7326e-02 -6.0000e+00 5.6184e-01 5.7780e-01 2.6864e-02 1.4481e-02 -6.0000e+00 2.4688e-01 2.7667e-05 -1.7806e-03 5.9405e-04 2.1342e-04 -6.0000e+00 1.8169e-02 7.9833e-02 -1.7987e-04 12 8 8 10 0 0 26.71 24.40 0.74 0.07983 0.06645 47 12 1 5 0 1025.990 28.29 19.99 24.40 14.13 37.5 941.95 900000 900000 102062 900000 -61706 -79666 -157317 -108585 -111762 -133446 900000 900000 -26764 238409 -85716 5724 -32187 50438 210204 -14487 -60093 189763 187397 -40241 -43517 -36264 -98703 900000 51507 -4897 900000 900000 129900 -29668 672 -51104 900000 34726 123453 76676 31877 71144 50141 44872 45518 -11832 2964 199873 -8758 215701 77877 81659 65144 10916 48785 609 50758 19154 26357 -4105 24755 50735 -3106 36952 3307 65170 31432 41337 38492 11415 4680 22013 13141 6155 -3049 4314 19845 6170 4546 13830 -7678 2187 -6261 -854 -545 12305 7635 6446 665 -931 -2957 -7697 -1629 -5917 -4384 -533 4014 1880 -2186 -2132 -8464 -3867 -5654 -2377 -3558 -3550 -392 -3882 -3674 -2726 2931 -374 2156 -1189 -595 1462 -1424 718 -1013 2352 -712 1609 3023 4315 468 6251 -287 -1699 2818 -85 -707 -147 789 562 -109 767 -1438 284 -514 452 -761 -889 900000 900000 900000 2058 900000 -1244 -1607 -6609 -2737 -2817 -4037 900000 900000 -540 4808 -4466 135 -1190 1017 4239 -438 -2626 3827 3779 -1285 -1390 -1036 -4976 900000 1039 -135 900000 900000 2620 -1523 23 -2998 900000 1082 2490 1968 1344 2087 1838 1728 1752 -824 185 4031 -690 4350 3141 3443 3463 1041 3220 65 3164 1545 1884 -399 1952 3534 -427 3726 473 5018 3515 4547 4940 2114 961 3713 2241 1004 -481 585 2601 1058 963 3207 -2570 741 -2462 -336 -225 4665 3110 2652 280 -373 -1139 -3042 -637 -2768 -2414 -338 2857 1536 -1918 -1780 -6760 -2620 -3740 -1597 -2569 -2721 -317 -3648 -3986 -3370 3778 -519 2909 -1609 -778 1885 -1975 1030 -1528 3372 -1002 2112 3792 5178 568 7034 -365 -2525 4688 -165 -1521 -338 1932 1481 -305 2181 -4228 817 -1426 1152 -1817 -2024 900000 SS 20231116T124050.2Z 8720.528359 65 1 48.36 2 81.41 124.09 117.22 105.64 0.00 1 0.00 1 0 17 5.940e-01 1.557e-02 2.823e-01 6.514e-03 7.873397e-01 3.790095e-03 8.938638e-03 -6.000000e+00 3.389196e-01 223.23 -2.00 3.51 -2.00 322.05 0.00e+00 9.368789e-03 2.238177e-03 2.625782e-03 -6.000000e+00 1.668037e-02 280.29 -2.00 20.00 -2.00 321.59 0.00e+00 6.316 0.005 302.00 328.00 3 1.2275e+00 1.4774e-02 7.5988e-02 -6.0000e+00 8.3376e-01 4.3578e-01 2.1970e-02 4.4663e-02 -6.0000e+00 9.0839e-01 -6.2025e-01 2.3101e-02 2.6272e-02 -6.0000e+00 5.4317e-01 2.4741e-01 1.0455e-02 1.1821e-02 -6.0000e+00 2.3782e-01 1.3322e-04 -1.5661e-03 1.9522e-04 1.8943e-04 -6.0000e+00 1.7084e-02 8.0011e-02 -1.7789e-04 12 8 8 10 0 0 26.02 24.40 0.46 0.08001 0.06824 117 29 1 5 0 413.260 28.29 20.00 24.40 15.29 37.4 949.28 900000 -216127 900000 -227651 -94407 -250604 -228140 -152028 -164299 900000 -220451 900000 -66413 900000 -127126 -21494 78248 -59015 -51532 -94603 900000 -21589 900000 -72797 53946 -27045 -47258 35524 -78127 900000 -27472 163854 -14616 40479 3579 -24598 109032 -15100 36424 -14485 88608 10282 11188 25552 25148 49378 5387 34762 5461 46048 34795 43681 24700 11279 17322 10606 23302 2316 15036 760 19192 7160 18332 13580 5698 11636 -2752 17652 1200 12566 4732 6258 3132 1155 1140 -5962 4468 -2809 4605 597 2365 344 -699 219 -2816 2396 -795 4284 -1070 628 -694 -5226 -3146 -4994 -588 -1619 356 -801 199 -1757 -2274 -577 -3380 -1445 -3749 -752 -1552 897 -356 -694 803 -350 634 -817 -188 -378 433 564 -94 522 485 1551 1059 2248 590 1065 392 -173 399 -291 1005 -940 543 -542 325 -95 349 259 -119 -109 -950 -524 900000 900000 -3769 900000 -3970 -599 -5032 -3858 -1285 -1650 900000 -4427 900000 -491 900000 -2821 -211 496 -1021 -861 -2454 900000 -261 900000 -1595 342 -390 -817 266 -1982 900000 -633 1039 -388 607 74 -709 943 -540 924 -693 1635 439 490 987 1000 1594 283 1443 327 2044 1946 2468 1837 1021 1528 1021 1961 232 1291 77 1935 935 2464 2092 961 1845 -522 2977 273 2845 1218 1575 767 262 231 -1206 827 -629 1150 185 838 139 -305 101 -1421 1206 -426 2192 -561 304 -320 -2446 -1494 -2723 -361 -1187 298 -756 191 -1636 -1922 -431 -2521 -1116 -3152 -650 -1462 914 -419 -927 1148 -521 921 -1156 -254 -514 609 837 -146 798 712 2158 1434 2902 751 1315 509 -256 677 -558 2061 -2092 1272 -1374 861 -258 963 714 -316 -270 -2222 -1171 900000 SS 20231116T125616.4Z 8720.539078 70 1 48.11 2 79.04 126.91 114.56 107.69 0.00 1 0.00 1 0 17 4.482e-01 7.939e-03 1.354e-01 2.433e-03 6.594478e-01 1.312025e-03 7.472131e-03 -6.000000e+00 2.553583e-01 223.23 -2.00 3.51 -2.00 321.39 0.00e+00 2.740612e-03 6.660948e-04 2.166628e-03 -6.000000e+00 1.136614e-02 280.29 -2.00 20.00 -2.00 320.88 0.00e+00 5.070 0.002 302.00 328.00 3 1.0719e+00 4.5735e-03 6.1651e-02 -6.0000e+00 6.2823e-01 6.2427e-02 6.5396e-03 3.7276e-02 -6.0000e+00 6.8421e-01 -1.0267e-01 6.9174e-03 2.0715e-02 -6.0000e+00 4.0837e-01 3.0773e-02 3.2491e-03 6.8730e-03 -6.0000e+00 1.7516e-01 6.0741e-04 -8.8600e-04 7.1580e-05 1.0401e-04 -6.0000e+00 1.2624e-02 8.0085e-02 -2.2097e-04 11 8 0 10 0 0 42.68 24.38 0.33 0.08008 0.07343 273 67 1 5 0 176.210 28.29 20.00 24.38 16.59 37.4 956.57 -203786 -147835 -158309 -108846 -160570 -119638 -45829 -144876 -102611 -187075 -143560 -106779 -60788 -55563 -37104 -42116 -37737 -57059 -56772 -29182 -49799 -18521 -25964 -12951 -20685 -14762 -13559 -50520 -41801 -33403 -15139 -13179 -7507 -5549 -12522 -11698 -10060 -9799 -9493 -1714 1489 1873 4530 501 7134 2128 -2259 336 427 5815 5570 8236 4809 6282 2231 2167 -39 2336 1613 2784 4935 4528 5612 3325 2357 38 193 656 3523 2286 2677 2895 64 -654 -3339 -2971 -5037 -2815 -1096 -109 -207 -1617 -813 -1473 -159 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