File name: Pandora162s1_Brussels-Uccle_20200519_L2Fit_fout2c2d20200309p1-8.txt File generation date: 20250630T092041.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: C. Hermans Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora162_OF_v5d20191031.txt Instrument calibration file used: Pandora162s1_CF_v2d20200309.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20200519_L1_smca1c2d20200309p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20200519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0904 305.2313 305.3722 305.5130 305.6538 305.7947 305.9355 306.0763 306.2171 306.3579 306.4986 306.6394 306.7801 306.9208 307.0616 307.2023 307.3429 307.4836 307.6243 307.7649 307.9056 308.0462 308.1868 308.3274 308.4680 308.6086 308.7492 308.8897 309.0303 309.1708 309.3113 309.4518 309.5923 309.7328 309.8733 310.0137 310.1542 310.2946 310.4350 310.5754 310.7158 310.8562 310.9966 311.1369 311.2773 311.4176 311.5579 311.6982 311.8385 311.9788 312.1191 312.2593 312.3996 312.5398 312.6801 312.8203 312.9605 313.1007 313.2408 313.3810 313.5211 313.6613 313.8014 313.9415 314.0816 314.2217 314.3618 314.5018 314.6419 314.7819 314.9220 315.0620 315.2020 315.3420 315.4819 315.6219 315.7619 315.9018 316.0417 316.1817 316.3216 316.4615 316.6013 316.7412 316.8811 317.0209 317.1607 317.3006 317.4404 317.5802 317.7199 317.8597 317.9995 318.1392 318.2789 318.4187 318.5584 318.6981 318.8378 318.9774 319.1171 319.2567 319.3964 319.5360 319.6756 319.8152 319.9548 320.0944 320.2339 320.3735 320.5130 320.6526 320.7921 320.9316 321.0711 321.2105 321.3500 321.4895 321.6289 321.7683 321.9078 322.0472 322.1866 322.3259 322.4653 322.6047 322.7440 322.8833 323.0227 323.1620 323.3013 323.4405 323.5798 323.7191 323.8583 323.9975 324.1368 324.2760 324.4152 324.5544 324.6935 324.8327 324.9718 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200519T041140.0Z 7444.174769 239 1 48.01 2 87.60 60.89 79.09 99.95 0.00 1 0.00 1 0 105 9.775e-01 8.878e-01 9.478e-01 8.198e-01 -8.519839e-01 5.795494e-01 3.398428e-02 -6.000000e+00 6.987571e-01 231.37 -2.00 3.79 -2.00 312.21 0.00e+00 -4.151101e-02 3.160101e-02 3.796615e-04 -6.000000e+00 5.077529e-02 277.48 -2.00 20.00 -2.00 312.25 0.00e+00 15.008 0.073 302.00 328.00 3 1.1309e+00 1.4702e+00 2.0031e-01 -6.0000e+00 1.7590e+00 -1.0616e+00 1.6189e+00 1.8983e-01 -6.0000e+00 1.9665e+00 1.5065e+00 9.4535e-01 3.8534e-02 -6.0000e+00 1.1400e+00 -6.9707e-01 3.8728e-01 3.3940e-02 -6.0000e+00 4.5440e-01 3.4394e-07 -2.0889e-02 1.4975e-02 1.1886e-03 -6.0000e+00 3.5379e-02 3.6157e-03 2.6194e-04 12 8 8 10 0 0 -321.86 18.93 18.24 0.00362 -0.15336 12 2 4 8 0 4000.000 14.99 18.93 15.51 21.27 21.48 30.3 1009.30 94881 65100 900000 41446 -163685 900000 -58280 900000 900000 900000 900000 900000 -16211 900000 900000 -17498 900000 49692 304930 196147 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 194992 900000 900000 900000 37008 -71111 -40871 599 -42195 58444 -67456 61929 -22226 900000 900000 900000 74726 12763 900000 900000 900000 900000 -25615 900000 238238 900000 900000 32165 900000 900000 67716 900000 900000 22702 52331 900000 956 -118699 60365 900000 900000 900000 900000 900000 13248 900000 -37932 32751 900000 900000 900000 26912 5849 900000 900000 3460 900000 293639 900000 63332 900000 900000 -7203 -11257 65498 900000 -38257 -63858 16561 -28798 23948 -39074 196400 181648 900000 29357 900000 48744 122161 26022 900000 -15067 34926 194677 -57788 18826 -20253 52372 900000 38761 118852 -83632 900000 -32144 900000 136315 54549 900000 64284 26104 900000 -49442 59236 101550 -30599 145508 -36635 900000 900000 36120 -26409 -12522 151423 74258 50950 900000 32437 -210096 900000 -45613 900000 900000 900000 900000 900000 -17850 900000 900000 -13695 900000 38892 238652 153514 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 152610 900000 900000 900000 28965 -55655 -31987 469 -38851 45741 -129723 48469 -32269 900000 900000 900000 58484 10740 900000 900000 900000 900000 -21577 900000 186456 900000 900000 25174 900000 900000 52998 900000 900000 20385 40957 900000 748 -239583 47244 900000 900000 900000 900000 900000 11920 900000 -54082 25633 900000 900000 900000 21063 4577 900000 900000 2839 900000 229816 900000 49567 900000 900000 -7820 -10744 51262 900000 -36758 -79401 12962 -26787 18743 -38351 153712 142166 900000 22976 900000 38149 95609 23252 900000 -18074 27335 152364 -76739 14734 -15851 40989 900000 30336 93019 -195308 900000 -51979 900000 106687 42692 900000 50311 20430 900000 -66010 46361 79478 -32954 113882 -49569 900000 900000 30727 -43421 -19354 118511 SS 20200519T042532.0Z 7444.184398 245 1 48.01 2 85.66 63.52 76.96 102.63 0.00 1 0.00 1 0 57 1.096e+00 5.568e-01 7.786e-01 4.429e-01 1.112330e+00 3.259426e-01 1.475714e-02 -6.000000e+00 7.363766e-01 231.37 -2.00 3.79 -2.00 316.54 0.00e+00 -2.770498e-02 2.951398e-02 5.268592e-03 -6.000000e+00 3.781208e-02 277.49 -2.00 20.00 -2.00 315.21 0.00e+00 10.852 0.027 302.00 328.00 3 -1.2043e-01 8.4745e-01 1.3854e-01 -6.0000e+00 1.8553e+00 3.5650e+00 9.8097e-01 1.1121e-01 -6.0000e+00 2.0564e+00 -2.0486e+00 5.3546e-01 3.2132e-02 -6.0000e+00 1.2099e+00 4.0332e-01 2.2437e-01 2.7857e-02 -6.0000e+00 5.1064e-01 9.2238e-07 1.9562e-02 1.1998e-02 2.3310e-04 -6.0000e+00 4.0706e-02 4.5445e-03 -1.8191e-04 12 9 8 11 8 0 -14.51 18.93 3.27 0.00454 0.15154 12 2 4 8 0 4000.000 15.00 18.93 16.08 21.27 21.48 30.1 1011.76 900000 -24717 900000 900000 900000 48088 -731 900000 -114674 102297 7080 83309 -59446 63680 900000 900000 900000 63316 900000 900000 900000 101210 900000 152705 28331 900000 900000 900000 900000 900000 900000 17948 900000 900000 -59544 900000 900000 -73711 900000 26828 900000 900000 900000 900000 900000 900000 900000 900000 -66079 900000 249202 347395 900000 900000 179175 269669 900000 -52171 900000 11981 900000 -114085 125077 186145 -5681 900000 900000 900000 -19555 900000 -35012 900000 184716 -44595 -60527 900000 900000 900000 900000 -71197 900000 111963 52359 -1788 900000 73938 -40574 900000 136591 900000 74030 89076 900000 900000 900000 900000 900000 34248 80420 8081 -11484 -52695 82211 22146 900000 -10565 187368 -25249 42968 107662 64747 515715 -7493 67614 -26557 35431 8046 80361 49392 -37616 23907 32103 -20111 -3801 78002 63321 155491 32534 50181 1693 -28190 -12654 -8406 42484 2407 -9171 -16061 25640 -22726 19286 47830 38569 99411 900000 -10498 900000 900000 900000 20424 -311 900000 -82834 43448 3007 35383 -31089 27047 900000 900000 900000 26892 900000 900000 900000 42987 900000 64858 12033 900000 900000 900000 900000 900000 900000 7623 900000 900000 -27281 900000 900000 -62128 900000 11394 900000 900000 900000 900000 900000 900000 900000 900000 -43782 900000 105843 147547 900000 900000 76100 114535 900000 -35670 900000 5088 900000 -136449 53124 79061 -2513 900000 900000 900000 -13248 900000 -28020 900000 78454 -26421 -36077 900000 900000 900000 900000 -73078 900000 47553 22238 -1197 900000 31403 -38810 900000 58014 900000 31443 37833 900000 900000 900000 900000 900000 24159 34761 6273 -9373 -56813 34917 12236 900000 -8584 79580 -29028 29456 45727 43561 219037 -10041 42307 -39867 29698 9083 46431 37500 -61977 20218 23983 -23901 -3729 33738 31295 66041 28623 43007 2604 -63301 -26311 -18162 60360 5245 -22458 -42235 43849 -57411 29721 51976 45159 69338 SS 20200519T044909.2Z 7444.200801 248 1 50.49 2 82.25 67.93 73.37 107.30 0.00 1 0.00 1 0 17 6.488e-01 2.073e-02 4.572e-01 1.600e-02 8.705851e-01 9.483641e-03 1.013770e-02 -6.000000e+00 3.803367e-01 231.37 -2.00 3.79 -2.00 322.30 0.00e+00 9.892362e-03 5.509274e-03 1.486134e-03 -6.000000e+00 1.849433e-02 277.49 -2.00 20.00 -2.00 321.85 0.00e+00 6.907 0.007 302.00 328.00 3 1.5507e+00 3.6883e-02 8.7846e-02 -6.0000e+00 9.6152e-01 6.9112e-01 5.3367e-02 5.9833e-02 -6.0000e+00 1.0506e+00 -9.5021e-01 5.3905e-02 2.8420e-02 -6.0000e+00 6.1673e-01 3.8267e-01 2.4334e-02 1.2538e-02 -6.0000e+00 2.5480e-01 5.0880e-05 -1.8425e-03 4.6147e-04 1.7035e-04 -6.0000e+00 1.7929e-02 2.7492e-03 -2.5671e-05 12 8 8 10 0 0 -3.75 18.93 0.40 0.00275 -0.01110 43 9 4 8 0 1173.830 15.00 18.93 16.74 21.27 21.58 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