File name: Pandora162s1_Brussels-Uccle_20220525_L2Fit_fwvt1c15d20210909p1-8.txt File generation date: 20250630T114543.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Michel Van Roozendael Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora162_OF_v8d20191031.txt Instrument calibration file used: Pandora162s1_CF_v15d20210909.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20220525_L1_smca1c15d20210909p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20220525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1648 1798 Nominal wavelengths inside fitting window [nm]: 492.0476 492.1683 492.2890 492.4097 492.5303 492.6510 492.7716 492.8922 493.0128 493.1334 493.2539 493.3745 493.4950 493.6155 493.7360 493.8564 493.9769 494.0973 494.2178 494.3382 494.4585 494.5789 494.6993 494.8196 494.9399 495.0602 495.1805 495.3008 495.4211 495.5413 495.6615 495.7817 495.9019 496.0221 496.1422 496.2624 496.3825 496.5026 496.6227 496.7427 496.8628 496.9828 497.1029 497.2229 497.3428 497.4628 497.5828 497.7027 497.8226 497.9425 498.0624 498.1823 498.3021 498.4220 498.5418 498.6616 498.7814 498.9012 499.0209 499.1407 499.2604 499.3801 499.4998 499.6194 499.7391 499.8587 499.9783 500.0980 500.2175 500.3371 500.4567 500.5762 500.6957 500.8152 500.9347 501.0542 501.1736 501.2931 501.4125 501.5319 501.6513 501.7707 501.8900 502.0094 502.1287 502.2480 502.3673 502.4865 502.6058 502.7250 502.8443 502.9635 503.0827 503.2018 503.3210 503.4401 503.5593 503.6784 503.7974 503.9165 504.0356 504.1546 504.2736 504.3926 504.5116 504.6306 504.7496 504.8685 504.9874 505.1063 505.2252 505.3441 505.4630 505.5818 505.7006 505.8194 505.9382 506.0570 506.1758 506.2945 506.4132 506.5320 506.6506 506.7693 506.8880 507.0066 507.1253 507.2439 507.3625 507.4810 507.5996 507.7181 507.8367 507.9552 508.0737 508.1921 508.3106 508.4291 508.5475 508.6659 508.7843 508.9027 509.0210 509.1394 509.2577 509.3760 509.4943 509.6126 509.7308 509.8491 509.9673 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220525T040221.8Z 8180.168308 44 1 50.42 2 88.05 58.41 72.72 118.00 0.00 1 0.00 1 0 22 4.535e-03 4.489e-03 1.716e-04 1.711e-04 1.412090e+04 1.221460e+01 9.559295e+02 -6.000000e+00 2.543197e+02 278.05 -2.00 20.00 -2.00 505.40 0.00e+00 3.178609e-03 4.741676e-06 1.840900e-04 -6.000000e+00 1.268640e-04 278.05 -2.00 20.00 -2.00 500.87 0.00e+00 1.580057e+00 3.392798e-03 1.010901e-01 -6.000000e+00 9.145753e-02 231.76 -2.00 3.79 -2.00 502.40 0.00e+00 16.180 0.092 489.00 513.00 1 8.7179e-01 2.5954e-04 2.7968e-02 -6.0000e+00 7.0127e-03 -3.1641e-02 6.4520e-05 2.8460e-03 -6.0000e+00 1.7993e-03 7.0071e-02 1.2560e-03 1.7103e-05 1.2737e-04 -6.0000e+00 5.0007e-04 3.7120e-03 -7.0801e-05 11 8 0 10 0 0 9.56 19.08 2.87 0.00371 0.01242 428 86 2 2 0 116.150 14.99 19.08 15.81 21.38 21.58 47.7 1002.70 -550 -426 -34 202 250 721 960 868 830 556 446 290 -67 -264 -266 -339 -228 103 295 75 117 354 271 419 558 401 281 260 -153 -599 -540 -546 -499 49 203 -193 -163 -35 -149 -266 -83 14 49 207 371 448 316 191 22 -296 -686 -804 -965 -869 -414 -182 -134 -73 105 221 372 510 437 416 340 191 -66 -146 -266 -434 -513 -426 -458 -288 -84 -290 -570 -579 -477 -611 -592 -527 -659 -537 -280 -303 -403 -284 -226 -30 52 249 556 543 384 355 186 -124 -292 -774 -1103 -1123 -862 -394 -287 -535 -519 -457 -389 -86 44 35 168 498 631 777 1031 1110 771 486 422 272 256 554 613 371 429 364 114 434 404 -104 -147 -117 -399 -221 156 -103 -83 237 284 184 289 301 314 275 95 -288 -553 -595 -506 -494 -387 -32 186 238 699 947 831 797 553 438 281 -64 -252 -253 -324 -221 97 286 74 116 352 271 421 563 407 285 261 -152 -581 -514 -521 -485 49 208 -194 -163 -35 -147 -261 -82 13 49 210 381 462 326 196 22 -294 -667 -797 -948 -858 -400 -181 -137 -75 109 229 386 531 458 436 355 198 -67 -148 -266 -430 -506 -419 -454 -289 -85 -292 -569 -570 -462 -590 -571 -510 -643 -529 -278 -304 -406 -285 -226 -30 52 251 544 531 384 346 176 -114 -273 -717 -1021 -1054 -803 -381 -278 -533 -520 -456 -387 -86 44 36 173 516 656 784 1050 1142 800 504 432 274 265 570 633 374 434 369 116 441 409 -105 -146 -116 -397 -222 159 -107 -89 246 300 196 311 325 340 296 101 -304 -577 -618 -529 SQ 20220525T041059.5Z 8180.174300 48 1 27.82 2 86.87 60.05 71.53 119.82 0.00 1 0.00 1 0 22 3.302e-03 3.273e-03 1.371e-04 1.369e-04 1.026717e+04 9.414560e+00 7.083857e+02 -6.000000e+00 1.851563e+02 278.06 -2.00 20.00 -2.00 505.37 0.00e+00 2.155262e-03 3.781069e-06 1.266434e-04 -6.000000e+00 9.236275e-05 278.06 -2.00 20.00 -2.00 500.76 0.00e+00 1.389064e+00 2.723562e-03 7.488625e-02 -6.000000e+00 6.658625e-02 231.76 -2.00 3.79 -2.00 502.31 0.00e+00 13.247 0.050 489.00 513.00 1 3.0515e-01 2.0840e-04 2.1205e-02 -6.0000e+00 5.1056e-03 -1.9125e-02 5.2102e-05 2.1192e-03 -6.0000e+00 1.3100e-03 1.9305e-01 1.0912e-03 1.4055e-05 9.3646e-05 -6.0000e+00 3.6406e-04 3.2355e-03 -6.9486e-05 10 0 0 10 0 0 -7.36 19.07 1.97 0.00324 0.01080 557 112 2 2 0 48.360 15.00 19.07 16.10 21.38 21.58 47.8 1003.88 -346 -262 15 150 115 482 718 615 560 392 281 190 -93 -175 -145 -272 -201 94 224 -6 27 238 213 302 438 327 224 243 -76 -448 -312 -325 -366 150 162 -271 -204 24 -88 -192 -33 9 24 153 265 298 225 117 40 -227 -542 -591 -704 -628 -329 -165 -211 -128 -4 158 310 381 345 312 292 127 -24 -121 -131 -308 -361 -250 -339 -215 -37 -181 -485 -435 -276 -408 -454 -367 -523 -416 -132 -229 -281 -225 -89 -10 39 172 449 353 199 266 149 -59 -161 -514 -767 -812 -667 -242 -213 -531 -461 -358 -280 -26 128 38 132 351 449 536 747 800 555 373 359 240 171 455 433 155 271 227 61 308 404 -92 -66 -64 -280 -136 185 -82 -145 196 197 124 209 227 199 186 77 -205 -393 -375 -342 -317 -243 14 142 112 480 701 608 555 385 273 190 -91 -171 -141 -266 -200 92 223 -6 28 243 219 311 452 328 224 249 -77 -442 -302 -314 -361 152 163 -276 -208 24 -88 -192 -33 9 24 157 275 310 234 120 41 -226 -528 -584 -688 -617 -329 -164 -214 -132 -4 163 321 395 360 314 303 130 -25 -121 -130 -303 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-6.0000e+00 3.6255e-04 3.8875e-03 -7.3276e-05 10 0 0 10 0 0 8.67 19.08 1.94 0.00389 0.01105 557 112 2 2 0 48.360 15.00 19.08 16.10 21.38 21.58 47.8 1003.88 -320 -270 1 112 100 457 707 616 575 398 303 196 -85 -151 -118 -254 -186 111 219 -15 28 240 196 311 458 325 206 239 -83 -442 -289 -320 -334 150 142 -263 -215 9 -90 -163 -40 13 9 142 255 299 213 88 48 -242 -522 -584 -692 -644 -311 -145 -193 -143 -28 132 284 425 335 309 271 165 -41 -121 -129 -299 -347 -267 -316 -210 -20 -199 -466 -411 -252 -395 -454 -361 -536 -422 -156 -199 -295 -200 -95 5 8 155 464 368 191 258 142 -80 -187 -516 -766 -822 -673 -248 -230 -532 -455 -345 -267 -19 108 19 115 351 452 530 744 827 564 355 337 222 166 449 439 164 286 223 53 368 380 -79 -101 -88 -300 -140 208 -82 -152 170 218 105 199 229 219 200 43 -213 -395 -400 -325 -298 -255 1 108 96 447 703 619 579 398 300 191 -82 -145 -113 -243 -181 110 221 -15 28 241 197 314 464 331 209 241 -82 -444 -284 -314 -334 149 145 -273 -222 9 -91 -165 -41 13 9 143 259 306 217 89 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