File name: Pandora162s1_Brussels-Uccle_20220705_L2Fit_fwvt1c15d20210909p1-8.txt File generation date: 20250630T120102.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Michel Van Roozendael Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora162_OF_v8d20191031.txt Instrument calibration file used: Pandora162s1_CF_v15d20210909.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20220705_L1_smca1c15d20210909p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20220705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1648 1798 Nominal wavelengths inside fitting window [nm]: 492.0476 492.1683 492.2890 492.4097 492.5303 492.6510 492.7716 492.8922 493.0128 493.1334 493.2539 493.3745 493.4950 493.6155 493.7360 493.8564 493.9769 494.0973 494.2178 494.3382 494.4585 494.5789 494.6993 494.8196 494.9399 495.0602 495.1805 495.3008 495.4211 495.5413 495.6615 495.7817 495.9019 496.0221 496.1422 496.2624 496.3825 496.5026 496.6227 496.7427 496.8628 496.9828 497.1029 497.2229 497.3428 497.4628 497.5828 497.7027 497.8226 497.9425 498.0624 498.1823 498.3021 498.4220 498.5418 498.6616 498.7814 498.9012 499.0209 499.1407 499.2604 499.3801 499.4998 499.6194 499.7391 499.8587 499.9783 500.0980 500.2175 500.3371 500.4567 500.5762 500.6957 500.8152 500.9347 501.0542 501.1736 501.2931 501.4125 501.5319 501.6513 501.7707 501.8900 502.0094 502.1287 502.2480 502.3673 502.4865 502.6058 502.7250 502.8443 502.9635 503.0827 503.2018 503.3210 503.4401 503.5593 503.6784 503.7974 503.9165 504.0356 504.1546 504.2736 504.3926 504.5116 504.6306 504.7496 504.8685 504.9874 505.1063 505.2252 505.3441 505.4630 505.5818 505.7006 505.8194 505.9382 506.0570 506.1758 506.2945 506.4132 506.5320 506.6506 506.7693 506.8880 507.0066 507.1253 507.2439 507.3625 507.4810 507.5996 507.7181 507.8367 507.9552 508.0737 508.1921 508.3106 508.4291 508.5475 508.6659 508.7843 508.9027 509.0210 509.1394 509.2577 509.3760 509.4943 509.6126 509.7308 509.8491 509.9673 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220705T035708.3Z 8221.164680 36 1 49.68 2 88.23 54.90 121.79 352.96 0.00 1 0.00 1 0 22 7.130e-03 7.044e-03 3.845e-04 3.824e-04 1.613679e+04 2.806848e+01 1.066259e+03 -6.000000e+00 4.065187e+02 282.29 -2.00 20.00 -2.00 505.47 0.00e+00 4.465835e-03 1.078356e-05 2.544339e-04 -6.000000e+00 2.015060e-04 282.29 -2.00 20.00 -2.00 501.12 0.00e+00 1.135872e+00 7.526837e-03 1.163820e-01 -6.000000e+00 1.437189e-01 233.67 -2.00 3.79 -2.00 502.62 0.00e+00 16.583 0.099 489.00 513.00 1 2.3174e+00 5.7701e-04 2.9616e-02 -6.0000e+00 1.1036e-02 -5.3055e-02 1.4167e-04 3.1413e-03 -6.0000e+00 2.8284e-03 1.5786e-02 1.5287e-03 3.8172e-05 1.4445e-04 -6.0000e+00 7.8653e-04 -7.0974e-04 -2.9939e-05 12 8 8 10 0 0 -1.09 19.22 4.93 -0.00071 0.00989 111 23 4 2 0 447.460 15.00 19.22 19.16 21.48 21.69 49.2 1009.82 -1140 -850 -315 252 557 1184 1518 1464 1396 990 628 344 -138 -428 -566 -635 -383 92 459 330 296 598 416 626 748 612 529 341 -214 -963 -1046 -1086 -762 -82 259 -160 -21 9 -206 -416 -168 -87 178 492 657 762 488 391 76 -397 -939 -1240 -1416 -1266 -641 -202 72 153 372 448 650 817 727 728 510 366 -66 -314 -386 -707 -950 -782 -797 -438 -219 -420 -816 -1015 -958 -1062 -1040 -833 -953 -766 -417 -437 -513 -451 -394 -140 38 378 736 832 628 650 272 -144 -584 -1316 -1692 -1655 -1241 -573 -301 -425 -599 -601 -595 -251 -26 68 325 775 1024 1157 1496 1537 1191 751 515 301 310 591 780 608 706 590 317 576 506 -144 -365 -299 -695 -440 1 -165 60 396 467 415 530 501 546 424 116 -440 -860 -972 -895 -1000 -755 -273 224 510 1106 1440 1404 1341 947 595 322 -128 -396 -522 -589 -360 88 427 312 282 569 398 603 725 597 515 330 -204 -904 -966 -1006 -718 -79 256 -161 -21 9 -205 -414 -167 -87 181 484 653 763 490 390 75 -385 -938 -1217 -1379 -1241 -639 -197 72 155 378 457 664 839 752 754 527 375 -67 -316 -384 -698 -935 -768 -790 -438 -220 -423 -814 -999 -931 -1028 -1006 -806 -931 -755 -414 -437 -516 -452 -393 -139 38 380 744 840 625 628 255 -132 -550 -1229 -1581 -1497 -1159 -556 -304 -420 -599 -599 -592 -250 -27 70 335 803 1066 1212 1583 1647 1236 779 551 317 323 614 814 640 748 627 324 588 538 -152 -383 -312 -731 -449 1 -174 65 431 514 463 595 564 591 476 129 -486 -943 -1062 -986 SQ 20220705T041532.7Z 8221.177462 41 1 50.56 2 85.80 58.38 122.08 358.12 0.00 1 0.00 1 0 22 3.555e-03 3.527e-03 1.141e-04 1.140e-04 1.022564e+04 7.945038e+00 6.945568e+02 -6.000000e+00 2.026983e+02 282.29 -2.00 20.00 -2.00 505.38 0.00e+00 2.489011e-03 3.190577e-06 1.454001e-04 -6.000000e+00 1.004747e-04 282.29 -2.00 20.00 -2.00 500.78 0.00e+00 1.004426e+00 2.270865e-03 7.317460e-02 -6.000000e+00 7.166253e-02 233.67 -2.00 3.79 -2.00 502.34 0.00e+00 11.067 0.029 489.00 513.00 1 8.6465e-01 1.7412e-04 1.7662e-02 -6.0000e+00 5.5028e-03 -3.0277e-02 4.3440e-05 1.9527e-03 -6.0000e+00 1.4104e-03 1.5339e-01 1.0097e-03 1.1743e-05 9.1873e-05 -6.0000e+00 3.9217e-04 -1.3698e-03 -2.8327e-05 10 0 0 10 0 0 5.38 19.21 2.03 -0.00137 0.00563 809 162 2 2 0 61.200 15.00 19.21 19.78 21.38 21.69 49.2 1011.41 -354 -261 38 164 142 515 772 714 654 463 339 217 -73 -147 -196 -301 -211 91 226 9 35 246 246 348 489 337 220 253 -84 -473 -358 -399 -417 102 116 -248 -190 1 -125 -213 -68 -5 10 143 255 290 234 109 36 -259 -556 -631 -772 -702 -363 -157 -179 -103 -1 138 296 444 335 309 311 152 -22 -119 -146 -357 -383 -289 -358 -247 -29 -196 -486 -447 -327 -442 -497 -405 -576 -472 -195 -239 -317 -234 -143 -36 37 142 464 397 242 286 159 -84 -223 -552 -848 -893 -722 -255 -229 -515 -470 -389 -297 -39 75 61 154 363 479 566 767 867 610 375 348 232 162 472 442 184 296 273 79 362 398 -104 -103 -81 -312 -120 206 -60 -118 210 264 135 225 249 227 225 59 -207 -415 -397 -353 -320 -239 36 160 137 507 771 721 661 465 336 213 -71 -142 -188 -289 -206 90 221 9 35 247 248 352 496 344 224 255 -83 -459 -354 -394 -404 101 119 -248 -190 1 -128 -217 -69 -5 10 145 261 297 240 111 36 -264 -554 -615 -745 -680 -359 -159 -179 -105 -1 141 302 456 346 319 319 155 -22 -118 -144 -347 -370 -289 -348 -243 -29 -194 -477 -431 -323 -434 -489 -400 -555 -458 -191 -236 -315 -232 -141 -35 37 142 468 402 242 280 152 -81 -210 -513 -786 -839 -674 -246 -229 -510 -467 -384 -292 -38 74 61 156 372 493 586 801 882 624 381 361 237 164 475 448 188 304 280 82 371 406 -105 -103 -81 -311 -121 211 -61 -121 219 278 144 233 259 236 234 63 -216 -428 -407 -364 SQ 20220705T042236.5Z 8221.182366 44 1 28.31 2 84.84 59.70 122.12 0.11 0.00 1 0.00 1 0 22 3.129e-03 3.106e-03 1.239e-04 1.237e-04 8.781754e+03 8.469254e+00 6.018223e+02 -6.000000e+00 1.784195e+02 282.29 -2.00 20.00 -2.00 505.36 0.00e+00 2.205093e-03 3.450261e-06 1.285352e-04 -6.000000e+00 8.843986e-05 282.29 -2.00 20.00 -2.00 500.73 0.00e+00 8.879310e-01 2.466352e-03 6.341180e-02 -6.000000e+00 6.307839e-02 233.67 -2.00 3.79 -2.00 502.28 0.00e+00 9.578 0.019 489.00 513.00 1 6.5546e-01 1.8899e-04 1.5114e-02 -6.0000e+00 4.8436e-03 -2.6181e-02 4.7398e-05 1.6820e-03 -6.0000e+00 1.2414e-03 2.3662e-01 9.7104e-04 1.2862e-05 8.1057e-05 -6.0000e+00 3.4519e-04 -3.5046e-03 -1.4955e-05 10 0 0 10 0 0 9.13 19.21 1.79 -0.00350 0.00323 646 130 2 2 0 41.680 15.00 19.21 20.25 21.48 21.69 48.8 1011.81 -266 -225 44 160 94 464 655 607 562 424 303 211 -47 -164 -163 -239 -173 80 213 -11 8 213 176 305 442 285 180 235 -115 -445 -266 -296 -378 116 126 -293 -215 -3 -86 -196 -44 -17 17 134 238 271 188 104 80 -191 -498 -530 -661 -593 -324 -151 -208 -149 -33 108 270 381 300 275 295 127 -39 -109 -110 -307 -342 -269 -344 -208 -3 -175 -461 -384 -269 -357 -413 -344 -524 -440 -137 -233 -273 -211 -97 -23 6 155 420 329 160 243 136 -55 -180 -447 -723 -774 -649 -216 -192 -504 -413 -342 -248 -20 91 34 134 334 426 503 680 772 516 332 310 240 177 463 404 124 261 232 27 319 375 -102 -70 -60 -311 -127 195 -52 -156 172 204 141 220 248 218 178 44 -198 -364 -355 -271 -245 -210 42 152 93 465 644 603 559 419 306 210 -46 -161 -158 -233 -171 78 212 -11 9 218 180 313 456 295 186 240 -116 -437 -256 -286 -372 117 126 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