File name: Pandora162s1_Brussels-Uccle_20221014_L2Fit_fnvs5c15d20210909p1-8.txt File generation date: 20250630T123607.9Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c15p1-8 Local principal investigator: Michel Van Roozendael Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora162_OF_v8d20191031.txt Instrument calibration file used: Pandora162s1_CF_v15d20210909.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20221014_L1_smca1c15d20210909p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20221014 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 921 1467 Nominal wavelengths inside fitting window [nm]: 400.0912 400.2231 400.3550 400.4869 400.6188 400.7507 400.8825 401.0144 401.1462 401.2780 401.4098 401.5416 401.6734 401.8051 401.9369 402.0686 402.2003 402.3320 402.4637 402.5954 402.7270 402.8587 402.9903 403.1219 403.2535 403.3851 403.5167 403.6482 403.7798 403.9113 404.0428 404.1743 404.3058 404.4373 404.5687 404.7002 404.8316 404.9630 405.0944 405.2258 405.3571 405.4885 405.6198 405.7512 405.8825 406.0138 406.1450 406.2763 406.4076 406.5388 406.6700 406.8012 406.9324 407.0636 407.1948 407.3259 407.4571 407.5882 407.7193 407.8504 407.9814 408.1125 408.2436 408.3746 408.5056 408.6366 408.7676 408.8986 409.0295 409.1605 409.2914 409.4223 409.5532 409.6841 409.8150 409.9458 410.0767 410.2075 410.3383 410.4691 410.5999 410.7307 410.8614 410.9922 411.1229 411.2536 411.3843 411.5150 411.6457 411.7763 411.9070 412.0376 412.1682 412.2988 412.4294 412.5599 412.6905 412.8210 412.9516 413.0821 413.2126 413.3430 413.4735 413.6039 413.7344 413.8648 413.9952 414.1256 414.2560 414.3863 414.5167 414.6470 414.7773 414.9076 415.0379 415.1682 415.2984 415.4287 415.5589 415.6891 415.8193 415.9495 416.0797 416.2098 416.3400 416.4701 416.6002 416.7303 416.8604 416.9905 417.1205 417.2506 417.3806 417.5106 417.6406 417.7706 417.9005 418.0305 418.1604 418.2903 418.4202 418.5501 418.6800 418.8099 418.9397 419.0695 419.1994 419.3292 419.4590 419.5887 419.7185 419.8482 419.9780 420.1077 420.2374 420.3671 420.4967 420.6264 420.7560 420.8856 421.0153 421.1449 421.2744 421.4040 421.5336 421.6631 421.7926 421.9221 422.0516 422.1811 422.3106 422.4400 422.5694 422.6989 422.8283 422.9577 423.0870 423.2164 423.3457 423.4751 423.6044 423.7337 423.8630 423.9922 424.1215 424.2507 424.3800 424.5092 424.6384 424.7676 424.8967 425.0259 425.1550 425.2842 425.4133 425.5424 425.6714 425.8005 425.9296 426.0586 426.1876 426.3166 426.4456 426.5746 426.7035 426.8325 426.9614 427.0903 427.2192 427.3481 427.4770 427.6059 427.7347 427.8635 427.9924 428.1212 428.2499 428.3787 428.5075 428.6362 428.7649 428.8936 429.0223 429.1510 429.2797 429.4083 429.5370 429.6656 429.7942 429.9228 430.0514 430.1799 430.3085 430.4370 430.5655 430.6940 430.8225 430.9510 431.0794 431.2079 431.3363 431.4647 431.5931 431.7215 431.8499 431.9782 432.1066 432.2349 432.3632 432.4915 432.6198 432.7480 432.8763 433.0045 433.1328 433.2610 433.3892 433.5173 433.6455 433.7736 433.9018 434.0299 434.1580 434.2861 434.4141 434.5422 434.6702 434.7983 434.9263 435.0543 435.1823 435.3102 435.4382 435.5661 435.6940 435.8220 435.9498 436.0777 436.2056 436.3334 436.4613 436.5891 436.7169 436.8447 436.9725 437.1002 437.2280 437.3557 437.4834 437.6111 437.7388 437.8665 437.9941 438.1218 438.2494 438.3770 438.5046 438.6322 438.7597 438.8873 439.0148 439.1423 439.2698 439.3973 439.5248 439.6523 439.7797 439.9071 440.0346 440.1620 440.2893 440.4167 440.5441 440.6714 440.7987 440.9261 441.0533 441.1806 441.3079 441.4351 441.5624 441.6896 441.8168 441.9440 442.0712 442.1983 442.3255 442.4526 442.5797 442.7068 442.8339 442.9610 443.0880 443.2151 443.3421 443.4691 443.5961 443.7231 443.8501 443.9770 444.1039 444.2309 444.3578 444.4847 444.6115 444.7384 444.8652 444.9921 445.1189 445.2457 445.3725 445.4992 445.6260 445.7527 445.8794 446.0062 446.1329 446.2595 446.3862 446.5128 446.6395 446.7661 446.8927 447.0193 447.1459 447.2724 447.3990 447.5255 447.6520 447.7785 447.9050 448.0314 448.1579 448.2843 448.4107 448.5372 448.6635 448.7899 448.9163 449.0426 449.1690 449.2953 449.4216 449.5479 449.6741 449.8004 449.9266 450.0528 450.1790 450.3052 450.4314 450.5576 450.6837 450.8099 450.9360 451.0621 451.1882 451.3142 451.4403 451.5663 451.6923 451.8184 451.9443 452.0703 452.1963 452.3222 452.4482 452.5741 452.7000 452.8259 452.9517 453.0776 453.2034 453.3293 453.4551 453.5809 453.7066 453.8324 453.9582 454.0839 454.2096 454.3353 454.4610 454.5867 454.7123 454.8380 454.9636 455.0892 455.2148 455.3404 455.4659 455.5915 455.7170 455.8425 455.9680 456.0935 456.2190 456.3444 456.4699 456.5953 456.7207 456.8461 456.9715 457.0968 457.2222 457.3475 457.4728 457.5981 457.7234 457.8487 457.9739 458.0992 458.2244 458.3496 458.4748 458.6000 458.7251 458.8503 458.9754 459.1005 459.2256 459.3507 459.4757 459.6008 459.7258 459.8508 459.9758 460.1008 460.2258 460.3508 460.4757 460.6006 460.7255 460.8504 460.9753 461.1002 461.2250 461.3498 461.4746 461.5994 461.7242 461.8490 461.9737 462.0985 462.2232 462.3479 462.4726 462.5973 462.7219 462.8466 462.9712 463.0958 463.2204 463.3450 463.4695 463.5941 463.7186 463.8431 463.9676 464.0921 464.2165 464.3410 464.4654 464.5898 464.7142 464.8386 464.9630 465.0874 465.2117 465.3360 465.4603 465.5846 465.7089 465.8331 465.9574 466.0816 466.2058 466.3300 466.4542 466.5784 466.7025 466.8266 466.9508 467.0749 467.1989 467.3230 467.4471 467.5711 467.6951 467.8191 467.9431 468.0671 468.1910 468.3150 468.4389 468.5628 468.6867 468.8105 468.9344 469.0582 469.1821 469.3059 469.4297 469.5534 469.6772 469.8009 469.9247 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Spectrometer control temperature [°C], 999=no temperature signal Column 159: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 160: Temperature in head sensor [°C], 999=no temperature signal Column 161: Temperature at electronics board 1 [°C], 999=no temperature signal Column 162: Temperature at electronics board 2 [°C], 999=no temperature signal Column 163: Humidity in head sensor [%], -9=no humidity signal Column 164: Pressure in head sensor [hPa], -9=no pressure signal Columns 165-711: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 712-1258: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221014T120017.4Z 8322.500201 374 1 0.78 2 59.44 189.12 94.16 318.75 0.00 1 0.00 1 0 33 1.990e-03 1.966e-03 2.091e-03 2.054e-03 1.326921e+03 3.998865e+02 1.062396e+02 1.373504e+02 3.951619e+02 276.67 -2.00 20.00 -2.00 445.51 0.00e+00 -2.297035e-04 2.264547e-04 1.539734e-06 2.139135e-05 2.168988e-04 276.67 -2.00 20.00 -2.00 454.95 0.00e+00 1.984882e-04 1.840330e-05 1.373148e-06 2.070433e-05 1.800069e-05 224.14 -2.00 2.36 -2.00 435.40 0.00e+00 6.094260e+05 2.888852e+05 1.264526e+04 3.278444e+05 2.874456e+05 259.43 -2.00 11.45 -2.00 457.72 0.00e+00 2.582159e-01 5.793944e-02 1.066439e-03 1.738332e-02 6.207444e-02 224.68 -2.00 3.79 -2.00 454.31 0.00e+00 6.494614e-06 7.371647e-06 2.528893e-07 1.641444e-06 7.632168e-06 276.67 -2.00 20.00 -2.00 455.60 0.00e+00 1.959 0.000 397.00 473.00 4 3.2090e+00 2.1875e-03 4.9104e-03 5.6821e-04 2.0237e-03 6.5970e-02 2.6163e-03 1.0257e-03 3.3201e-04 2.5117e-03 -1.2795e-03 1.5007e-03 1.3577e-04 1.3873e-04 1.4317e-03 -1.2730e-03 5.0363e-04 1.7705e-05 3.5592e-05 4.8405e-04 4.0092e-04 2.5683e-04 8.4503e-06 1.9877e-05 2.4203e-04 5.2128e-02 2.5693e-02 1.4842e-03 8.3945e-06 5.3790e-05 1.2092e-03 -5.7527e-05 2.3487e-05 2.6902e-07 5.5537e-07 2.2252e-05 -3.0953e-05 3.1896e-05 3.2227e-07 6.7621e-07 3.0281e-05 -1.7457e-02 -2.6387e-07 6.8983e-01 2.0694e-01 7.0893e-04 3.5598e-03 1.8773e-01 12 9 9 12 1 1 999.00 18.67 2.05 -0.01746 -0.01609 2 62 2 2 0 164.170 15.00 18.67 22.45 21.06 21.27 49.9 999.69 -173 -269 23 -62 215 70 -261 131 -23 -33 -127 89 49 -260 -5 13 464 -96 123 -117 -9 43 -7 -184 -161 66 71 146 -395 -198 91 576 61 114 -136 -84 338 508 35 171 -104 -75 11 47 -170 -235 27 113 316 468 -15 380 311 110 358 -169 -151 -402 -109 132 -151 -38 -416 210 -367 -171 -100 -72 -302 422 26 -115 51 168 -427 213 68 37 195 -12 -55 -325 23 -171 -150 187 -332 -144 -134 459 -70 177 52 -11 -160 -184 126 50 -42 -153 -159 -158 195 300 -176 -104 -226 -306 343 191 -268 -50 -133 258 113 -36 -180 -442 -88 217 406 110 11 -152 -45 -40 -98 408 104 -421 118 126 -114 58 -193 -77 -47 -108 -99 252 116 -20 -175 72 150 -343 376 0 357 -5 154 -383 101 206 -84 -91 -336 -220 300 183 -76 -234 219 78 -116 84 -5 -104 181 -17 -81 66 -107 -79 -547 -196 30 -142 212 -93 114 -203 166 -132 61 179 430 15 -7 128 207 164 -63 -127 336 142 267 -48 -2 189 12 64 234 -21 -302 -233 -80 9 -90 139 255 0 -185 357 130 20 119 1 -28 139 -12 224 -139 619 127 204 96 -205 -104 -487 223 -120 107 -322 110 232 -367 272 -440 104 -364 30 -313 76 148 7 -196 -125 -81 90 -221 156 162 -285 -37 174 -178 -140 134 -275 -57 -50 -19 15 -79 311 -17 205 -172 373 12 37 111 -331 6 -185 -69 -24 204 133 -46 -48 -120 93 -26 91 -332 268 125 -9 -181 50 -188 255 -216 -110 43 -72 98 -248 189 172 -523 -347 -130 -37 87 -237 79 -57 -200 319 106 -89 -82 38 -22 63 142 196 65 -228 -14 29 -308 116 -114 -199 -241 -56 -58 211 238 28 191 440 -348 61 210 -160 206 -343 269 -77 32 411 126 36 87 -278 -127 2 -238 308 49 -347 129 158 80 -82 179 368 73 -117 -142 -245 -130 -125 359 -226 139 -268 -25 -15 34 16 295 -164 117 -108 -153 271 26 -114 -121 233 12 89 197 2 133 -166 -89 -143 -152 92 46 -213 -349 198 450 210 -58 -304 -64 -96 212 51 -304 -7 17 475 -242 -335 34 192 -219 -64 208 121 -61 -164 -37 69 -27 -365 -284 -15 66 -144 144 -4 236 -13 189 61 183 87 246 72 -246 272 -73 -86 -154 -257 287 -187 319 -85 243 425 18 -229 -7 286 138 -446 -235 -253 8 59 183 171 32 -277 -97 -53 -106 79 201 -75 -228 -146 45 97 57 237 -23 73 250 60 -91 8 8 -220 121 162 -189 -127 248 9 177 141 69 -259 -48 -16 77 -18 -366 149 -116 -381 -195 91 -283 108 -222 -134 -162 -198 -110 -75 49 3 298 32 111 -267 226 308 79 191 77 -95 -63 200 178 331 43 -73 -10 0 -1 413 139 276 4 -4 -62 -190 -432 -123 -109 1 -185 -146 -229 19 -51 178 58 -222 113 -20 -29 -113 78 43 -230 -5 12 415 -86 110 -104 -8 38 -6 -157 -134 55 61 130 -358 -182 83 518 53 97 -113 -71 294 453 32 155 -94 -66 10 42 -152 -210 23 98 269 399 -13 338 278 98 326 -153 -135 -358 -95 117 -137 -36 -389 195 -343 -163 -96 -70 -297 406 26 -109 47 152 -379 186 58 32 166 -11 -50 -309 21 -163 -144 179 -328 -144 -135 451 -68 171 50 -11 -156 -179 121 48 -40 -144 -151 -150 185 289 -174 -105 -226 -301 330 180 -256 -49 -130 254 111 -35 -176 -427 -84 209 391 109 11 -152 -45 -40 -98 401 104 -411 114 119 -106 54 -185 -73 -45 -104 -95 242 110 -19 -165 68 143 -331 371 0 347 -4 146 -355 93 190 -80 -88 -329 -217 299 184 -77 -238 219 77 -113 82 -5 -103 182 -17 -77 61 -94 -71 -493 -186 29 -140 205 -89 109 -194 156 -128 59 176 427 15 -7 122 196 155 -60 -121 324 136 253 -46 -2 175 11 61 229 -21 -295 -222 -75 8 -79 121 229 0 -176 343 125 20 112 1 -27 128 -11 201 -126 562 115 186 88 -182 -87 -403 178 -95 85 -254 87 180 -280 207 -346 87 -320 28 -309 77 152 7 -195 -120 -74 81 -197 144 155 -283 -37 174 -177 -137 128 -248 -49 -43 -16 13 -73 298 -16 204 -170 365 12 35 107 -322 6 -183 -68 -24 205 136 -47 -49 -121 94 -26 89 -327 258 120 -8 -175 49 -185 240 -198 -98 39 -65 90 -234 180 166 -502 -337 -128 -36 86 -233 78 -55 -191 297 99 -85 -79 38 -22 64 143 194 65 -225 -14 29 -317 118 -115 -200 -242 -56 -59 213 238 28 189 432 -342 61 210 -162 205 -339 269 -77 33 413 127 37 86 -275 -124 2 -225 288 46 -332 122 153 78 -81 175 359 71 -116 -142 -248 -134 -128 365 -228 139 -268 -24 -15 34 16 303 -167 118 -108 -153 270 26 -115 -123 238 12 91 205 2 139 -176 -95 -151 -161 97 48 -224 -363 203 469 216 -60 -316 -67 -99 218 51 -303 -7 17 470 -239 -334 34 197 -227 -66 218 128 -65 -171 -39 72 -28 -379 -294 -15 68 -150 151 -5 251 -14 204 66 196 94 263 77 -265 295 -80 -94 -169 -283 317 -208 351 -94 262 459 19 -246 -7 311 153 -493 -261 -284 9 65 201 188 35 -306 -108 -59 -118 87 225 -86 -263 -170 53 113 66 273 -26 84 287 69 -105 9 9 -258 142 189 -222 -149 290 11 207 167 82 -303 -55 -19 89 -21 -428 173 -136 -440 -222 106 -327 126 -263 -159 -192 -235 -130 -90 59 4 353 37 128 -306 257 350 90 222 90 -113 -74 235 213 392 51 -85 -11 0 -1 495 164 331 5 -5 -74 -224 -513 -146 -128 2 -215 SQ 20221014T125738.1Z 8322.540024 403 1 14.54 2 62.13 205.10 99.15 330.26 0.00 1 0.00 1 0 33 2.234e-03 2.161e-03 1.887e-03 1.833e-03 1.721094e+03 3.591501e+02 1.305150e+02 1.374283e+02 4.436010e+02 276.66 -2.00 20.00 -2.00 446.02 0.00e+00 -2.000673e-04 2.040836e-04 2.578899e-06 2.190334e-05 2.433335e-04 276.66 -2.00 20.00 -2.00 455.49 0.00e+00 2.946929e-04 1.645016e-05 2.152506e-06 2.070910e-05 2.022171e-05 224.28 -2.00 2.36 -2.00 436.39 0.00e+00 5.113664e+05 2.578921e+05 1.386169e+04 3.277866e+05 3.226983e+05 259.42 -2.00 11.45 -2.00 458.13 0.00e+00 3.733409e-01 5.040620e-02 1.802486e-03 1.727259e-02 6.966739e-02 224.68 -2.00 3.79 -2.00 454.84 0.00e+00 -6.822377e-08 6.445085e-06 3.193844e-07 1.643333e-06 8.568319e-06 276.66 -2.00 20.00 -2.00 456.04 0.00e+00 2.128 0.000 397.00 473.00 4 6.2606e+00 1.9809e-03 5.3348e-03 5.6763e-04 2.2740e-03 6.0084e-02 2.3651e-03 1.1147e-03 3.4045e-04 2.8273e-03 -1.6271e-03 1.3505e-03 1.4832e-04 1.4307e-04 1.6037e-03 -4.4590e-04 4.5379e-04 1.9489e-05 3.6140e-05 5.4291e-04 -2.0612e-04 2.3277e-04 9.3222e-06 2.0097e-05 2.7161e-04 2.3761e-03 1.7868e-02 1.3489e-03 1.0013e-05 6.0262e-05 1.3628e-03 -5.3170e-05 2.0975e-05 3.3510e-07 5.4846e-07 2.4981e-05 6.6137e-06 2.8503e-05 4.2905e-07 6.7905e-07 3.3995e-05 -1.7177e-02 -3.7030e-06 4.6701e-01 1.8849e-01 7.6785e-04 3.7498e-03 2.1099e-01 12 9 9 12 1 1 99.72 18.69 2.05 -0.01718 -0.01891 4 4 1 2 0 2869.460 15.00 18.69 23.90 21.06 21.27 50.1 998.97 -44 -31 -24 150 66 -178 629 -800 555 -14 80 384 -337 345 55 222 212 77 10 171 -41 64 68 -189 -263 61 -71 -109 -275 349 -182 -410 -174 -103 -360 241 -291 -100 -113 28 188 -137 -330 232 -5 -165 369 87 282 82 675 277 652 57 414 -311 -419 82 70 -31 -168 -431 -101 -744 -13 80 110 317 -50 149 -118 225 -414 -67 -46 122 -361 32 -324 -401 -128 -411 181 -218 -65 261 -241 233 -168 -360 -17 315 394 -183 95 -161 -24 -222 90 -9 -26 -62 -200 -198 -535 -137 -81 267 187 209 36 167 176 -31 42 -97 74 -224 -421 -315 30 -316 234 -103 32 -5 232 149 456 -283 -3 270 67 61 447 56 -10 -95 218 -687 36 201 113 613 -353 33 -69 -49 83 -6 -17 57 -90 35 348 24 80 -94 20 -59 345 107 -146 -280 -256 169 317 232 122 228 -34 -96 276 196 69 349 223 -157 118 -195 -18 412 241 48 -74 124 -60 126 3 -258 -36 118 101 217 -236 -203 59 -154 -270 18 -35 -290 87 -97 -220 321 62 516 -106 204 -10 -201 -327 302 -420 53 174 47 113 274 70 202 302 -114 615 71 69 -252 -155 -195 -142 298 -151 6 -114 385 -104 213 -466 -179 61 83 161 -135 -28 60 118 69 301 -574 213 -66 -20 58 53 -131 -4 -235 -151 6 -86 -487 147 -197 58 -159 -150 16 180 -288 -162 247 -18 -73 267 -63 307 -172 -49 340 -86 135 -27 -124 -200 -186 204 133 515 384 -261 -305 -172 116 -166 -226 -179 302 -223 -183 -535 208 -424 68 -32 -180 231 140 201 529 -381 38 212 -122 41 -19 -338 -418 -319 -246 99 -15 -124 -111 4 -437 205 53 -134 -29 -152 266 80 -164 -219 -317 192 124 -248 115 129 -186 -96 167 71 526 -323 11 279 231 -435 30 22 -112 34 -65 -368 -159 -107 140 -183 -232 187 393 -48 83 -260 100 -10 -97 358 -212 -226 -102 34 -107 239 -47 -37 -72 104 -459 -155 -116 193 213 64 236 -37 367 -118 261 -77 -5 280 -16 157 165 -55 -206 -132 115 20 -67 159 -219 -86 22 -88 486 56 243 -54 -77 224 285 14 162 -30 4 -76 -162 313 39 -206 -87 442 -174 402 43 -93 -244 65 -26 338 149 66 166 -319 367 29 -163 -167 -256 278 -146 311 -91 190 -302 199 224 -29 -134 -316 67 210 -296 28 -1 -8 -7 -68 98 89 -108 292 355 -190 -160 -101 -190 12 121 -55 -2 -164 83 83 230 -244 -16 -204 -141 -192 181 282 38 346 -9 11 172 -3 44 266 -98 -152 43 -106 268 23 97 -99 61 8 -16 -16 -126 -116 -59 -86 -177 -238 -127 -179 -426 -73 46 -93 11 -290 -257 45 82 -57 380 -209 -349 323 27 -168 4 -2 -263 125 -44 -35 77 140 -200 -93 108 150 321 354 162 -28 -35 -25 -19 119 52 -142 515 -656 457 -12 67 317 -280 286 46 187 180 65 9 146 -35 54 58 -154 -207 49 -59 -92 -241 308 -161 -353 -147 -82 -278 187 -242 -89 -98 24 166 -118 -278 194 -5 -140 305 71 236 69 558 241 565 49 358 -268 -358 69 58 -26 -148 -395 -94 -695 -12 76 102 299 -47 139 -108 211 -379 -60 -39 102 -289 26 -265 -352 -114 -381 169 -207 -63 242 -230 226 -164 -346 -16 294 368 -174 90 -152 -23 -206 86 -9 -24 -58 -190 -186 -525 -137 -80 254 180 197 34 154 167 -29 40 -92 68 -217 -404 -290 28 -306 232 -104 33 -5 231 146 439 -269 -3 256 63 57 425 52 -9 -89 204 -648 33 184 103 561 -329 31 -68 -49 80 -6 -16 52 -83 32 314 22 78 -95 19 -58 338 106 -143 -269 -254 166 312 223 119 218 -33 -85 237 167 62 322 210 -150 110 -187 -17 381 225 46 -70 118 -58 121 3 -248 -33 109 94 206 -218 -190 55 -146 -252 17 -33 -272 85 -96 -214 297 57 442 -88 171 -8 -188 -304 283 -396 50 160 43 102 253 63 177 266 -102 558 65 62 -215 -129 -151 -105 215 -111 4 -84 289 -77 157 -345 -145 52 76 155 -137 -29 62 116 66 264 -509 191 -60 -19 58 53 -133 -5 -230 -145 5 -73 -403 123 -169 54 -149 -146 16 177 -276 -151 228 -17 -70 263 -63 310 -170 -49 344 -87 136 -27 -121 -194 -186 200 128 490 369 -256 -304 -168 107 -150 -195 -154 269 -201 -172 -514 200 -414 64 -30 -176 225 136 193 515 -364 36 198 -116 38 -19 -346 -416 -329 -249 98 -15 -127 -112 4 -443 205 53 -133 -29 -153 266 80 -161 -212 -306 187 123 -252 117 130 -186 -96 168 73 521 -324 11 273 230 -422 28 20 -102 32 -61 -348 -154 -106 134 -178 -225 181 383 -48 84 -270 105 -11 -100 360 -210 -220 -100 34 -110 247 -48 -38 -72 105 -465 -157 -118 197 220 67 249 -38 381 -125 277 -82 -5 296 -17 164 177 -58 -219 -140 122 22 -71 168 -230 -88 22 -89 480 56 241 -54 -78 229 298 14 170 -32 4 -81 -172 327 41 -220 -92 462 -183 423 46 -100 -265 72 -28 369 164 72 187 -356 406 33 -185 -190 -292 315 -167 356 -105 217 -341 219 242 -32 -149 -357 77 232 -332 32 -2 -9 -8 -77 112 102 -124 335 408 -221 -187 -119 -226 14 147 -67 -2 -199 100 100 276 -294 -19 -248 -171 -234 221 344 47 423 -11 14 210 -3 53 320 -118 -182 51 -126 319 28 116 -122 74 10 -19 -20 -156 -139 -71 -103 -212 -289 -156 -222 -531 -90 58 -114 13 -336 -299 53 99 -70 475 -254 -424 407 33 -209 5 -3 -329 158 -53 -42 93 170 -241 -112 131 182 391 428 202 -34