File name: Pandora162s1_Brussels-Uccle_20240224_L2Fit_fout2c10d20230607p1-8.txt File generation date: 20240410T145541.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Michel Van Roozendael Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora162_OF_v8d20191031.txt Instrument calibration file used: Pandora162s1_CF_v10d20230607.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20240224_L1_smca1c10d20230607p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20240224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration and analysis after repairs + OoB session First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0216 305.1625 305.3033 305.4442 305.5850 305.7258 305.8666 306.0074 306.1482 306.2890 306.4298 306.5705 306.7113 306.8520 306.9927 307.1334 307.2741 307.4148 307.5555 307.6961 307.8368 307.9774 308.1181 308.2587 308.3993 308.5399 308.6804 308.8210 308.9616 309.1021 309.2426 309.3832 309.5237 309.6642 309.8047 309.9451 310.0856 310.2260 310.3665 310.5069 310.6473 310.7877 310.9281 311.0685 311.2089 311.3492 311.4896 311.6299 311.7702 311.9105 312.0508 312.1911 312.3314 312.4717 312.6119 312.7522 312.8924 313.0326 313.1728 313.3130 313.4532 313.5933 313.7335 313.8736 314.0138 314.1539 314.2940 314.4341 314.5742 314.7143 314.8543 314.9944 315.1344 315.2744 315.4145 315.5545 315.6945 315.8344 315.9744 316.1144 316.2543 316.3942 316.5342 316.6741 316.8140 316.9538 317.0937 317.2336 317.3734 317.5133 317.6531 317.7929 317.9327 318.0725 318.2123 318.3520 318.4918 318.6315 318.7713 318.9110 319.0507 319.1904 319.3301 319.4697 319.6094 319.7490 319.8887 320.0283 320.1679 320.3075 320.4471 320.5867 320.7262 320.8658 321.0053 321.1448 321.2843 321.4238 321.5633 321.7028 321.8423 321.9817 322.1212 322.2606 322.4000 322.5394 322.6788 322.8182 322.9576 323.0969 323.2363 323.3756 323.5149 323.6542 323.7935 323.9328 324.0721 324.2114 324.3506 324.4899 324.6291 324.7683 324.9075 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240224T120342.0Z 8820.502570 395 1 49.88 2 60.36 182.23 117.25 0.96 0.00 1 0.00 1 0 25 1.168e-01 1.685e-02 9.716e-02 9.830e-03 4.243284e-01 5.147717e-03 5.393907e-03 -6.000000e+00 6.769376e-02 224.24 -2.00 3.79 -2.00 319.35 0.00e+00 1.431330e-03 1.266853e-03 2.068116e-04 -6.000000e+00 3.176985e-03 268.03 -2.00 20.00 -2.00 318.92 0.00e+00 2.014 0.000 302.00 328.00 3 6.4653e+00 1.4104e-02 3.0821e-02 -6.0000e+00 1.6758e-01 7.9381e-02 1.6352e-02 2.3365e-02 -6.0000e+00 1.8247e-01 -8.2685e-04 1.3225e-02 1.2084e-02 -6.0000e+00 1.0778e-01 -1.1274e-02 7.0764e-03 4.1361e-03 -6.0000e+00 4.6913e-02 6.0955e-05 7.6641e-04 3.0170e-04 4.4956e-05 -6.0000e+00 3.3710e-03 -2.8625e-02 0.0000e+00 12 8 8 10 0 0 99.99 18.42 1.07 -0.02863 -0.02287 148 30 1 8 0 336.870 14.96 18.42 11.01 20.87 21.38 1.8 890.79 900000 900000 20100 900000 -34405 900000 26873 8643 15610 -56400 900000 -16610 900000 1949 44780 13085 49765 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-1391 1398 -890 422 -2155 578 -505 1180 -241 -286 6766 -2318 758 -1990 820 -695 -1233 -1111 249 -670 2136 -1015 -3457 -297 797 2041 -1393 1649 654 1309 253 564 193 -1290 504 -2342 1618 953 2196 -3935 -1907 -2205 -1028 1694 -33 966 -1859 1670 -1344 2053 171 2233 -536 -832 -367 -1764 2570 -536 1937 -1658 1654 1550 1071 2236 -1698 -397 -1222 1010 -977 2139 -3386 2999 -1624 536 -227 -883 -58 SS 20240224T125432.6Z 8820.537877 424 1 48.01 2 61.66 196.49 116.39 14.35 0.00 1 0.00 1 0 17 5.097e-01 3.465e-02 2.422e-01 1.687e-02 4.525583e-01 8.731130e-03 5.850663e-03 -6.000000e+00 2.951581e-01 224.25 -2.00 3.79 -2.00 319.26 0.00e+00 7.705179e-03 2.069974e-03 7.584421e-04 -6.000000e+00 1.313041e-02 268.04 -2.00 20.00 -2.00 318.84 0.00e+00 2.096 0.000 302.00 328.00 3 7.3377e+00 2.3702e-02 3.2556e-02 -6.0000e+00 7.3083e-01 2.8143e-01 2.7220e-02 2.5292e-02 -6.0000e+00 7.9542e-01 -1.7202e-01 2.1260e-02 1.4523e-02 -6.0000e+00 4.6951e-01 7.0987e-02 1.1476e-02 8.8593e-03 -6.0000e+00 2.0081e-01 2.0683e-05 -3.4090e-04 4.9644e-04 8.4682e-05 -6.0000e+00 1.4580e-02 -2.6354e-02 0.0000e+00 12 9 8 11 8 0 98.22 18.42 2.61 -0.02635 -0.02892 12 2 2 8 0 4000.000 14.96 18.42 12.25 20.87 21.38 1.7 898.64 900000 123707 -4937 11104 70246 900000 40531 49901 8852 118484 900000 -87569 191535 46572 480327 14259 100248 -3444 42460 19131 -29374 40011 -17844 17610 6484 8089 27079 61435 -7772 -3817 15523 -1308 -10056 -30193 38834 -31898 9583 2255 -210 -8019 -7958 5933 -9667 11279 -4448 -4256 5013 12889 5898 10446 -10688 5481 9820 3623 -1170 428 6131 -7080 -2318 18736 433 -4297 1876 7773 6312 -2328 -307 -7128 18998 8995 -644 3690 -5425 -552 -5299 -249 54307 -363 1091 -11025 -2466 5853 -3471 1224 378 -3472 -1920 284 2290 2910 -55 -3288 -671 -1443 -2257 2705 -2131 684 -324 -1720 561 -3025 -90 -328 2903 -4041 -1495 -1637 -2843 631 374 4777 486 203 -1632 1839 -1833 -694 1614 -818 -302 3487 1478 -2118 1212 3525 2297 -398 -1084 -1097 -1443 -505 -138 1513 -137 3146 -2080 2042 -207 -1092 -2777 1247 -496 900000 2034 -200 384 1272 900000 879 1038 293 1948 900000 -7949 3150 1667 7899 996 3443 -340 2877 1686 -4194 2929 -2236 1605 676 850 2403 3862 -911 -436 1606 -181 -1699 -6680 4385 -6728 1399 393 -44 -2100 -2331 1624 -3212 3163 -1470 -1424 1552 3714 1832 3166 -4171 1978 3650 1513 -534 196 2693 -3523 -1079 7003 195 -2153 975 4190 3644 -1433 -176 -4245 9109 5243 -455 2652 -4291 -403 -3787 -154 18134 -194 593 -7520 -1776 4367 -3083 1098 359 -3625 -2082 312 2497 3092 -57 -3240 -599 -1250 -2049 2587 -2397 838 -438 -2413 743 -3814 -101 -359 3229 -5084 -1917 -2204 -4082 945 604 7775 822 332 -2555 2618 -2629 -1005 2399 -1309 -492 5422 2267 -3247 1725 4709 2969 -520 -1503 -1660 -2352 -857 -240 2682 -259 6046 -4302 4135 -430 -2249 -5570 2298 -891 SS 20240224T130746.4Z 8820.547065 432 1 50.16 2 62.31 200.11 115.88 17.78 0.00 1 0.00 1 0 25 4.093e-02 6.570e-03 2.150e-02 1.870e-03 4.346277e-01 9.577111e-04 5.543268e-03 -6.000000e+00 2.362355e-02 224.25 -2.00 3.79 -2.00 319.13 0.00e+00 8.415696e-04 2.252692e-04 2.196616e-04 -6.000000e+00 9.936661e-04 268.04 -2.00 20.00 -2.00 318.70 0.00e+00 2.141 0.000 302.00 328.00 3 4.1711e+00 2.6084e-03 3.2052e-02 -6.0000e+00 5.8502e-02 4.8197e-02 3.0068e-03 2.3901e-02 -6.0000e+00 6.3633e-02 9.4922e-03 2.3841e-03 1.2222e-02 -6.0000e+00 3.7671e-02 -1.5035e-02 1.2797e-03 3.8573e-03 -6.0000e+00 1.6101e-02 5.3957e-04 4.9190e-04 5.5440e-05 4.2277e-05 -6.0000e+00 1.1642e-03 -2.7318e-02 0.0000e+00 11 8 0 10 0 0 100.00 18.38 0.18 -0.02732 -0.02362 286 57 4 8 0 174.730 14.97 18.38 12.37 20.87 21.38 1.7 897.87 900000 -6014 -15044 6709 -22294 23517 -16508 5878 -4217 -4329 14461 3604 8270 -4472 2757 -2797 2917 -2920 1711 -272 -455 2088 -2201 1681 -5059 425 -6283 -776 -4357 2337 -2371 2598 1165 -1315 -549 -3885 229 -2569 971 -1740 -1722 -2152 -677 -1086 -1223 495 -865 -496 150 74 703 1016 28 926 -76 814 855 -440 559 -229 1275 1170 1976 1421 541 239 549 400 1365 2028 -717 146 -669 261 328 684 2311 264 773 217 -582 -866 -1449 -1938 -645 -1097 -317 -464 -455 73 18 1124 480 1502 1325 603 293 560 74 -941 -316 -415 235 943 69 -1627 -766 -1024 -543 105 -188 -207 -611 63 -15 816 1065 1018 397 -36 -560 -407 56 -76 444 416 219 1244 1388 136 -12 -237 -29 95 118 -11 -593 289 -136 -241 -174 -83 -124 900000 -155 -455 167 -674 445 -462 148 -131 -147 431 124 307 -221 152 -188 205 -232 139 -24 -41 185 -207 161 -553 47 -757 -87 -483 243 -276 324 164 -205 -84 -595 35 -461 200 -435 -487 -657 -213 -352 -399 160 -285 -163 49 25 248 388 11 405 -35 387 417 -219 272 -110 611 593 1082 850 342 149 325 232 817 1331 -530 113 -529 200 237 453 1385 154 460 144 -437 -724 -1315 -1858 -641 -1156 -348 -526 -520 82 20 1115 450 1352 1239 617 333 696 99 -1296 -419 -515 271 1061 81 -2060 -1000 -1394 -771 158 -301 -344 -1020 101 -23 1178 1503 1466 599 -58 -907 -653 87 -115 650 590 299 1669 1950 207 -20 -400 -51 168 218 -22 -1174 578 -273 -480 -337 -155 -224 SS 20240224T141034.2Z 8820.590673 469 1 12.98 2 67.00 216.46 111.95 33.42 0.00 1 0.00 1 0 25 4.766e-02 6.857e-03 1.325e-02 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