File name: Pandora162s1_Brussels-Uccle_20240427_L2Fit_fout2c13d20231120p1-8.txt File generation date: 20240912T125614.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Michel Van Roozendael Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora162_OF_v8d20191031.txt Instrument calibration file used: Pandora162s1_CF_v13d20231120.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20240427_L1_smca1c13d20231120p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20240427 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 for fieldcal First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0129 305.1537 305.2944 305.4352 305.5759 305.7166 305.8573 305.9980 306.1387 306.2793 306.4200 306.5606 306.7012 306.8419 306.9825 307.1231 307.2637 307.4042 307.5448 307.6853 307.8259 307.9664 308.1069 308.2474 308.3879 308.5284 308.6689 308.8093 308.9498 309.0902 309.2306 309.3710 309.5114 309.6518 309.7922 309.9326 310.0729 310.2133 310.3536 310.4939 310.6342 310.7745 310.9148 311.0551 311.1953 311.3356 311.4758 311.6161 311.7563 311.8965 312.0367 312.1769 312.3170 312.4572 312.5973 312.7375 312.8776 313.0177 313.1578 313.2979 313.4380 313.5780 313.7181 313.8581 313.9982 314.1382 314.2782 314.4182 314.5582 314.6982 314.8381 314.9781 315.1180 315.2579 315.3978 315.5378 315.6776 315.8175 315.9574 316.0973 316.2371 316.3769 316.5168 316.6566 316.7964 316.9362 317.0759 317.2157 317.3555 317.4952 317.6349 317.7746 317.9144 318.0541 318.1937 318.3334 318.4731 318.6127 318.7524 318.8920 319.0316 319.1712 319.3108 319.4504 319.5899 319.7295 319.8690 320.0086 320.1481 320.2876 320.4271 320.5666 320.7061 320.8455 320.9850 321.1244 321.2638 321.4033 321.5427 321.6821 321.8214 321.9608 322.1002 322.2395 322.3788 322.5182 322.6575 322.7968 322.9361 323.0753 323.2146 323.3539 323.4931 323.6323 323.7715 323.9108 324.0499 324.1891 324.3283 324.4675 324.6066 324.7457 324.8849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240427T065427.3Z 8883.287816 239 1 5.86 2 67.49 95.36 100.22 237.87 0.00 1 0.00 1 0 25 1.716e-01 9.331e-03 1.400e-01 5.795e-03 5.107921e-01 2.983102e-03 6.407185e-03 -6.000000e+00 9.859445e-02 229.12 -2.00 3.79 -2.00 319.53 0.00e+00 1.809161e-03 8.173817e-04 5.257507e-04 -6.000000e+00 4.163611e-03 274.87 -2.00 20.00 -2.00 319.00 0.00e+00 2.590 0.000 302.00 328.00 3 3.9517e+00 8.3568e-03 3.8923e-02 -6.0000e+00 2.4648e-01 2.9272e-02 9.8619e-03 2.8786e-02 -6.0000e+00 2.6701e-01 -1.8840e-02 8.4192e-03 1.4820e-02 -6.0000e+00 1.5814e-01 1.2657e-03 4.4547e-03 4.8898e-03 -6.0000e+00 6.7282e-02 3.9504e-04 -5.8553e-05 1.5992e-04 4.8940e-05 -6.0000e+00 4.5396e-03 -1.0257e-03 0.0000e+00 12 9 9 12 1 1 98.48 18.49 0.43 -0.00103 -0.00147 4 8 4 8 0 1111.810 15.00 18.49 15.30 20.96 21.48 1.6 919.35 -52328 64506 -55182 84274 -60637 -56008 -62353 4495 -37779 -49041 -18421 -40889 41461 -39553 31414 -12674 -740 -1150 2304 3915 3634 -4468 -12006 5804 -21966 1458 -9387 -401 -10629 -17121 -3947 1680 11956 -7065 10930 -4147 13667 -2859 -4071 -1914 7320 -394 835 -229 -1528 5538 -1740 125 -3470 1176 -1332 1044 -521 -238 2608 -79 3186 533 2575 -1657 3358 256 1517 2945 761 917 310 1004 1671 1782 -55 829 -444 371 -807 272 78 -2012 -1066 -2609 233 -669 -731 -3041 -1467 -1261 -105 541 967 817 282 1484 -80 -460 -435 842 -657 685 1053 -680 980 -1478 -909 -1039 319 -1444 -677 -1462 -832 22 343 886 -186 383 -757 355 233 455 411 418 138 -449 645 743 891 207 -490 859 779 368 388 -218 -562 147 -562 307 -881 456 90 -63 249 -170 -670 -914 434 -1285 514 -1369 -1145 -1424 61 -877 -1391 -405 -1173 639 -1637 810 -591 -35 -58 122 217 209 -280 -822 362 -1924 109 -801 -31 -858 -1489 -337 158 1162 -902 1158 -485 1427 -402 -696 -384 1532 -95 209 -59 -405 1396 -475 34 -989 332 -412 347 -190 -93 1046 -33 1351 233 1088 -712 1398 116 746 1574 438 518 169 539 933 1109 -38 602 -329 266 -550 169 45 -1135 -620 -1722 170 -544 -644 -2853 -1419 -1286 -111 586 1050 875 289 1425 -74 -415 -411 862 -749 848 1399 -932 1287 -1849 -1058 -1187 377 -1819 -876 -1976 -1173 33 542 1455 -309 618 -1181 525 340 676 634 672 225 -727 1013 1142 1325 300 -693 1191 1140 580 649 -381 -1008 269 -1076 607 -1793 931 186 -128 491 -325 -1246 SS 20240427T070533.2Z 8883.295523 246 1 5.34 2 65.74 97.59 101.68 239.78 0.00 1 0.00 1 0 17 4.781e-02 6.024e-03 1.794e-02 1.551e-03 4.802234e-01 7.918197e-04 6.092469e-03 -6.000000e+00 2.746945e-02 229.12 -2.00 3.79 -2.00 318.88 0.00e+00 8.842734e-04 1.775007e-04 3.315956e-04 -6.000000e+00 1.160125e-03 274.87 -2.00 20.00 -2.00 318.33 0.00e+00 2.417 0.000 302.00 328.00 3 1.8571e+00 2.1630e-03 3.6440e-02 -6.0000e+00 6.8671e-02 2.2561e-02 2.4856e-03 2.6933e-02 -6.0000e+00 7.4393e-02 -1.1860e-02 1.9123e-03 1.3515e-02 -6.0000e+00 4.4061e-02 -2.5540e-03 1.0247e-03 4.0148e-03 -6.0000e+00 1.8744e-02 3.9488e-03 -1.8760e-04 4.2342e-05 4.0161e-05 -6.0000e+00 1.2649e-03 -4.2396e-04 0.0000e+00 12 1 1 12 1 1 99.44 18.49 0.28 -0.00042 -0.00183 39 79 2 8 0 126.740 15.00 18.49 15.54 20.96 21.48 1.6 921.66 -16147 -16826 -9633 -16557 -27241 -16928 -19874 -4449 -10915 -3172 -13507 -10641 -11647 -1490 -4713 71 -1647 -2259 -1560 -1177 329 -588 280 542 -107 -591 -3276 -1562 -4576 -2625 -2009 -246 682 2176 -3842 -4172 -2926 -2595 -1136 118 -708 -1632 -1146 -401 -326 -478 323 130 -378 -217 481 1000 744 1508 554 1116 1424 629 -86 269 959 1243 1928 2522 1751 19 395 -933 259 1188 531 724 223 509 91 -38 -436 -947 -852 -99 -851 -1209 -1369 -2086 -1085 -1044 -390 -153 285 461 326 801 88 252 519 194 -17 750 651 -133 -189 -786 -926 -326 51 -1279 -957 -802 -714 -114 278 328 170 467 1 178 441 303 67 330 -50 -144 351 381 418 839 -82 495 938 165 199 -147 -492 -228 -5 37 -459 398 54 -225 -9 -207 -443 -357 -443 -256 -471 -783 -412 -523 -114 -342 -101 -495 -396 -513 -73 -264 4 -118 -176 -130 -103 29 -53 26 53 -11 -68 -397 -181 -518 -291 -245 -34 106 366 -671 -695 -510 -522 -274 31 -216 -542 -397 -142 -116 -172 116 47 -139 -82 194 408 331 716 282 585 769 345 -47 142 506 697 1108 1602 1191 13 250 -589 170 877 414 600 188 413 69 -28 -290 -602 -563 -74 -694 -1053 -1316 -2139 -1098 -1133 -445 -171 320 535 355 802 87 242 523 208 -19 970 881 -186 -252 -1018 -1090 -371 61 -1678 -1239 -1095 -984 -170 429 537 279 735 1 258 619 438 103 511 -80 -225 554 581 608 1222 -114 679 1374 256 320 -251 -833 -401 -8 70 -861 754 104 -426 -16 -369 -791 SS 20240427T071511.8Z 8883.302220 251 1 0.59 2 64.23 99.57 102.96 241.42 0.00 1 0.00 1 0 17 9.519e-02 1.045e-02 7.048e-02 7.996e-03 4.641954e-01 4.080354e-03 5.925028e-03 -6.000000e+00 5.470392e-02 229.12 -2.00 3.79 -2.00 318.37 0.00e+00 5.641556e-04 7.806761e-04 1.676120e-04 -6.000000e+00 2.309856e-03 274.87 -2.00 20.00 -2.00 317.81 0.00e+00 2.286 0.000 302.00 328.00 3 1.8283e+00 1.1005e-02 3.4857e-02 -6.0000e+00 1.3676e-01 4.8917e-02 1.2469e-02 2.5926e-02 -6.0000e+00 1.4814e-01 -2.8390e-02 8.7323e-03 1.2860e-02 -6.0000e+00 8.7739e-02 5.4753e-03 4.6387e-03 3.7153e-03 -6.0000e+00 3.7335e-02 4.6411e-03 -2.3673e-04 2.1777e-04 3.8132e-05 -6.0000e+00 2.5183e-03 -1.9277e-03 0.0000e+00 12 9 9 12 1 1 999.00 18.50 0.31 -0.00193 -0.00371 1 71 4 8 0 140.910 15.00 18.50 16.14 20.96 21.48 1.6 926.71 -14972 -6614 -10706 -25528 11404 -32552 70550 -43414 14094 -31878 -20810 -18513 -1833 -5565 -14227 10251 -7989 15419 -5013 12988 -4310 706 -7836 -1177 4351 -2562 1042 -4460 6197 2528 7147 1387 1763 971 -2742 -903 -1621 -8 -385 2420 -1479 2843 -2417 -85 -3124 1974 -1158 -2987 2747 -801 1249 2229 2034 -180 3415 -222 1017 1783 -1046 -435 -719 1461 -1387 2959 1266 701 -883 -456 412 1305 846 1729 739 -1393 2629 -265 9 -992 -1506 -840 -1753 -890 -1278 -2472 -1896 -993 -2147 554 613 1639 142 1302 352 1093 420 -328 -712 660 741 -1054 42 -392 -1250 388 -579 -1664 -135 -29 -1139 737 594 553 -557 -226 593 883 -57 -89 -107 1278 -718 22 -444 548 -192 1117 -464 1113 1549 465 230 -398 -388 146 -441 -85 681 11 540 -496 -261 -189 -1055 -515 -246 -446 -1217 352 -1428 1227 -2466 535 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