File name: Pandora162s1_Brussels-Uccle_20240430_L2Fit_fout2c10d20230607p1-8.txt File generation date: 20240430T234609.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Michel Van Roozendael Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora162_OF_v8d20191031.txt Instrument calibration file used: Pandora162s1_CF_v10d20230607.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20240430_L1_smca1c10d20230607p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20240430 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration and analysis after repairs + OoB session First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0216 305.1625 305.3033 305.4442 305.5850 305.7258 305.8666 306.0074 306.1482 306.2890 306.4298 306.5705 306.7113 306.8520 306.9927 307.1334 307.2741 307.4148 307.5555 307.6961 307.8368 307.9774 308.1181 308.2587 308.3993 308.5399 308.6804 308.8210 308.9616 309.1021 309.2426 309.3832 309.5237 309.6642 309.8047 309.9451 310.0856 310.2260 310.3665 310.5069 310.6473 310.7877 310.9281 311.0685 311.2089 311.3492 311.4896 311.6299 311.7702 311.9105 312.0508 312.1911 312.3314 312.4717 312.6119 312.7522 312.8924 313.0326 313.1728 313.3130 313.4532 313.5933 313.7335 313.8736 314.0138 314.1539 314.2940 314.4341 314.5742 314.7143 314.8543 314.9944 315.1344 315.2744 315.4145 315.5545 315.6945 315.8344 315.9744 316.1144 316.2543 316.3942 316.5342 316.6741 316.8140 316.9538 317.0937 317.2336 317.3734 317.5133 317.6531 317.7929 317.9327 318.0725 318.2123 318.3520 318.4918 318.6315 318.7713 318.9110 319.0507 319.1904 319.3301 319.4697 319.6094 319.7490 319.8887 320.0283 320.1679 320.3075 320.4471 320.5867 320.7262 320.8658 321.0053 321.1448 321.2843 321.4238 321.5633 321.7028 321.8423 321.9817 322.1212 322.2606 322.4000 322.5394 322.6788 322.8182 322.9576 323.0969 323.2363 323.3756 323.5149 323.6542 323.7935 323.9328 324.0721 324.2114 324.3506 324.4899 324.6291 324.7683 324.9075 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given 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3279 1127 3342 3243 3407 1287 1843 3327 1307 2026 1720 3005 2616 4705 2184 2369 4278 4701 1830 3939 1525 3043 2148 1904 5045 -404 1676 -2385 -11335 882 586 617 1258 2582 -2318 -156 -717 144 2235 732 -1123 928 -1145 -321 -175 -777 -1198 -1953 170 -2346 -649 -256 232 -1817 -2222 -2332 -3213 -1206 -1704 -531 -1070 -1690 -872 1077 1231 -1195 1025 -274 1345 1233 3152 1363 -24 3526 816 4611 1166 -316 -199 -49 743 2288 -772 2376 -1626 2557 1391 -5719 -1750 489 -1692 SS 20240430T053723.0Z 8886.234294 151 1 49.80 2 78.86 79.98 78.56 189.13 0.00 1 0.00 1 0 25 4.834e-01 2.168e-02 3.182e-01 9.500e-03 8.376803e-01 5.575042e-03 9.936717e-03 -6.000000e+00 2.921124e-01 229.44 -2.00 3.79 -2.00 321.59 0.00e+00 1.365430e-02 2.739877e-03 3.619290e-03 -6.000000e+00 1.463965e-02 275.22 -2.00 20.00 -2.00 321.16 0.00e+00 4.995 0.003 302.00 328.00 3 3.6220e+00 1.8959e-02 7.6858e-02 -6.0000e+00 7.3332e-01 4.5002e-01 2.7386e-02 6.7627e-02 -6.0000e+00 7.9677e-01 -4.5789e-01 3.0031e-02 2.8126e-02 -6.0000e+00 4.6559e-01 1.7165e-01 1.4117e-02 2.0376e-02 -6.0000e+00 1.9630e-01 3.5317e-05 -3.7149e-04 2.6901e-04 1.7978e-04 -6.0000e+00 1.4351e-02 -1.8160e-02 0.0000e+00 12 8 8 10 0 0 99.94 18.65 0.41 -0.01816 -0.02095 26 5 1 8 0 1914.930 15.00 18.65 18.52 21.06 21.69 1.5 941.56 -159950 -309622 900000 900000 -52822 900000 900000 900000 -154591 900000 900000 -202535 900000 -9869 900000 900000 900000 -11073 -52447 -89205 -124219 106154 -44276 92439 -100807 14626 76831 900000 -77054 -42578 7895 20902 -9126 46437 41433 -67556 -6287 -36314 34035 -20356 50064 -15931 -992 16996 37437 10121 32536 33173 -2736 37676 28202 28045 12252 28065 1331 21835 17025 -3872 11115 39425 -11757 2144 23567 6341 12089 4691 15756 -3232 22557 6738 -2926 7208 7526 6276 -4497 9090 25048 -663 3322 -3824 -23728 4821 -1142 733 1566 1597 -3074 -899 823 -3121 1627 8 157 1214 -1126 549 -346 595 348 -1006 750 453 520 808 957 -2774 -1847 -5055 -1136 -524 -563 -720 -411 -333 -1350 1259 -1194 945 670 485 -323 970 800 50 -188 1532 1996 2287 2320 -762 1734 -227 615 589 -386 99 -766 669 -347 -899 -892 420 -295 -1478 -9083 900000 900000 -488 900000 900000 900000 -1429 900000 900000 -2945 900000 -91 900000 900000 900000 -110 -859 -2195 -4353 981 -719 854 -2961 148 710 900000 -1929 -854 121 357 -249 839 789 -3463 -188 -1622 926 -1088 1565 -1006 -58 882 1655 600 1634 1752 -216 2205 2000 2238 1257 2693 175 2450 2040 -563 1365 3625 -1784 309 3174 1157 2307 988 2993 -759 4478 1763 -934 2211 2303 1844 -1341 2144 4693 -159 853 -1249 -11137 2002 -560 378 845 911 -1923 -568 516 -1982 935 4 83 648 -680 379 -282 556 364 -1105 784 434 448 658 807 -2558 -1771 -5322 -1256 -647 -779 -1085 -638 -515 -2037 1790 -1721 1378 1025 770 -514 1471 1162 71 -257 2008 2536 2947 3306 -1268 3134 -451 1282 1294 -904 241 -1933 1685 -882 -2237 -2104 921 -620 SS 20240430T054345.3Z 8886.238719 154 1 49.83 2 77.86 81.18 78.71 190.53 0.00 1 0.00 1 0 25 4.848e-01 8.643e-03 2.255e-01 3.384e-03 7.866867e-01 1.899204e-03 9.336717e-03 -6.000000e+00 2.863723e-01 229.44 -2.00 3.79 -2.00 321.21 0.00e+00 6.931571e-03 8.698806e-04 1.608382e-03 -6.000000e+00 1.341774e-02 275.22 -2.00 20.00 -2.00 320.76 0.00e+00 4.616 0.002 302.00 328.00 3 2.6470e+00 6.1785e-03 6.6447e-02 -6.0000e+00 7.1585e-01 1.4778e-01 8.9818e-03 5.0682e-02 -6.0000e+00 7.7548e-01 -1.2044e-01 1.0148e-02 2.6858e-02 -6.0000e+00 4.5798e-01 3.2084e-02 4.8345e-03 1.4384e-02 -6.0000e+00 1.9597e-01 1.5667e-04 8.6392e-05 9.2935e-05 1.2564e-04 -6.0000e+00 1.4001e-02 -2.3589e-02 0.0000e+00 11 8 0 10 0 0 99.53 18.65 0.31 -0.02359 -0.02294 64 13 1 8 0 778.530 15.00 18.65 18.61 21.06 21.69 1.5 941.76 900000 -242917 -239145 900000 -225629 900000 -205226 -117118 -78241 -96688 900000 -173291 900000 -67859 24879 -11190 30984 -35096 -33093 -79068 -77718 9884 -8638 -54891 -46311 -38628 -39501 18569 -66831 -6500 -34326 -10014 -10015 2507 21081 -46642 11207 -20577 3287 1015 -3848 -11865 53 693 -724 5041 -370 10520 -5678 -40 3159 6035 10460 4078 3232 1348 859 20 47 451 3558 2777 6476 1414 3871 3488 1679 -1467 2514 2586 -120 1883 553 1658 767 -841 6410 -1022 -118 -390 -7213 125 -1136 -1315 -191 -259 -608 303 -19 54 573 1834 91 162 -19 -71 108 1342 82 -236 -112 -492 348 639 301 -1938 -1079 -1417 -927 -120 -485 -208 -411 -120 -294 892 499 809 199 -264 -379 -9 496 291 48 275 82 1153 1421 240 167 -197 166 263 -288 -167 -542 452 -29 -556 -39 160 -98 900000 -2213 -2418 900000 -2013 900000 -1513 -407 -258 -344 900000 -1586 900000 -392 82 -64 141 -348 -361 -1445 -1470 82 -88 -938 -789 -652 -700 191 -1562 -93 -772 -223 -269 68 487 -1999 295 -838 129 49 -225 -827 4 48 -53 360 -29 781 -525 -4 324 680 1263 573 494 220 146 3 8 75 581 493 1261 331 973 903 442 -410 732 853 -45 742 222 634 274 -276 1822 -310 -39 -151 -3498 65 -665 -824 -125 -180 -444 226 -14 40 401 1199 58 105 -14 -57 100 1394 95 -282 -131 -530 340 597 292 -2018 -1165 -1620 -1135 -161 -717 -328 -669 -193 -460 1335 743 1231 316 -435 -627 -15 763 436 70 390 114 1599 2132 405 307 -387 340 564 -651 -393 -1306 1093 -69 -1333 -89 348 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