File name: Pandora162s1_Brussels-Uccle_20240909_L2Fit_fout2c10d20230607p1-8.txt File generation date: 20240909T234153.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Michel Van Roozendael Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora162_OF_v8d20191031.txt Instrument calibration file used: Pandora162s1_CF_v10d20230607.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20240909_L1_smca1c10d20230607p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20240909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full lab calibration and analysis after repairs + OoB session First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0216 305.1625 305.3033 305.4442 305.5850 305.7258 305.8666 306.0074 306.1482 306.2890 306.4298 306.5705 306.7113 306.8520 306.9927 307.1334 307.2741 307.4148 307.5555 307.6961 307.8368 307.9774 308.1181 308.2587 308.3993 308.5399 308.6804 308.8210 308.9616 309.1021 309.2426 309.3832 309.5237 309.6642 309.8047 309.9451 310.0856 310.2260 310.3665 310.5069 310.6473 310.7877 310.9281 311.0685 311.2089 311.3492 311.4896 311.6299 311.7702 311.9105 312.0508 312.1911 312.3314 312.4717 312.6119 312.7522 312.8924 313.0326 313.1728 313.3130 313.4532 313.5933 313.7335 313.8736 314.0138 314.1539 314.2940 314.4341 314.5742 314.7143 314.8543 314.9944 315.1344 315.2744 315.4145 315.5545 315.6945 315.8344 315.9744 316.1144 316.2543 316.3942 316.5342 316.6741 316.8140 316.9538 317.0937 317.2336 317.3734 317.5133 317.6531 317.7929 317.9327 318.0725 318.2123 318.3520 318.4918 318.6315 318.7713 318.9110 319.0507 319.1904 319.3301 319.4697 319.6094 319.7490 319.8887 320.0283 320.1679 320.3075 320.4471 320.5867 320.7262 320.8658 321.0053 321.1448 321.2843 321.4238 321.5633 321.7028 321.8423 321.9817 322.1212 322.2606 322.4000 322.5394 322.6788 322.8182 322.9576 323.0969 323.2363 323.3756 323.5149 323.6542 323.7935 323.9328 324.0721 324.2114 324.3506 324.4899 324.6291 324.7683 324.9075 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240909T102117.4Z 9018.431452 203 1 45.26 2 48.62 153.52 105.33 109.22 0.00 1 0.00 1 0 17 1.191e-02 6.982e-03 5.350e-03 2.261e-03 2.256266e-01 1.173919e-03 2.948212e-03 -6.000000e+00 7.011037e-03 229.37 -2.00 3.79 -2.00 316.65 0.00e+00 2.734645e-04 1.421249e-04 4.885832e-05 -6.000000e+00 3.051022e-04 281.03 -2.00 20.00 -2.00 315.98 0.00e+00 1.510 0.000 302.00 328.00 3 5.6060e+00 3.0727e-03 1.9651e-02 -6.0000e+00 1.7493e-02 4.1427e-02 3.4271e-03 1.2622e-02 -6.0000e+00 1.8918e-02 -3.9266e-04 2.0088e-03 6.1919e-03 -6.0000e+00 1.1240e-02 -5.0324e-03 9.5738e-04 1.7455e-03 -6.0000e+00 4.8015e-03 3.3248e-04 5.5166e-04 6.7360e-05 2.1242e-05 -6.0000e+00 3.3955e-04 -2.2960e-02 0.0000e+00 11 8 0 10 0 0 99.99 18.76 0.44 -0.02296 -0.01881 36 7 2 8 0 1256.920 15.00 18.76 23.40 21.06 21.38 1.3 975.00 900000 -3571 -2254 732 -3085 1928 -3685 -223 -546 -3955 399 -2311 3581 -2267 994 -32 -301 1773 -376 -347 0 1279 1167 1536 -493 173 23 -736 -816 2622 2296 1962 1857 148 -2263 -3345 -606 684 -281 -151 -1954 -1188 -504 -766 -429 -504 -1126 -835 196 610 230 596 593 842 487 1160 1789 43 342 774 927 1296 1976 942 -221 -690 333 224 1637 1356 -974 173 -32 236 -77 -57 472 -353 425 -539 -1536 -1548 -2015 -1572 -667 -335 -519 25 7 4 238 560 64 1202 1066 488 -45 877 -82 -583 -567 -641 -196 305 -81 -1490 -535 -959 -618 53 357 -62 -167 293 89 409 514 254 777 331 -562 -20 232 214 102 675 348 1412 1269 393 260 -89 -91 76 77 -98 -361 474 -296 -408 -115 -290 -747 900000 -603 -391 120 -478 264 -539 -34 -94 -751 73 -436 682 -510 243 -9 -86 514 -115 -109 0 407 373 507 -174 63 8 -264 -274 822 733 666 672 57 -862 -1232 -227 282 -135 -84 -1204 -765 -331 -511 -285 -335 -744 -539 122 377 146 396 413 609 364 879 1367 33 263 588 712 1035 1668 843 -204 -612 274 177 1298 1168 -925 171 -32 232 -73 -51 383 -271 323 -442 -1390 -1513 -2096 -1693 -744 -392 -637 32 9 6 286 630 67 1197 1074 523 -52 1086 -108 -777 -733 -785 -228 353 -98 -1925 -709 -1316 -872 77 540 -95 -255 427 123 534 655 331 1049 472 -830 -30 337 305 140 893 445 1760 1626 530 364 -128 -132 113 118 -156 -590 785 -496 -681 -188 -463 -1175 SS 20240909T110437.5Z 9018.461545 227 1 2.54 2 46.36 167.87 99.34 116.89 0.00 1 0.00 1 0 17 8.725e-03 7.269e-03 1.236e-03 7.651e-04 2.052296e-01 4.023032e-04 2.712455e-03 -6.000000e+00 5.134791e-03 229.37 -2.00 3.79 -2.00 315.43 0.00e+00 1.646661e-04 3.702436e-05 2.709333e-05 -6.000000e+00 2.234234e-04 281.02 -2.00 20.00 -2.00 314.83 0.00e+00 1.447 0.000 302.00 328.00 3 1.1235e+00 1.0379e-03 1.8409e-02 -6.0000e+00 1.2811e-02 5.8531e-03 1.1505e-03 1.1475e-02 -6.0000e+00 1.3855e-02 -9.6779e-04 6.5976e-04 5.6284e-03 -6.0000e+00 8.2318e-03 -3.5712e-03 2.9722e-04 1.5782e-03 -6.0000e+00 3.5170e-03 3.3077e-02 5.5522e-04 2.2509e-05 2.1114e-05 -6.0000e+00 2.4865e-04 -2.3893e-02 0.0000e+00 12 9 1 12 1 1 99.90 18.77 0.28 -0.02389 -0.01972 71 285 2 8 0 35.170 15.00 18.77 23.00 21.17 21.38 1.2 968.06 900000 -1613 -1610 -2504 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-1331 -2280 -2278 -1066 -1223 -744 -577 -218 -172 -48 641 311 1291 1587 727 405 723 -198 -1169 -610 -627 80 729 123 -1787 -1014 -957 -779 293 -133 -81 -311 87 192 888 1400 929 729 304 -736 -420 -35 171 546 1007 405 1921 1910 447 388 -286 64 264 477 -220 -878 349 -533 -670 -495 -695 -826 SS 20240909T110917.4Z 9018.464785 229 1 53.08 2 46.21 169.46 98.72 117.73 0.00 1 0.00 1 0 25 8.738e-03 7.266e-03 2.010e-04 1.254e-04 2.048072e-01 6.578980e-05 2.704020e-03 -6.000000e+00 5.142662e-03 229.37 -2.00 3.79 -2.00 315.40 0.00e+00 1.427387e-04 6.024709e-06 2.668089e-05 -6.000000e+00 2.237630e-04 281.02 -2.00 20.00 -2.00 314.79 0.00e+00 1.443 0.000 302.00 328.00 3 5.1304e-01 1.6967e-04 1.8358e-02 -6.0000e+00 1.2831e-02 1.6479e-03 1.8804e-04 1.1443e-02 -6.0000e+00 1.3876e-02 -1.1235e-03 1.0788e-04 5.6125e-03 -6.0000e+00 8.2444e-03 -3.1873e-03 4.8647e-05 1.5695e-03 -6.0000e+00 3.5224e-03 6.1290e-02 5.7542e-04 3.6802e-06 2.1462e-05 -6.0000e+00 2.4903e-04 -2.3980e-02 0.0000e+00 11 8 0 10 0 0 99.97 18.78 0.32 -0.02398 -0.01966 2555 512 2 8 0 19.540 15.00 18.78 23.07 21.06 21.38 1.3 972.54 900000 -1969 -1483 -2607 -2285 -276 -18 536 199 -583 -1557 -126 511 -370 -13 -253 -634 614 591 906 676 235 1578 1186 618 462 -53 -355 421 1397 1989 1369 1675 -225 -2107 -326 -461 -743 -368 -889 -1503 -1117 -726 -901 -637 -294 -801 -444 -366 102 1084 671 540 878 501 787 972 345 582 858 1118 1372 1185 921 -117 -778 477 284 1242 1054 -428 -169 -307 37 4 -119 349 214 717 136 -1086 -1276 -2121 -1913 -927 -1060 -721 -508 -231 -134 -76 536 406 1347 1516 621 376 623 -90 -891 -456 -468 -4 752 78 -1415 -749 -775 -526 221 -30 -141 -272 109 169 710 1112 746 603 180 -551 -418 3 101 347 784 291 1652 1474 446 196 -173 -32 172 281 -166 -468 175 -314 -561 -270 -479 -466 900000 -560 -436 -749 -637 -69 -5 147 56 -178 -485 -38 164 -134 -5 -106 -280 275 255 401 308 107 713 557 307 239 -28 -180 195 654 935 640 834 -119 -1100 -159 -234 -402 -221 -597 -1075 -842 -562 -709 -499 -229 -615 -329 -278 76 815 509 434 700 415 664 832 298 496 720 949 1224 1088 863 -113 -748 434 245 1076 962 -420 -176 -312 38 4 -113 309 184 607 119 -1030 -1281 -2217 -2098 -1022 -1256 -869 -638 -282 -167 -89 595 427 1369 1553 662 425 744 -112 -1136 -576 -571 -5 882 94 -1790 -949 -1026 -698 307 -43 -205 -387 150 222 892 1401 928 798 247 -770 -587 5 139 453 1006 370 2019 1867 584 261 -239 -45 237 406 -247 -697 266 -487 -863 -402 -717 -677 SS 20240909T111554.5Z 9018.469381 232 1 53.16 2 46.05 171.74 97.84 118.92 0.00 1 0.00 1 0 25 8.708e-03 7.266e-03 2.039e-04 1.267e-04 2.035989e-01 6.652285e-05 2.690933e-03 -6.000000e+00 5.125175e-03 229.37 -2.00 3.79 -2.00 315.42 0.00e+00 1.453513e-04 6.106676e-06 2.700556e-05 -6.000000e+00 2.230011e-04 281.02 -2.00 20.00 -2.00 314.81 0.00e+00 1.439 0.000 302.00 328.00 3 5.3577e-01 1.7159e-04 1.8287e-02 -6.0000e+00 1.2787e-02 2.0393e-03 1.9026e-04 1.1383e-02 -6.0000e+00 1.3829e-02 -1.0518e-03 1.0907e-04 5.5830e-03 -6.0000e+00 8.2163e-03 -3.3258e-03 4.9103e-05 1.5645e-03 -6.0000e+00 3.5105e-03 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