File name: Pandora162s1_Brussels-Uccle_20250507_L2Fit_fwvt1c13d20231120p1-8.txt
File generation date: 20250507T234452.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c13p1-8
Local principal investigator: Michel Van Roozendael
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 162
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora162_OF_v8d20191031.txt
Instrument calibration file used: Pandora162s1_CF_v13d20231120.txt
Level 1 file used: Pandora162s1_Brussels-Uccle_20250507_L1_smca1c13d20231120p1-8.txt
Full location name: Uccle (BIRA-IASB, KMI-IRM)
Short location name: Brussels-Uccle
Country of location: Belgium
Location latitude [deg]: 50.7980
Location longitude [deg]: 4.3580
Location altitude [m]: 107
Local noon date: 20250507
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Based on session 12 for fieldcal
First and last pixel inside fitting window: 1648 1798
Nominal wavelengths inside fitting window [nm]: 492.0019 492.1226 492.2433 492.3640 492.4847 492.6053 492.7260 492.8466 492.9672 493.0878 493.2084 493.3289 493.4495 493.5700 493.6905 493.8110 493.9314 494.0519 494.1723 494.2927 494.4131 494.5335 494.6539 494.7742 494.8946 495.0149 495.1352 495.2555 495.3758 495.4960 495.6162 495.7365 495.8567 495.9768 496.0970 496.2172 496.3373 496.4574 496.5775 496.6976 496.8177 496.9377 497.0577 497.1778 497.2978 497.4177 497.5377 497.6577 497.7776 497.8975 498.0174 498.1373 498.2572 498.3770 498.4968 498.6166 498.7364 498.8562 498.9760 499.0957 499.2155 499.3352 499.4549 499.5746 499.6942 499.8139 499.9335 500.0531 500.1727 500.2923 500.4118 500.5314 500.6509 500.7704 500.8899 501.0094 501.1289 501.2483 501.3677 501.4871 501.6065 501.7259 501.8453 501.9646 502.0839 502.2032 502.3225 502.4418 502.5611 502.6803 502.7995 502.9187 503.0379 503.1571 503.2762 503.3954 503.5145 503.6336 503.7527 503.8718 503.9908 504.1099 504.2289 504.3479 504.4669 504.5858 504.7048 504.8237 504.9426 505.0615 505.1804 505.2993 505.4181 505.5370 505.6558 505.7746 505.8934 506.0121 506.1309 506.2496 506.3683 506.4870 506.6057 506.7244 506.8430 506.9616 507.0803 507.1988 507.3174 507.4360 507.5545 507.6731 507.7916 507.9101 508.0285 508.1470 508.2654 508.3839 508.5023 508.6207 508.7390 508.8574 508.9757 509.0941 509.2124 509.3306 509.4489 509.5672 509.6854 509.8036 509.9218
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250507T100355.1Z 9258.419388 344 1 49.81 2 38.83 141.99 119.54 34.90 0.00 1 0.00 1 0 15 2.555e-03 2.549e-03 1.413e-03 1.407e-03 1.102572e+03 8.243922e+01 8.616634e+01 -6.000000e+00 1.418308e+02 275.97 -2.00 20.00 -2.00 505.24 0.00e+00 4.079837e-04 3.818558e-05 2.392567e-05 -6.000000e+00 7.107382e-05 275.97 -2.00 20.00 -2.00 500.28 0.00e+00 5.153589e-02 2.866766e-02 8.718525e-03 -6.000000e+00 5.170462e-02 230.12 -2.00 3.79 -2.00 501.88 0.00e+00 1.283 0.000 489.00 513.00 1 8.0402e+00 2.1977e-03 2.0362e-03 -6.0000e+00 3.9578e-03 8.6965e-03 5.6627e-04 2.2823e-04 -6.0000e+00 1.0251e-03 5.2236e-04 1.2102e-03 1.5226e-04 1.3670e-05 -6.0000e+00 2.8239e-04 -1.0422e-02 2.8431e-06 10 0 0 10 0 0 99.62 18.88 2.13 -0.01042 -0.00203 14 3 1 2 0 3557.520 14.99 18.88 17.01 21.27 21.88 1.5 929.49 900000 -367 64 268 -223 -15 386 69 352 -17 -19 608 88 -202 -271 -96 -290 -88 647 23 -189 219 166 -27 537 124 246 291 -218 -345 -56 -274 -622 -133 487 -297 19 -49 143 -194 -43 -32 -44 -145 37 304 133 412 123 80 -385 -471 -253 -419 81 -281 1 -266 -49 -132 3 208 403 112 -60 -179 28 -146 237 -12 -198 -28 -98 -222 248 -314 -328 -38 -20 301 -552 77 27 -432 -8 128 44 -287 29 98 210 -57 -132 -37 12 51 19 503 -384 -229 -308 164 -417 -349 -335 -258 37 -155 -231 100 112 -177 -40 -107 112 270 404 151 245 -106 181 533 169 247 344 272 -5 116 -221 -54 692 -249 -147 -66 -8 -172 243 -68 -23 -15 154 409 79 362 33 147 12 -43 -495 -289 -356 900000 -369 61 264 -227 -16 408 74 378 -18 -20 629 90 -205 -272 -97 -294 -91 679 24 -205 237 179 -29 582 135 267 312 -230 -357 -56 -274 -632 -138 516 -322 20 -53 152 -204 -45 -33 -46 -155 40 329 143 439 130 82 -388 -463 -244 -404 78 -282 1 -278 -52 -138 3 218 422 118 -63 -187 29 -148 235 -12 -193 -27 -96 -219 246 -315 -325 -37 -19 287 -530 73 26 -423 -8 127 42 -272 27 93 200 -55 -129 -37 12 49 18 468 -353 -218 -291 155 -379 -327 -322 -251 36 -149 -220 94 106 -171 -39 -107 112 271 406 153 247 -106 178 514 162 236 329 261 -4 111 -213 -52 654 -235 -137 -60 -7 -157 224 -64 -22 -15 150 400 78 358 33 146 12 -41 -469 -269 -331
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SQ 20250507T103555.0Z 9258.441608 361 1 3.30 2 36.14 153.78 116.59 42.97 0.00 1 0.00 1 0 15 1.547e-03 1.548e-03 4.746e-04 4.737e-04 9.880216e+02 2.708355e+01 7.503075e+01 -6.000000e+00 8.586893e+01 275.97 -2.00 20.00 -2.00 505.24 0.00e+00 3.143295e-04 1.290379e-05 1.954728e-05 -6.000000e+00 4.303009e-05 275.97 -2.00 20.00 -2.00 500.42 0.00e+00 -1.397053e-02 9.540390e-03 8.111869e-03 -6.000000e+00 3.130316e-02 230.12 -2.00 3.79 -2.00 502.01 0.00e+00 1.237 0.000 489.00 513.00 1 3.9129e+00 7.3047e-04 1.9336e-03 -6.0000e+00 2.3962e-03 1.2124e-02 1.8888e-04 2.1100e-04 -6.0000e+00 6.2058e-04 3.2809e-02 1.3497e-03 5.1018e-05 1.2249e-05 -6.0000e+00 1.7096e-04 -1.2071e-02 1.3399e-05 12 1 1 12 1 1 99.67 18.89 2.12 -0.01207 -0.00271 41 128 1 2 0 78.510 15.00 18.89 18.17 21.27 21.88 1.6 939.46 900000 -10 -14 17 -126 30 318 208 305 199 87 168 -50 11 -26 -59 -109 10 159 -137 -115 115 -5 102 356 132 -7 130 6 -314 -32 52 -303 24 154 -268 -264 31 85 -24 19 61 -7 73 82 148 66 83 129 19 -160 -170 -273 -307 -155 -135 -180 -239 -119 -33 34 127 152 162 93 79 49 -36 -28 -121 -192 -55 -84 -108 57 -69 -250 -196 41 6 -100 -79 -208 -308 -71 -12 -169 -156 -57 39 -41 8 303 207 -33 6 55 -50 -43 -147 -234 -193 -293 5 -94 -277 -294 -115 -43 -2 270 37 -73 14 74 120 156 241 192 -12 269 167 -9 289 334 -14 18 259 32 199 270 -40 -52 37 17 -75 293 71 -251 -76 53 -39 35 178 132 9 2 -192 -269 -4 -19 900000 -10 -15 18 -129 32 332 220 323 209 91 176 -51 11 -26 -59 -112 10 165 -145 -120 120 -6 107 374 139 -7 135 6 -319 -33 52 -308 24 161 -280 -276 32 89 -25 19 63 -7 75 85 155 68 86 133 19 -162 -167 -264 -302 -152 -136 -181 -245 -120 -33 34 128 154 165 94 80 49 -36 -27 -119 -188 -54 -82 -107 55 -68 -243 -192 40 6 -96 -77 -203 -303 -68 -12 -166 -154 -56 38 -41 8 302 208 -34 6 53 -49 -41 -140 -222 -184 -278 5 -93 -276 -292 -113 -42 -2 262 37 -74 14 75 121 157 244 193 -12 264 166 -9 282 327 -14 18 254 32 194 262 -39 -50 35 16 -71 281 68 -246 -74 52 -38 35 176 131 9 2 -186 -259 -4 -18
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