File name: Pandora111s1_Bucharest_20211103_L2Fit_fout2c1d20200901p1-8.txt File generation date: 20240917T132437.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Anca Nemuc Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 111 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora111_OF_v1d20200312.txt Instrument calibration file used: Pandora111s1_CF_v1d20200901.txt Level 1 file used: Pandora111s1_Bucharest_20211103_L1_smca1c1d20200901p1-8.txt Full location name: MARS Atmospheric Observatory Short location name: Bucharest Country of location: Romania Location latitude [deg]: 44.3440 Location longitude [deg]: 26.0120 Location altitude [m]: 93 Local noon date: 20211103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 363 Nominal wavelengths inside fitting window [nm]: 305.1225 305.2643 305.4060 305.5477 305.6894 305.8310 305.9727 306.1144 306.2560 306.3976 306.5393 306.6809 306.8225 306.9640 307.1056 307.2472 307.3887 307.5303 307.6718 307.8133 307.9549 308.0964 308.2378 308.3793 308.5208 308.6622 308.8037 308.9451 309.0865 309.2280 309.3694 309.5108 309.6521 309.7935 309.9349 310.0762 310.2175 310.3589 310.5002 310.6415 310.7828 310.9240 311.0653 311.2066 311.3478 311.4890 311.6303 311.7715 311.9127 312.0539 312.1950 312.3362 312.4774 312.6185 312.7597 312.9008 313.0419 313.1830 313.3241 313.4652 313.6062 313.7473 313.8883 314.0294 314.1704 314.3114 314.4524 314.5934 314.7344 314.8753 315.0163 315.1572 315.2982 315.4391 315.5800 315.7209 315.8618 316.0027 316.1435 316.2844 316.4252 316.5661 316.7069 316.8477 316.9885 317.1293 317.2700 317.4108 317.5516 317.6923 317.8330 317.9738 318.1145 318.2552 318.3959 318.5365 318.6772 318.8178 318.9585 319.0991 319.2397 319.3803 319.5209 319.6615 319.8021 319.9427 320.0832 320.2238 320.3643 320.5048 320.6453 320.7858 320.9263 321.0668 321.2072 321.3477 321.4881 321.6285 321.7689 321.9093 322.0497 322.1901 322.3305 322.4708 322.6112 322.7515 322.8919 323.0322 323.1725 323.3128 323.4530 323.5933 323.7336 323.8738 324.0140 324.1543 324.2945 324.4347 324.5749 324.7150 324.8552 324.9954 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211103T065831.2Z 7977.290639 147 1 44.00 2 72.35 133.99 54.40 147.79 0.00 1 0.00 1 0 33 1.541e-01 2.775e-02 3.465e-01 4.541e-02 3.659467e-01 2.233606e-02 4.424062e-03 -6.000000e+00 8.393311e-02 223.63 -2.00 3.58 -2.00 319.28 0.00e+00 8.643034e-03 5.591883e-03 9.827763e-04 -6.000000e+00 3.690061e-03 278.81 -2.00 20.00 -2.00 318.68 0.00e+00 3.252 0.001 302.00 328.00 3 6.8537e+00 6.1691e-02 3.7050e-02 -6.0000e+00 2.0726e-01 2.1737e-01 7.1573e-02 1.9438e-02 -6.0000e+00 2.2552e-01 -5.1748e-02 5.3079e-02 1.1944e-02 -6.0000e+00 1.3429e-01 2.1954e-02 2.8359e-02 8.7864e-03 -6.0000e+00 5.9283e-02 1.3059e-05 6.5065e-04 1.1974e-03 6.4764e-05 -6.0000e+00 3.6651e-03 1.3969e-02 0.0000e+00 12 9 8 11 8 0 93.99 15.83 0.53 0.01397 0.01886 11 4 4 8 0 4000.000 15.00 15.83 16.84 23.32 22.80 46.6 1005.73 27678 29973 29701 -79685 -46569 -14913 -33737 -61824 -4087 30472 29840 -33854 14571 -16331 -12227 1871 -14712 5450 21888 48181 -4652 -8438 -18850 -1044 37074 18283 8488 19005 11972 23979 56726 -9093 4744 2504 -11362 384 20420 -12053 2805 4886 -338 -11318 2913 5462 2246 9237 -8837 5318 -3868 6800 967 5173 1712 3250 5028 2221 7358 -4407 4254 -4573 -1260 1652 10013 1471 -1357 1982 -185 -5323 2336 3866 2590 1060 -2343 -5808 270 -6861 -7154 -13441 -10671 977 -2898 -1260 -1233 -1223 -596 1159 6560 2474 4778 -1167 -2201 -1931 -7411 1370 -853 2569 1475 3991 1364 -4134 -3387 -4506 -1640 1350 3601 -465 46 -726 1508 1940 1508 262 275 -2662 -3022 -724 -2269 1545 1403 3106 2320 132 1333 -842 -1808 -2762 -2243 -947 -1654 152 103 -880 -181 -1217 2718 -578 2124 1144 -1357 457 -1702 900000 1225 1327 1315 -6081 -2275 -660 -1545 -4152 -181 1349 1321 -2067 714 -1296 -1101 160 -1572 507 1869 3275 -522 -960 -2444 -117 2931 1763 872 1682 1178 2319 4557 -1538 758 380 -1832 58 2938 -2896 683 1282 -98 -3847 884 1632 710 2731 -3115 1683 -1351 2274 376 2052 744 1428 2193 1012 3148 -2059 1806 -2197 -642 912 5598 919 -803 1046 -97 -3177 1505 2681 1885 773 -1683 -3980 160 -3948 -3983 -8650 -7830 727 -2496 -1137 -1152 -1224 -635 1282 7058 2759 4986 -1186 -2050 -1637 -6611 1233 -891 2917 1906 5362 1825 -5342 -3869 -4887 -1832 1605 4366 -614 64 -1078 2388 3259 2565 431 417 -3807 -4292 -1025 -3451 2443 2333 5049 3663 207 1962 -1209 -2477 -3614 -3078 -1427 -2723 258 177 -1573 -339 -2462 5472 -1219 4441 2392 -2781 871 -3141 900000 SS 20211103T075039.9Z 7977.326850 173 1 49.52 2 66.35 145.82 50.83 163.15 0.00 1 0.00 1 0 25 2.301e-02 1.080e-02 3.024e-02 4.777e-03 2.914101e-01 2.324614e-03 3.579392e-03 -6.000000e+00 1.253083e-02 223.63 -2.00 3.58 -2.00 318.90 0.00e+00 1.668277e-03 5.110767e-04 7.181546e-04 -6.000000e+00 5.508703e-04 278.81 -2.00 20.00 -2.00 318.25 0.00e+00 2.475 0.000 302.00 328.00 3 3.7702e+00 6.3433e-03 2.8658e-02 -6.0000e+00 3.0942e-02 -1.8533e-03 7.3037e-03 1.5178e-02 -6.0000e+00 3.3669e-02 5.1117e-04 5.1695e-03 7.9092e-03 -6.0000e+00 2.0049e-02 -3.5024e-03 2.7473e-03 2.6811e-03 -6.0000e+00 8.8512e-03 7.5996e-04 6.5778e-04 1.2936e-04 2.4218e-05 -6.0000e+00 5.4716e-04 1.3480e-02 0.0000e+00 12 8 8 10 0 0 99.97 15.90 0.21 0.01348 0.01842 402 84 2 8 0 123.170 14.99 15.90 17.32 23.32 22.90 46.7 1008.12 2180 -1572 -2370 -7343 -2468 -13483 -4699 -7416 -12 -2622 -5349 -3703 -4675 933 1023 1238 2503 1458 3837 1423 2490 -360 2182 -1660 257 -935 -997 -873 -3366 -418 -1387 2737 -1053 -3593 -4583 -4920 -2095 -1564 1023 102 148 994 147 1055 485 665 -46 -788 -1053 -343 1040 739 2098 824 1381 430 -323 -258 -239 493 1078 2382 2700 1467 -548 -1508 -2151 -811 -5 552 944 485 609 -459 -2133 -2850 -5312 -3389 -2971 -1816 -1160 -1846 -1100 -346 716 857 1442 1815 1652 807 -896 -1556 -2354 -1356 -914 453 1475 852 123 -866 -1582 -2207 -833 -1044 -215 34 339 1012 1477 2045 1371 958 90 -1201 -1143 -1388 -711 -12 421 422 666 572 59 -193 -1398 -1426 -1541 -984 -465 -703 -392 -826 -107 278 403 803 887 511 194 -199 -719 900000 111 -88 -132 -376 -108 -670 -241 -449 -1 -163 -334 -254 -385 85 107 138 286 177 473 187 319 -47 294 -249 40 -149 -151 -122 -465 -60 -222 467 -201 -654 -782 -899 -436 -396 301 34 51 353 53 380 178 240 -16 -278 -372 -128 416 315 1021 419 713 230 -173 -135 -123 259 612 1472 1808 1010 -351 -892 -1237 -496 -4 427 759 389 470 -332 -1394 -1684 -3054 -2037 -2062 -1412 -995 -1699 -1044 -351 773 981 1688 2111 1848 837 -857 -1359 -2042 -1269 -955 521 1882 1162 165 -1071 -1775 -2367 -941 -1302 -278 46 476 1502 2361 3444 2333 1557 136 -1676 -1514 -1881 -1013 -19 684 688 1053 879 87 -273 -1891 -1821 -2060 -1440 -730 -1158 -650 -1410 -192 533 801 1621 1828 1052 386 -379 -1448 900000 SS 20211103T080006.4Z 7977.333408 175 1 49.65 2 65.43 148.11 50.44 166.08 0.00 1 0.00 1 0 25 3.611e-02 1.346e-02 5.749e-02 9.880e-03 2.844979e-01 4.827081e-03 3.511116e-03 -6.000000e+00 1.967023e-02 223.62 -2.00 3.58 -2.00 318.77 0.00e+00 1.687696e-03 1.006675e-03 7.559030e-04 -6.000000e+00 8.647056e-04 278.81 -2.00 20.00 -2.00 318.12 0.00e+00 2.389 0.000 302.00 328.00 3 5.5383e+00 1.3073e-02 2.7740e-02 -6.0000e+00 4.8572e-02 3.7167e-02 1.4964e-02 1.4765e-02 -6.0000e+00 5.2851e-02 -5.1131e-03 1.0388e-02 7.6940e-03 -6.0000e+00 3.1471e-02 -2.4358e-03 5.5429e-03 2.6020e-03 -6.0000e+00 1.3894e-02 1.3961e-04 7.5644e-04 2.6824e-04 2.2560e-05 -6.0000e+00 8.5889e-04 1.3314e-02 0.0000e+00 12 8 8 10 0 0 99.83 15.91 0.36 0.01331 0.01900 49 10 1 8 0 1013.170 15.00 15.91 17.62 23.32 22.90 46.6 1009.15 7341 3063 -6985 5596 -17657 6916 -18044 4656 -5657 4304 -10537 -7065 1509 -1850 6827 573 7394 2808 -824 6239 -5437 3023 -1569 7274 -1568 2457 -727 -3295 702 -3588 3203 -2462 2349 -4807 -7155 -4143 -4703 -802 -113 2717 -271 1567 468 -307 1796 124 824 -2029 -559 381 -81 593 684 2229 623 1946 -1434 -1174 -1134 -486 2231 1431 4431 647 914 -1727 -2881 -489 -1055 1639 -197 1440 393 -302 -2246 -4566 -4436 -5745 -2362 -1593 -1182 -1392 -1894 270 604 1528 2028 2715 1156 824 -1295 -2509 -2026 -1718 -737 510 2190 843 448 -432 -2558 -2434 -1461 -795 -654 -197 287 1434 2005 2097 1555 914 89 -1405 -1476 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