File name: Pandora111s1_Bucharest_20230226_L2Fit_fout2c1d20200901p1-8.txt File generation date: 20240917T182917.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Anca Nemuc Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 111 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora111_OF_v1d20200312.txt Instrument calibration file used: Pandora111s1_CF_v1d20200901.txt Level 1 file used: Pandora111s1_Bucharest_20230226_L1_smca1c1d20200901p1-8.txt Full location name: MARS Atmospheric Observatory Short location name: Bucharest Country of location: Romania Location latitude [deg]: 44.3440 Location longitude [deg]: 26.0120 Location altitude [m]: 93 Local noon date: 20230226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 363 Nominal wavelengths inside fitting window [nm]: 305.1225 305.2643 305.4060 305.5477 305.6894 305.8310 305.9727 306.1144 306.2560 306.3976 306.5393 306.6809 306.8225 306.9640 307.1056 307.2472 307.3887 307.5303 307.6718 307.8133 307.9549 308.0964 308.2378 308.3793 308.5208 308.6622 308.8037 308.9451 309.0865 309.2280 309.3694 309.5108 309.6521 309.7935 309.9349 310.0762 310.2175 310.3589 310.5002 310.6415 310.7828 310.9240 311.0653 311.2066 311.3478 311.4890 311.6303 311.7715 311.9127 312.0539 312.1950 312.3362 312.4774 312.6185 312.7597 312.9008 313.0419 313.1830 313.3241 313.4652 313.6062 313.7473 313.8883 314.0294 314.1704 314.3114 314.4524 314.5934 314.7344 314.8753 315.0163 315.1572 315.2982 315.4391 315.5800 315.7209 315.8618 316.0027 316.1435 316.2844 316.4252 316.5661 316.7069 316.8477 316.9885 317.1293 317.2700 317.4108 317.5516 317.6923 317.8330 317.9738 318.1145 318.2552 318.3959 318.5365 318.6772 318.8178 318.9585 319.0991 319.2397 319.3803 319.5209 319.6615 319.8021 319.9427 320.0832 320.2238 320.3643 320.5048 320.6453 320.7858 320.9263 321.0668 321.2072 321.3477 321.4881 321.6285 321.7689 321.9093 322.0497 322.1901 322.3305 322.4708 322.6112 322.7515 322.8919 323.0322 323.1725 323.3128 323.4530 323.5933 323.7336 323.8738 324.0140 324.1543 324.2945 324.4347 324.5749 324.7150 324.8552 324.9954 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230226T090524.6Z 8457.378757 134 1 15.74 2 56.35 154.98 80.01 71.03 0.00 1 0.00 1 0 17 1.942e-02 1.118e-02 1.611e-02 3.546e-03 2.697063e-01 1.690566e-03 3.203430e-03 -6.000000e+00 1.045966e-02 225.06 -2.00 3.58 -2.00 318.14 0.00e+00 1.372445e-03 2.937349e-04 3.985164e-04 -6.000000e+00 4.510154e-04 272.75 -2.00 20.00 -2.00 317.56 0.00e+00 1.799 0.000 302.00 328.00 3 4.8635e+00 4.5224e-03 2.2447e-02 -6.0000e+00 2.5944e-02 -8.5340e-03 5.1431e-03 1.3654e-02 -6.0000e+00 2.8403e-02 2.4826e-03 3.3616e-03 6.9469e-03 -6.0000e+00 1.6847e-02 -4.8592e-03 1.7480e-03 2.2745e-03 -6.0000e+00 7.1744e-03 5.0226e-04 2.6807e-04 9.2823e-05 1.8315e-05 -6.0000e+00 4.6072e-04 6.6876e-04 0.0000e+00 12 9 9 12 1 1 96.62 16.11 0.23 0.00067 0.00268 12 9 1 8 0 1197.640 15.00 16.11 22.74 23.53 23.11 47.0 1054.75 4448 972 -2577 -1912 -4507 -5159 -4678 -3402 -2564 -6590 -5765 -5374 -986 -1232 2274 579 964 2710 1701 2624 230 2164 979 35 -1098 -1464 -386 -2360 -2079 -1176 -1143 219 23 -3418 -5208 -4595 -2597 -756 617 769 595 391 131 908 753 169 -36 -984 -592 68 569 1471 1052 945 654 559 237 -327 -316 208 1441 2156 2957 1602 -62 -1101 -2662 -295 -203 969 915 731 843 -222 -1202 -3396 -4538 -4505 -2672 -1750 -1700 -1910 -1254 -227 288 1427 1547 1861 1405 725 -565 -1463 -1695 -1845 -557 9 1359 1037 347 -437 -1793 -1873 -747 -1148 -298 223 406 1028 1584 2138 1658 830 144 -687 -1499 -1146 -569 -48 517 689 802 488 -49 -240 -1023 -1353 -1242 -807 -511 -261 -737 -760 -296 477 475 799 826 452 467 6 -581 -821 313 75 -205 -133 -286 -329 -331 -274 -223 -597 -550 -557 -115 -153 312 86 162 469 308 491 44 396 190 7 -245 -334 -83 -478 -399 -233 -250 52 6 -858 -1219 -1123 -721 -251 242 336 274 187 64 437 366 82 -17 -458 -271 32 294 800 607 564 398 350 149 -201 -191 128 940 1537 2269 1274 -46 -746 -1751 -201 -160 838 828 663 736 -183 -892 -2297 -2906 -3011 -2018 -1485 -1601 -1926 -1302 -250 310 1611 1800 2160 1581 832 -595 -1400 -1574 -1847 -615 11 1664 1365 450 -526 -2169 -2136 -889 -1516 -410 290 549 1455 2403 3418 2683 1291 208 -999 -2071 -1596 -831 -69 786 1059 1201 711 -75 -353 -1438 -1787 -1686 -1195 -813 -394 -1132 -1190 -485 831 863 1475 1560 856 854 11 -981 -1379 SS 20230226T091038.5Z 8457.382391 137 1 24.68 2 55.97 156.46 79.14 71.84 0.00 1 0.00 1 0 25 1.955e-02 1.057e-02 6.020e-03 1.346e-03 2.658717e-01 6.426994e-04 3.167415e-03 -6.000000e+00 1.052568e-02 225.06 -2.00 3.58 -2.00 318.36 0.00e+00 1.252886e-03 1.164566e-04 3.737888e-04 -6.000000e+00 4.538833e-04 272.75 -2.00 20.00 -2.00 317.77 0.00e+00 1.781 0.000 302.00 328.00 3 3.2019e+00 1.7236e-03 2.2196e-02 -6.0000e+00 2.6108e-02 -1.8355e-02 1.9638e-03 1.3476e-02 -6.0000e+00 2.8583e-02 2.2334e-03 1.2843e-03 6.8368e-03 -6.0000e+00 1.6953e-02 -4.4315e-03 6.6679e-04 2.2083e-03 -6.0000e+00 7.2192e-03 2.7250e-03 2.8417e-04 3.5975e-05 1.8368e-05 -6.0000e+00 4.6367e-04 1.2290e-03 0.0000e+00 12 9 9 12 1 1 99.26 16.11 0.27 0.00123 0.00336 125 53 1 8 0 194.510 15.01 16.11 23.01 23.53 23.11 47.1 1056.31 923 253 65 -3916 -6783 -6867 -6020 -2074 -3386 -4154 -6578 -4912 -1797 -349 1415 114 2020 974 2431 2592 1165 2022 1145 1186 -133 -80 -1098 -1800 -1999 -185 -420 412 -344 -3921 -5043 -4844 -2992 -805 193 443 272 530 438 984 1020 238 336 -863 -626 153 673 1001 1146 956 685 439 159 -227 -215 516 1583 1948 3015 1499 206 -1430 -2213 -622 9 728 780 435 467 -431 -1522 -3096 -4442 -3816 -2738 -2009 -1254 -1959 -1369 -476 428 1082 1499 1927 1240 793 -424 -1496 -2008 -1614 -585 139 1254 891 226 -591 -1524 -1981 -1000 -803 -337 -208 317 1008 1532 1712 1379 905 32 -1026 -1351 -1249 -856 -76 402 609 541 667 36 -126 -1097 -1453 -1172 -932 -413 -412 -546 -561 -268 346 348 785 942 558 285 -116 -499 -791 66 19 5 -294 -465 -471 -456 -174 -314 -388 -608 -487 -202 -45 205 18 319 163 416 462 208 353 211 234 -28 -17 -227 -345 -364 -34 -87 92 -84 -936 -1115 -1124 -790 -254 72 184 119 239 201 447 467 109 149 -379 -271 69 327 516 623 538 394 260 94 -131 -123 298 974 1313 2181 1125 143 -915 -1364 -399 7 594 666 373 386 -336 -1067 -1967 -2920 -2603 -1950 -1609 -1107 -1860 -1339 -495 476 1269 1809 2315 1448 857 -420 -1349 -1762 -1518 -608 159 1592 1215 304 -737 -1730 -2129 -1125 -996 -436 -282 444 1480 2410 2849 2319 1457 48 -1409 -1753 -1639 -1180 -114 634 972 842 1007 52 -174 -1456 -1977 -1636 -1304 -620 -646 -867 -907 -455 626 656 1503 1844 1096 542 -212 -875 -1379 SS 20230226T091526.1Z 8457.385718 139 1 49.73 2 55.63 157.83 78.34 72.59 0.00 1 0.00 1 0 25 1.970e-02 1.047e-02 4.010e-03 8.547e-04 2.647956e-01 4.088620e-04 3.176877e-03 -6.000000e+00 1.061067e-02 225.06 -2.00 3.58 -2.00 318.47 0.00e+00 1.270259e-03 7.717858e-05 4.019483e-04 -6.000000e+00 4.575347e-04 272.75 -2.00 20.00 -2.00 317.89 0.00e+00 1.766 0.000 302.00 328.00 3 2.5660e+00 1.0986e-03 2.2093e-02 -6.0000e+00 2.6318e-02 -1.1077e-02 1.2548e-03 1.3506e-02 -6.0000e+00 2.8813e-02 -7.5208e-04 8.2814e-04 6.8591e-03 -6.0000e+00 1.7090e-02 -3.7609e-03 4.3048e-04 2.2202e-03 -6.0000e+00 7.2778e-03 5.2182e-03 2.8850e-04 2.2801e-05 1.8648e-05 -6.0000e+00 4.6738e-04 8.4392e-04 0.0000e+00 12 8 8 10 0 0 99.86 16.11 0.21 0.00084 0.00301 551 115 1 8 0 89.910 15.00 16.11 23.40 23.53 23.11 47.3 1058.85 289 1081 -778 -4798 -7172 -7023 -4325 -2864 -2000 -4819 -6643 -4994 -2625 -339 942 1110 1566 1503 2329 2362 1635 1484 1589 931 18 -48 -994 -1809 -2559 -802 -549 1121 -437 -3525 -5215 -5021 -2864 -876 412 382 358 504 435 858 652 363 183 -664 -633 220 692 956 1368 783 879 567 210 -209 -279 526 1342 1990 2833 1649 -53 -1248 -2315 -722 27 613 829 408 538 -453 -1704 -3068 -4579 -3643 -2896 -1866 -1378 -2031 -1391 -479 432 1110 1439 1875 1317 750 -392 -1634 -1973 -1407 -636 203 1309 928 177 -540 -1444 -2032 -972 -975 -406 -178 400 1012 1378 1748 1410 954 45 -982 -1303 -1246 -820 -117 406 511 493 618 -8 -184 -1189 -1349 -1258 -886 -505 -464 -467 -670 -270 307 338 778 895 563 364 -107 -572 -691 20 84 -61 -346 -469 -458 -306 -230 -174 -429 -582 -469 -282 -42 130 163 235 236 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