File name: Pandora114s1_BuenosAires_20170323_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T001237.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170323_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170323 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170323T100507.0Z 6291.420220 334 1 32.00 2 89.74 88.38 34.06 66.09 0.00 1 0.00 1 0 29 1.342e-01 1.254e-01 1.433e-01 1.383e-01 1.000995e+04 9.622610e+03 9.527090e+02 -6.000000e+00 7.480192e+03 287.83 -2.00 20.00 -2.00 505.31 0.00e+00 -1.958278e-03 3.807260e-03 3.212267e-04 -6.000000e+00 3.768695e-03 287.83 -2.00 20.00 -2.00 500.45 0.00e+00 -1.339726e+00 2.674036e+00 4.266526e-02 -6.000000e+00 2.628011e+00 227.57 -2.00 3.16 -2.00 502.06 0.00e+00 19.967 0.075 489.00 513.00 1 1.0274e+01 2.0480e-01 3.1471e-02 -6.0000e+00 2.0160e-01 1.2090e-01 5.1932e-02 1.8316e-03 -6.0000e+00 5.2680e-02 4.2970e-06 1.6869e-02 1.2451e-02 1.6337e-04 -6.0000e+00 1.3228e-02 -4.1425e-02 1.9167e-04 12 9 8 11 8 0 -143.12 22.47 -53.45 -0.04142 0.07559 8 2 1 4 0 4000.000 26.41 20.00 22.47 18053 -12979 7386 9016 -10844 -10681 -27517 621 -8881 -688 -6454 2332 16808 33284 24647 23768 27490 13496 -7527 698 -3424 -12933 5697 9785 -6731 20575 10540 10681 -6754 -3098 6722 -8571 20781 -14996 -6909 22816 16721 -8026 -4155 -1260 -1164 11601 -19333 -186 26990 -4508 1558 12307 11412 -16539 -13787 -3952 6846 11045 4557 5727 6097 18097 -10030 6174 14066 4949 6368 -7335 -1222 -8252 -1245 -7744 12679 39106 -14629 12029 -8662 10484 15957 -13742 18028 -9465 770 -9651 -7842 15120 17224 16294 5612 6974 19991 -15435 2618 9057 -7367 8409 10538 11168 5725 -18446 5169 17580 9624 -394 7551 -9680 7125 -1168 -18263 -4694 4259 -5272 17644 -5811 -10421 -12470 -3611 5542 -1750 15181 -3609 -368 24276 11860 11803 7246 -2483 -4745 12848 27999 -17367 3387 -9986 16170 10045 15516 -12072 -9764 4647 -8173 9844 -26541 -9109 -6546 13202 17337 -1269 22960 -10005 -8275 -7721 14897 2552 12158 -11660 -5796 41958 14164 -14332 6868 8472 -12710 -12725 -39182 668 -10409 -733 -7189 2349 14490 24180 19576 19339 22101 12811 -8968 771 -3946 -16411 6015 9952 -8084 18734 10515 10449 -7144 -3301 6446 -9066 18116 -18031 -7807 20554 14815 -8998 -4433 -1299 -1199 10593 -24294 -196 21716 -4972 1606 11237 10317 -19288 -15206 -3859 5942 9287 4203 5385 5842 15543 -11425 5973 12589 4876 6218 -8222 -1282 -9176 -1272 -8331 11004 25809 -16399 10331 -9241 9383 13705 -15903 14995 -10182 738 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1.6108e-03 -6.0000e+00 6.0257e-02 4.5794e-06 -2.0267e-02 1.2085e-02 5.7412e-05 -6.0000e+00 1.5234e-02 7.1150e-02 -1.8529e-04 12 9 8 11 8 0 -113.65 22.47 15.59 0.07115 -0.06943 8 2 1 4 0 4000.000 26.41 20.00 22.47 7383 -13502 3801 3528 -17240 7542 7206 7208 19730 11393 6155 -3131 11653 13320 7011 -20224 2404 28023 -16559 -11339 7110 3679 9489 12186 15113 4090 8026 -43400 -4903 19860 6412 2637 24654 -24050 18255 -1687 4052 6039 3362 5136 14898 11749 10129 14166 1104 20271 46598 11356 12737 -1946 -15694 -17906 4463 1240 -13326 21877 -3150 -5235 -11027 4783 -459 -17024 3817 -1692 -864 -5185 13944 -7170 37096 -5865 7482 -1952 6037 34044 10569 -12430 -6946 -4270 22722 6321 2205 -6314 18164 6404 -371 -4034 -9870 1073 -14083 1015 -3100 21045 -5485 16396 26105 -6149 5029 13837 -5576 24503 -13433 20983 -6091 6732 1873 -14374 53080 -9318 -15392 -13420 12632 -10489 -8324 10941 26348 14721 21158 -592 6670 -13573 -14650 17484 4175 3019 38653 -5931 -3633 -447 14246 17344 -13062 55620 -29451 -6680 596 -4118 11325 6085 13580 323 -9689 7699 -18383 4446 12716 11752 -3136 25577 1838 1868 -13630 842 15603 6733 -15267 3709 3571 -22166 7772 7623 7756 18891 11844 6679 -3683 11688 12997 7224 -27294 2608 24020 -21280 -14186 8039 4328 10556 12342 14921 4525 8538 -76829 -5842 18085 6494 2716 20353 -32955 16935 -1967 4517 6579 3720 5508 14327 11600 10172 13745 1230 18805 33314 11501 12575 -2186 -19768 -22403 4330 1214 -14970 17502 -3325 -5792 -13139 4885 -492 -21444 3898 -1829 -927 -5781 12698 -7933 25889 -6190 6814 -1927 5446 23180 9175 -13753 -7330 -4361 17405 5595 2008 -6233 14068 5613 -350 -3734 -9766 959 -14720 915 -2919 16657 -5339 12951 18954 -6231 4574 11482 -5561 17791 -13934 15068 -5637 5479 1629 -15139 29223 -9665 -16825 -14135 10079 -10461 -8169 8991 18921 12098 16544 -581 6121 -15270 -16598 14229 3830 2770 24673 -5915 -3565 -428 11821 13977 -14278 30621 -38069 -6875 566 -4041 9398 5292 11052 307 -10437 7126 -22441 4364 11566 10877 -3203 21020 1808 1824 -15250 797 12537 SO 20170323T101312.0Z 6291.425833 342 1 32.00 2 88.08 87.23 32.59 63.91 0.00 1 0.00 1 0 22 8.162e-02 7.820e-02 7.915e-02 7.729e-02 1.244747e+04 5.817121e+03 1.128073e+03 -6.000000e+00 4.547641e+03 287.83 -2.00 20.00 -2.00 505.34 0.00e+00 -2.250161e-03 2.116815e-03 7.282672e-05 -6.000000e+00 2.289332e-03 287.83 -2.00 20.00 -2.00 500.11 0.00e+00 5.848813e-01 1.543367e+00 1.819099e-02 -6.000000e+00 1.590079e+00 227.56 -2.00 3.16 -2.00 501.76 0.00e+00 16.181 0.040 489.00 513.00 1 1.0079e+01 1.1756e-01 2.4027e-02 -6.0000e+00 1.2209e-01 8.6159e-02 3.0119e-02 1.7318e-03 -6.0000e+00 3.1719e-02 7.8626e-06 8.1836e-03 6.8039e-03 9.5626e-05 -6.0000e+00 8.0218e-03 6.7413e-02 -1.4669e-04 12 8 8 10 0 0 -442.86 22.47 -0.70 0.06741 0.12418 8 2 1 4 0 4000.000 26.41 20.00 22.47 -1657 -4749 1999 7297 -1101 6140 5126 -5202 1378 -431 -1745 -7246 -3142 14257 -6837 494 -9141 1269 620 -4624 5200 -1265 17822 -1631 8341 -1073 3589 9196 -13153 3377 6792 -15552 -5052 950 488 4799 5811 6985 4825 11852 -8322 -1491 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