File name: Pandora114s1_BuenosAires_20170330_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T001310.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170330_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170330 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170330T101035.0Z 6298.424016 423 1 32.00 2 89.74 85.05 120.09 97.38 0.00 1 0.00 1 0 15 1.742e-02 1.696e-02 1.485e-02 1.467e-02 4.298683e+03 9.693043e+02 2.808215e+02 -6.000000e+00 9.694893e+02 287.49 -2.00 20.00 -2.00 505.21 0.00e+00 1.170229e-03 4.016711e-04 6.528515e-05 -6.000000e+00 4.885163e-04 287.49 -2.00 20.00 -2.00 500.00 0.00e+00 1.706226e+00 2.952271e-01 3.344936e-02 -6.000000e+00 3.403157e-01 227.16 -2.00 3.16 -2.00 501.63 0.00e+00 19.980 0.075 489.00 513.00 1 7.6890e+00 2.2629e-02 3.0690e-02 -6.0000e+00 2.6114e-02 1.2069e-01 5.8501e-03 1.8234e-03 -6.0000e+00 6.8072e-03 4.4808e-05 -9.1996e-04 1.3855e-03 3.4712e-05 -6.0000e+00 1.7139e-03 8.8025e-03 2.6953e-05 12 8 8 10 0 0 -50.42 22.63 2.91 0.00880 0.00242 8 2 1 4 0 4000.000 26.51 20.00 22.63 -1718 -1991 -1369 -748 -1401 2972 434 -457 1754 -527 2049 1754 -29 1436 -2776 1066 -2335 33 592 -249 -783 -2490 -514 -1451 2521 689 1004 1040 -2453 -1181 954 428 -1148 1526 680 -1271 1309 -379 -314 -1880 2080 1223 2608 550 -242 -443 1015 3125 -554 -1028 2557 598 -1721 179 -744 -1145 1678 117 185 699 -2114 132 -962 331 -1403 -100 671 -1680 219 -1734 -100 873 3936 1691 -411 1070 -172 -1489 -1122 -1441 1265 -4854 571 -2303 -187 -1014 3979 -672 -1860 1342 -1879 -680 669 3332 1953 2581 -655 -3533 1642 675 -2949 2600 1150 -1762 -48 329 -1322 -78 1621 2883 -1739 937 -17 -1432 980 106 -1697 -63 2099 -1993 -1723 3055 915 -790 -734 1567 -2596 -1009 219 -1767 2713 3077 -228 1229 1583 -1611 1265 4161 -1068 4664 565 -387 -2022 -3277 1678 -2859 2048 962 -1011 -208 -2420 -15 -1561 -1729 -2056 -1452 -813 -1573 3263 497 -531 1988 -604 2253 1908 -32 1529 -2873 1066 -2453 35 634 -272 -864 -2798 -567 -1621 2720 758 1097 1124 -2688 -1242 958 431 -1192 1592 738 -1427 1430 -417 -341 -2052 2175 1294 2746 598 -268 -495 1115 3335 -604 -1104 2579 598 -1722 174 -741 -1177 1727 125 199 746 -2314 141 -1046 357 -1445 -107 703 -1772 223 -1780 -99 855 3733 1557 -391 1014 -165 -1420 -1046 -1330 1130 -4612 516 -2159 -173 -956 3599 -640 -1792 1250 -1806 -649 635 3124 1872 2451 -632 -3432 1477 598 -2650 2176 976 -1570 -44 308 -1288 -75 1522 2636 -1654 872 -16 -1405 951 105 -1716 -63 2067 -2052 -1762 2941 885 -765 -704 1473 -2416 -928 199 -1638 2400 2710 -206 1086 1371 -1421 1078 3471 -955 4025 517 -362 -1944 -3211 1573 -2819 1929 915 -971 -194 -2261 -14 -1418 SO 20170330T101445.0Z 6298.426910 427 1 31.99 2 88.89 84.46 119.29 96.75 0.00 1 0.00 1 0 22 1.385e-02 1.402e-02 1.135e-02 1.123e-02 3.731791e+03 7.229778e+02 2.639921e+02 -6.000000e+00 7.708086e+02 287.49 -2.00 20.00 -2.00 505.20 0.00e+00 8.041803e-04 3.076873e-04 2.984256e-05 -6.000000e+00 3.884382e-04 287.49 -2.00 20.00 -2.00 500.01 0.00e+00 1.563641e+00 2.231815e-01 2.376588e-02 -6.000000e+00 2.706572e-01 227.16 -2.00 3.16 -2.00 501.64 0.00e+00 18.279 0.057 489.00 513.00 1 7.6625e+00 1.7109e-02 2.7499e-02 -6.0000e+00 2.0768e-02 1.1454e-01 4.4271e-03 1.6063e-03 -6.0000e+00 5.4157e-03 5.9636e-05 1.8737e-03 1.0552e-03 2.6966e-05 -6.0000e+00 1.3628e-03 1.9688e-02 -5.9273e-05 12 8 8 10 0 0 -128.82 22.63 2.63 0.01969 0.03268 8 2 1 4 0 4000.000 26.51 20.00 22.63 -2996 -2602 2013 -328 -661 -1452 1373 -828 -93 2119 -1195 -2740 861 -1265 -1213 -2732 -1035 -125 652 1296 1638 19 -1624 570 -1098 1999 2978 5975 99 -548 -704 -2463 -44 456 1675 1123 76 -483 -2292 -252 245 637 1404 824 1224 416 1176 1042 -1436 2057 -403 -1985 -278 -546 -513 363 -684 572 1140 231 195 -1739 740 603 -477 -365 704 -1412 -758 1096 -1047 -187 -2248 -5 3478 -135 1118 -231 1538 -1261 182 389 -2382 1346 -481 -1182 -275 1084 1535 411 146 442 706 1471 936 895 -737 491 1833 -747 -1109 -2016 -962 -417 911 -382 -989 -1006 -367 332 -1140 595 -407 856 632 -572 1060 -1468 1970 777 -367 -1059 -635 22 1173 1092 -751 804 -156 1247 1243 267 1705 -160 74 -1505 1439 1116 237 546 -1963 513 -3042 -573 -1432 2592 588 -103 1014 -3235 969 -2251 -1873 -3131 -2776 2120 -342 -708 -1600 1492 -925 -102 2260 -1297 -2979 890 -1323 -1261 -2902 -1100 -135 714 1427 1803 22 -1850 638 -1253 2214 3250 6253 108 -581 -732 -2601 -46 493 1841 1255 86 -541 -2580 -276 266 691 1524 910 1360 468 1311 1151 -1600 2167 -423 -2059 -278 -545 -519 375 -691 581 1158 236 199 -1812 756 618 -493 -373 702 -1413 -743 1042 -1004 -176 -2166 -5 3238 -131 1068 -220 1413 -1177 167 356 -2255 1237 -454 -1135 -264 1031 1453 393 140 424 684 1432 923 878 -723 465 1671 -682 -994 -1799 -852 -376 839 -369 -980 -997 -357 316 -1095 566 -396 789 592 -546 1001 -1429 1864 746 -354 -1015 -595 21 1058 988 -696 736 -144 1135 1130 245 1533 -145 65 -1340 1239 972 213 498 -1867 482 -2989 -553 -1400 2448 568 -100 962 -3139 882 -2081 -1725 SO 20170330T101843.0Z 6298.429664 431 1 31.99 2 88.07 83.89 118.52 96.15 0.00 1 0.00 1 0 15 1.184e-02 1.184e-02 1.092e-02 1.081e-02 4.552908e+03 7.058421e+02 2.732410e+02 -6.000000e+00 6.586574e+02 287.49 -2.00 20.00 -2.00 505.21 0.00e+00 9.833795e-04 2.959829e-04 6.100246e-05 -6.000000e+00 3.318887e-04 287.49 -2.00 20.00 -2.00 500.05 0.00e+00 1.291419e+00 2.148402e-01 3.881803e-02 -6.000000e+00 2.310161e-01 227.16 -2.00 3.16 -2.00 501.68 0.00e+00 16.177 0.040 489.00 513.00 1 7.9384e+00 1.6472e-02 2.4096e-02 -6.0000e+00 1.7730e-02 1.0029e-01 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