File name: Pandora114s1_BuenosAires_20170331_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T001034.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170331_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170331 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170331T101122.0Z 6299.424560 423 1 32.01 2 89.74 84.58 132.84 102.64 0.00 1 0.00 1 0 22 2.451e-02 2.369e-02 2.460e-02 2.415e-02 4.561901e+03 1.646371e+03 3.738335e+02 -6.000000e+00 1.363300e+03 287.44 -2.00 20.00 -2.00 505.18 0.00e+00 -5.016633e-05 6.683462e-04 2.548964e-05 -6.000000e+00 6.873287e-04 287.44 -2.00 20.00 -2.00 499.75 0.00e+00 2.533294e+00 4.934864e-01 1.769690e-02 -6.000000e+00 4.796207e-01 227.11 -2.00 3.16 -2.00 501.43 0.00e+00 19.979 0.075 489.00 513.00 1 8.1712e+00 3.8011e-02 3.0573e-02 -6.0000e+00 3.6786e-02 1.3753e-01 9.6810e-03 1.7602e-03 -6.0000e+00 9.6163e-03 2.6457e-05 4.1083e-03 2.2829e-03 3.8025e-05 -6.0000e+00 2.4144e-03 2.6679e-02 -2.3361e-04 12 8 8 10 0 0 70.20 22.62 3.60 0.02668 0.05518 8 2 1 4 0 4000.000 26.51 20.00 22.62 930 -1595 1212 -617 144 -837 628 396 406 535 -414 3140 -630 -3255 -914 -357 -1154 -2198 1842 -88 1956 1053 866 -162 -2050 -503 1730 257 -2540 998 -1680 -2165 4069 2936 6213 2803 795 -1956 -1558 1506 -2863 -1397 -1452 2279 -1807 320 -3539 -919 1796 -2653 4047 -2891 -1408 552 2407 4885 -1680 -1782 261 1730 827 -1954 2021 1470 577 -724 2632 -1605 -1087 -1655 -2175 3559 39 1062 353 -3327 3474 168 1040 -1386 266 -1918 -1113 -4425 -1745 2837 -5038 4371 1527 2544 -1561 -3128 56 -448 3453 -2490 3432 1284 -1673 1845 179 3246 -5146 2587 -3651 -2869 -1959 1343 1416 1543 -123 -3012 3706 1024 2415 3241 -3308 -3818 553 4160 -1385 1101 3825 869 -1913 -2194 2051 -1671 -1491 984 -3056 955 2734 1358 -291 5018 306 2511 4591 -3656 4386 1714 -313 -5824 -3710 -2743 -710 7343 -954 367 -1142 -426 -523 927 -1672 1276 -682 161 -970 728 463 472 614 -472 3410 -701 -3679 -1004 -392 -1300 -2568 2113 -104 2276 1236 1020 -193 -2501 -567 1894 282 -2804 1032 -1745 -2255 4058 3059 6445 3044 877 -2194 -1718 1593 -3152 -1519 -1593 2431 -2027 353 -4043 -1012 1892 -2858 3965 -2947 -1383 529 2294 4670 -1762 -1903 275 1789 860 -2090 2084 1527 602 -758 2625 -1642 -1089 -1646 -2147 3286 37 1013 344 -3387 3285 161 971 -1309 246 -1811 -1047 -4335 -1678 2632 -5099 4042 1453 2391 -1527 -3120 55 -444 3311 -2517 3209 1197 -1472 1624 148 2558 -4422 2104 -3280 -2653 -1833 1218 1268 1360 -109 -2773 3231 930 2186 2930 -3207 -3738 522 3794 -1329 1016 3377 778 -1748 -2013 1813 -1538 -1371 881 -2843 852 2388 1188 -254 4109 262 2119 3868 -3416 3849 1566 -295 -5832 -3658 -2693 -685 6525 -911 339 -1048 -382 -469 SO 20170331T101534.0Z 6299.427477 427 1 32.00 2 88.88 83.98 132.05 101.90 0.00 1 0.00 1 0 15 1.987e-02 1.968e-02 1.790e-02 1.761e-02 5.290893e+03 1.198517e+03 3.336276e+02 -6.000000e+00 1.105495e+03 287.44 -2.00 20.00 -2.00 505.19 0.00e+00 7.358157e-04 4.828308e-04 4.057438e-05 -6.000000e+00 5.570606e-04 287.44 -2.00 20.00 -2.00 499.80 0.00e+00 9.748878e-01 3.583843e-01 3.900151e-02 -6.000000e+00 3.878093e-01 227.11 -2.00 3.16 -2.00 501.45 0.00e+00 18.262 0.057 489.00 513.00 1 8.1869e+00 2.7501e-02 2.7582e-02 -6.0000e+00 2.9763e-02 1.5273e-01 7.1027e-03 1.7283e-03 -6.0000e+00 7.7508e-03 3.6887e-05 4.7907e-03 1.6479e-03 2.9329e-05 -6.0000e+00 1.9553e-03 1.4120e-02 5.1275e-05 12 9 8 11 8 0 46.26 22.62 2.61 0.01412 0.04735 8 2 1 4 0 4000.000 26.51 20.00 22.62 2870 -3712 -1298 -1463 -1369 2810 -2479 5122 -1753 301 1452 2160 -837 -1647 645 -3959 -1391 199 -320 91 1375 2254 -548 1249 -1437 689 358 -557 852 -390 -2359 334 2297 1170 -1006 2885 -1123 -1505 -2956 3426 2883 1538 1061 -720 -231 -1597 2513 599 -1682 1013 -1738 1711 -3533 1076 -992 3931 -1394 1232 -2113 441 1473 -1350 738 1151 -231 2097 -2401 403 -2050 1765 -1597 -519 426 -867 2594 -417 2307 -1540 1589 -2019 -1474 -1262 -3099 3737 -3685 1453 -902 -328 761 -2110 5355 17 2233 880 1352 1005 -2295 1147 -1947 -582 -1291 326 1533 -3802 2256 115 -1072 -1526 1825 206 -771 -1340 -915 1266 -2981 -44 2067 1840 211 -3074 3763 -738 -322 280 1305 834 -1879 1887 -1038 3369 1095 -2207 565 2562 2160 3181 2986 2043 -2018 -2745 -2090 897 487 -805 -3035 4149 -503 -527 -1548 -3014 -210 -2970 1888 2869 -4074 -1436 -1668 -1596 3200 -3012 5780 -2104 348 1637 2383 -939 -1844 703 -4559 -1493 215 -356 102 1514 2460 -615 1383 -1640 768 398 -615 904 -407 -2466 341 2356 1254 -1130 3136 -1262 -1677 -3300 3558 3007 1634 1143 -798 -257 -1807 2715 652 -1840 1054 -1805 1670 -3570 1039 -997 3875 -1487 1298 -2308 468 1545 -1461 785 1220 -247 2167 -2553 409 -2107 1725 -1594 -509 415 -866 2534 -422 2249 -1531 1505 -1962 -1420 -1144 -2878 3266 -3502 1325 -848 -307 705 -2005 4723 16 2068 835 1280 945 -2183 1027 -1751 -504 -1104 272 1272 -3419 1986 107 -1024 -1459 1666 188 -710 -1253 -864 1185 -2938 -42 1956 1754 205 -3099 3514 -709 -302 257 1183 762 -1772 1716 -971 3009 998 -2074 513 2245 1868 2693 2531 1769 -1856 -2592 -1879 792 435 -732 -2837 3624 -460 -480 -1404 -2713 -180 -2583 1569 SO 20170331T101939.0Z 6299.430313 431 1 32.00 2 88.04 83.40 131.27 101.20 0.00 1 0.00 1 0 15 1.580e-02 1.563e-02 1.393e-02 1.369e-02 8.009889e+03 9.690933e+02 5.823161e+02 -6.000000e+00 8.788967e+02 287.44 -2.00 20.00 -2.00 505.18 0.00e+00 3.985096e-04 3.753164e-04 3.197109e-05 -6.000000e+00 4.429492e-04 287.44 -2.00 20.00 -2.00 499.81 0.00e+00 1.195915e+00 2.768239e-01 3.861525e-02 -6.000000e+00 3.086755e-01 227.11 -2.00 3.16 -2.00 501.46 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