File name: Pandora114s1_BuenosAires_20170412_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T003627.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170412_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170412 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170412T102045.0Z 6311.431076 307 1 32.00 2 89.72 79.06 79.44 266.68 0.00 1 0.00 1 0 22 9.157e-02 8.720e-02 7.858e-02 7.695e-02 1.575236e+03 4.572287e+03 2.008527e+02 -6.000000e+00 5.080967e+03 286.86 -2.00 20.00 -2.00 505.19 0.00e+00 2.338197e-03 2.093255e-03 2.195050e-04 -6.000000e+00 2.564231e-03 286.86 -2.00 20.00 -2.00 500.15 0.00e+00 -2.876612e-01 1.528830e+00 3.296489e-02 -6.000000e+00 1.791828e+00 226.42 -2.00 3.16 -2.00 501.75 0.00e+00 19.981 0.075 489.00 513.00 1 9.5378e+00 1.1687e-01 3.1024e-02 -6.0000e+00 1.3739e-01 1.5362e-01 3.0792e-02 1.6840e-03 -6.0000e+00 3.5953e-02 8.0132e-06 3.2951e-03 7.3639e-03 8.7612e-05 -6.0000e+00 9.0198e-03 9.7049e-02 -7.1389e-04 12 8 8 10 0 0 99.48 21.18 0.00 0.09705 0.11991 8 2 1 4 0 4000.000 25.28 20.03 21.18 -4370 3935 -2759 -228 -6806 -4332 4165 6144 9707 6806 -2671 -11020 8576 4745 -1499 -7842 1530 930 4087 -12857 6944 2054 18224 -2572 195 11640 -128 28293 -10209 3323 -1531 -5246 -12197 -10275 8238 4101 16700 -7754 -3137 7195 7023 8049 -10185 3822 5001 -6658 868 11280 7756 -4386 6253 -12421 -5605 -11343 2449 10211 2243 1294 -4428 8989 11466 5066 9597 -9543 4357 10580 -7979 -14268 -7819 13785 -7830 20718 -8192 5112 -20132 -2061 8183 8819 262 -6304 28027 10780 1596 8220 11851 -5237 -4394 412 -4278 3460 -11518 -8288 2777 -8238 4470 16498 2021 4685 -480 -4308 -8484 5719 -5494 4528 4490 -4145 -7836 -7956 15079 -5705 4384 6585 560 4287 14080 -5624 6156 1916 -2209 -818 7454 -4699 2887 -5544 13187 2976 11763 -2440 -19105 2660 -4243 23465 -8417 2590 -2159 6996 -6012 2931 24024 436 2557 -7853 5004 -10999 11869 10211 -7380 8251 -611 5076 -6136 -16874 16778 -4520 3837 -2972 -247 -8067 -5111 4577 6653 10093 7187 -3051 -13478 8501 4832 -1508 -8439 1523 954 4152 -15646 6948 2159 16311 -2846 211 11238 -139 22763 -11807 3259 -1540 -5461 -13861 -11832 8119 4268 15284 -8968 -3424 7018 6851 7812 -11984 3959 5181 -7801 943 10947 7683 -4808 6006 -13991 -5778 -12320 2352 9345 2290 1360 -4965 8814 10955 5171 9410 -11372 4513 10215 -9148 -17148 -8690 12200 -8505 16773 -8857 4884 -23537 -2031 7736 7650 243 -6181 20717 8893 1452 7053 9889 -5233 -4392 394 -4295 3213 -12434 -8713 2644 -8893 4298 14077 1972 4373 -462 -4204 -8439 4853 -5206 3949 4043 -4201 -8386 -8514 12653 -5809 4009 5929 544 4082 12346 -6071 5949 1942 -2343 -856 7133 -5007 2803 -5776 11314 2834 10314 -2473 -21531 2558 -4104 18252 -8440 2298 -1973 6101 -5575 2652 17894 394 2303 -7944 4485 -11615 10006 8790 -7596 7249 -580 4460 -5881 -17669 12506 SO 20170412T102457.0Z 6311.433993 311 1 31.99 2 88.88 78.46 80.27 266.11 0.00 1 0.00 1 0 22 8.166e-02 5.186e-02 4.279e-02 4.197e-02 4.750966e+03 2.691976e+03 3.422830e+02 -6.000000e+00 4.532903e+03 286.86 -2.00 20.00 -2.00 505.26 0.00e+00 3.199933e-03 1.139312e-03 1.563606e-04 -6.000000e+00 2.286768e-03 286.86 -2.00 20.00 -2.00 500.34 0.00e+00 2.319780e+00 8.113905e-01 3.127341e-02 -6.000000e+00 1.596153e+00 226.42 -2.00 3.16 -2.00 501.92 0.00e+00 18.274 0.057 489.00 513.00 1 8.9428e+00 6.2044e-02 2.7779e-02 -6.0000e+00 1.2243e-01 5.2594e-02 1.5925e-02 1.6335e-03 -6.0000e+00 3.1965e-02 1.5064e-05 1.0767e-02 3.9144e-03 6.8900e-05 -6.0000e+00 8.0391e-03 3.6236e-03 -3.0143e-05 12 8 8 10 0 0 79.90 21.18 3.83 0.00362 0.07831 8 2 1 4 0 4000.000 25.28 19.70 21.18 -6233 947 -5458 3500 -7912 1712 956 1083 2083 4146 -4035 10590 9404 6788 1223 -179 341 441 2259 3231 4471 2771 -1973 169 690 4563 -6317 4026 -7551 -6872 1386 -1322 -4813 -646 3992 676 4354 1409 925 -3335 4735 4840 -6424 1263 -5189 -2205 -914 3190 4346 2853 -2230 81 -3425 60 -1864 -51 -336 3050 538 -3757 426 -2615 -2856 -530 1207 540 -4028 -5829 -5904 1964 8455 1711 1061 -3810 4017 12 480 784 -801 4243 1467 -4769 -7789 7665 -4919 6825 4300 9849 4795 -645 318 -2036 4400 -3617 5852 -2445 5983 -809 -5156 -5894 -7315 13291 -2264 5 -1455 -4436 511 -2100 -8578 -5297 -2523 -1177 7897 -3505 2520 -661 1523 7149 -2658 -3985 3471 -2732 -842 100 2875 3790 347 -543 -121 12098 84007 11213 -3582 2050 -4545 -4411 2033 72 1422 -160 2664 5642 -2323 -3119 -6812 -622 -2779 -527 -1055 396 137 -2139 4245 -6466 943 -5598 3379 -8767 1756 999 1132 2137 4105 -4272 9556 8485 6237 1188 -179 345 457 2342 3341 4574 2888 -2164 183 745 4743 -7277 4118 -8450 -7426 1361 -1345 -5214 -695 4193 738 4550 1499 979 -3668 4818 4965 -7470 1379 -6106 -2528 -1030 3412 4518 2942 -2354 81 -3523 60 -1943 -53 -365 3245 552 -4019 437 -2777 -3055 -555 1235 549 -4226 -6130 -6133 1863 7435 1601 1004 -3830 3781 11 464 741 -758 3786 1343 -4660 -7890 6701 -4920 6125 3980 8635 4414 -625 306 -2021 4152 -3748 5537 -2490 5492 -776 -5038 -5668 -6997 10252 -2061 5 -1403 -4539 503 -2111 -9087 -5380 -2498 -1165 7269 -3677 2372 -648 1470 6574 -2714 -4128 3309 -2731 -813 95 2644 3476 332 -526 -117 10335 37152 9660 -3554 1895 -4422 -4248 1840 67 1342 -156 2572 5352 -2406 -3276 -7468 -645 -2945 -543 -1077 390 132 -2101 3945 SO 20170412T102858.0Z 6311.436782 315 1 32.00 2 88.07 77.89 81.07 265.56 0.00 1 0.00 1 0 15 1.566e-02 1.554e-02 1.320e-02 1.316e-02 5.431714e+03 8.480462e+02 3.671285e+02 -6.000000e+00 8.690655e+02 286.86 -2.00 20.00 -2.00 505.35 0.00e+00 4.374761e-03 3.618963e-04 2.400246e-04 -6.000000e+00 4.383471e-04 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