File name: Pandora114s1_BuenosAires_20170414_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T003630.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170414_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170414 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170414T102218.0Z 6313.432153 320 1 32.00 2 89.73 78.18 58.44 273.42 0.00 1 0.00 1 0 22 1.041e-01 9.799e-02 7.638e-02 7.408e-02 1.233792e+04 5.534833e+03 9.411776e+02 -6.000000e+00 5.775919e+03 286.76 -2.00 20.00 -2.00 505.30 0.00e+00 2.236506e-06 2.051986e-03 9.992558e-05 -6.000000e+00 2.912909e-03 286.76 -2.00 20.00 -2.00 500.11 0.00e+00 1.555769e+00 1.504859e+00 4.108827e-02 -6.000000e+00 2.026650e+00 226.31 -2.00 3.16 -2.00 501.75 0.00e+00 19.987 0.075 489.00 513.00 1 9.3697e+00 1.1549e-01 3.0851e-02 -6.0000e+00 1.5556e-01 9.4169e-02 2.9282e-02 2.1535e-03 -6.0000e+00 4.0420e-02 8.3435e-06 -5.1992e-04 6.7917e-03 8.3626e-05 -6.0000e+00 1.0234e-02 5.0014e-03 2.3056e-04 12 8 8 10 0 0 -707.58 22.21 19.16 0.00500 0.00140 8 2 1 4 0 4000.000 26.21 19.59 22.21 5414 14996 -9661 21981 1443 9460 7921 -1806 2785 176 6416 -12220 6382 -11004 9805 7939 -17697 9962 -9993 -4281 8244 -5109 1141 -5346 3310 -2393 5079 -16586 13347 -3608 12216 14557 -11873 15280 1169 13025 -7507 -4472 13313 -13870 10728 -7149 23801 2717 2813 -4512 -6434 11331 -8696 15714 4762 17391 -3354 -10950 -1370 -3512 27426 -16915 -819 -3173 -1599 4068 -14952 5710 4022 10266 10778 -3306 8798 -7204 9643 -12091 9139 11291 -3655 2704 -8540 8250 -9115 8339 -2457 5726 10591 2957 7153 -16515 20389 -4455 5927 -2763 9374 3126 -10108 1703 -15748 8960 -550 5219 19603 -14742 2812 -7694 -403 -467 15373 3724 1202 12875 1571 40277 -2797 12304 -7587 -11595 1228 -10807 9934 -5206 -3198 7266 -13527 8755 -9561 1959 1454 8064 -7389 2630 -1448 -9894 7002 -2256 28103 -7793 -12 5716 6976 6824 -10662 683 11614 8151 3261 -6204 -5913 -9464 18103 614 12073 13313 -6302 -331 -4953 5026 12989 -11074 18926 1564 9666 8340 -2108 3091 198 6689 -15148 6488 -13184 9510 7906 -21674 9500 -11900 -4870 8301 -5886 1237 -6211 3542 -2711 5311 -21277 12406 -3860 10941 12755 -13852 14054 1273 12737 -8976 -5131 12632 -17122 10335 -8271 20393 2907 3037 -5265 -7631 11135 -10272 14225 4680 14648 -3409 -11979 -1386 -3740 22039 -21535 -892 -3532 -1750 4215 -18819 5860 4186 9940 10227 -3553 8262 -7847 8776 -13580 8317 10167 -3875 2709 -8915 7628 -9225 7001 -2286 4911 8700 2644 6200 -18363 15823 -4448 5326 -2696 8083 2880 -10735 1623 -17867 7808 -512 4429 13968 -14452 2272 -6844 -336 -403 11861 3380 1151 11044 1497 25774 -2742 10442 -7953 -12788 1198 -11918 8927 -5482 -3338 6892 -15778 8066 -10370 1858 1372 7136 -7679 2482 -1426 -9973 6323 -2101 20407 -7523 -12 5007 6047 6008 -10748 627 10331 7172 3050 -6439 -6163 -10267 14924 601 10417 11145 -6299 -308 -4845 SO 20170414T102628.0Z 6313.435046 324 1 31.99 2 88.89 77.58 59.28 272.82 0.00 1 0.00 1 0 15 5.591e-02 5.446e-02 4.603e-02 4.540e-02 8.191821e+03 3.168313e+03 4.566387e+02 -6.000000e+00 3.102254e+03 286.76 -2.00 20.00 -2.00 505.34 0.00e+00 1.073973e-04 1.253505e-03 6.302546e-05 -6.000000e+00 1.563957e-03 286.76 -2.00 20.00 -2.00 500.28 0.00e+00 3.308374e+00 8.928885e-01 7.264204e-02 -6.000000e+00 1.086447e+00 226.31 -2.00 3.16 -2.00 501.90 0.00e+00 18.304 0.057 489.00 513.00 1 8.9848e+00 6.8553e-02 2.8114e-02 -6.0000e+00 8.3419e-02 3.4441e-02 1.7318e-02 2.1399e-03 -6.0000e+00 2.1631e-02 1.3905e-05 -4.1719e-03 4.1350e-03 3.9374e-05 -6.0000e+00 5.4890e-03 7.3085e-02 -7.6631e-05 12 8 8 10 0 0 90.60 22.18 4.12 0.07308 0.04415 8 2 1 4 0 4000.000 26.21 20.67 22.18 4186 2230 -3639 6823 -15318 -992 -5719 896 -4372 -3636 5001 -1804 -5775 -3868 -666 4667 -1596 4559 -1006 13209 -490 7205 474 5634 1143 -7526 3473 26584 -7103 -2480 -4984 7148 -4283 -340 -1757 957 -5090 3021 -1416 -6699 -1403 -422 8665 821 6778 -4701 -5208 2623 4609 -1994 5507 -1973 4382 9154 -1154 -495 3993 -3136 9705 1783 5804 4261 4677 2389 -6376 2490 -146 1580 741 -2189 3687 -7742 -3714 484 -3021 1414 3088 1021 -2026 2162 -1376 -8781 3234 2167 11451 -1647 1286 -6788 -3545 -3856 3879 4918 1187 -5225 -2189 11202 -5690 2206 5739 -7253 6091 4686 3704 -9643 5510 800 5323 3366 -2935 8837 -6471 -164 1221 1987 2642 6955 5083 -9412 -1522 -3973 5519 4292 -3215 6235 2010 -2993 1339 -2624 -5335 2074 2884 -3195 -2490 -7659 5801 -5696 -1712 14900 -10697 4862 329 1892 2045 2967 5080 -4728 2634 3230 2001 2087 -10451 1385 -6939 3912 2183 -3650 6357 -18270 -1048 -6431 949 -4864 -3970 4941 -1885 -6203 -4039 -672 4501 -1672 4613 -1101 12698 -542 7396 521 5917 1262 -9066 3730 22401 -8198 -2657 -5368 6829 -4689 -370 -1997 1070 -6026 3263 -1580 -7812 -1548 -463 8767 909 7140 -5580 -6196 2857 4841 -2189 5458 -2049 4186 8311 -1182 -518 4111 -3306 9646 1796 5602 4183 4592 2405 -6988 2472 -146 1534 716 -2150 3374 -7882 -3637 459 -3009 1357 2895 960 -1927 1948 -1279 -8793 2888 1971 9588 -1590 1217 -6986 -3530 -3840 3571 4501 1139 -5407 -2204 9753 -5730 1994 4869 -6840 4931 3806 3060 -9361 4797 761 4960 3212 -2956 7817 -6642 -160 1186 1940 2435 6172 4618 -9955 -1502 -4046 5101 3966 -3148 5468 1826 -2867 1237 -2535 -5307 1916 2642 -3112 -2399 -7680 5012 -5473 -1582 11819 -11202 4455 321 1848 2018 2929 4948 -5112 2655 3230 2006 2055 -11436 1331 -7266 SO 20170414T103029.0Z 6313.437836 328 1 31.99 2 88.08 77.01 60.08 272.24 0.00 1 0.00 1 0 22 2.692e-02 2.644e-02 2.795e-02 2.772e-02 9.239469e+03 1.946607e+03 5.573801e+02 -6.000000e+00 1.493900e+03 286.76 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